CAS 88-89-1 MFCD00007102-Picric acid 2,4,6-三硝基酚(民爆品，不能销售) TAO{mole}

Picric acid 2,4,6-三硝基酚(民爆品，不能销售)

CAS 88-89-1 MFCD00007102

化学结构图

SMILES: O=[N+]([O-])c1cc([N+](=O)[O-])c(O)c([N+](=O)[O-])c1

化学属性

Mol. Formula	(O2N)3C6H2OH
Mol. Weight	229.10
Melting Point	122-123 °C (dried material, Lit. Merck Index 12th Ed.)(lit.)
Density	1.00 g/mL at 20 °C
Vapor Pressure	1 mmHg ( 195 °C)
Vapor Density	7.9 (vs air)
Flash Point	150℃
Boiling Point	300℃
Appearance	solution (saturated aqueous)
Solubility	可混溶，溶于热水、醇、苯、乙醚等。

别名和识别编码

Chemical Name	Picric Acid
Synonym	1,3,5-Trinitrophenol 1-Hydroxy-2,4,6-trinitrobenzene 1-Hydroxy-2,4,6-trinitrobenzol 2,4,6-Trinitrofenol 2,4,6-Trinitrofenolo 2,4,6-Trinitrophenol 2,4,6-Trinitrophenyl 2,4,6-trinitro-pheno 2,4,6-trinitrophenol 2,4,6-三硝[ 2,4,6-三硝基苯酚(干的或含水<30%) 2,4,6-三硝基酚 2-HYDROXY-1,3,5-TRINITROBENZENE 2-Hydroxy-1,3,5-trinitrobenzene 2-Hydroxy-1,3,5-trinitrobenzol 2.4.6-三硝基酚 2，4，6-三硝基苯酚 Acide picrique Acido picrico C.I. 10305 Carbazotic acid Kyselina pikrova Melinite Nitroxanthic acid PA PHENOL TRINITRATE PICRIC ACID PICRIC ACID, SATURATED PICRINIC ACID p
CAS Number	88-89-1
PubChem Substance ID	6954
Beilstein Registry Number	423400
MDL Number	MFCD00007102
EC Number	200-835-2
Chemical Name Translation	2,4,6-三硝基酚(民爆品，不能销售)
Merck Number	13,7492
Wiswesser Line Notation	WNR BQ CNW ENW
LabNetwork Molecule ID	LN00194841
InChI	InChI=1S/C6H3N3O7/c10-6-4(8(13)14)1-3(7(11)12)2-5(6)9(15)16/h1-2,10H

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

安全信息

GHS Symbol

WGK Germany1

Hazard statements

H201 Explosive; mass explosion hazard 爆炸品；大规模爆炸危险。
H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
H228 Flammable solid 易燃固体
H301 Toxic if swallowed 吞食有毒
H302+H332
H311 Toxic in contact with skin 皮肤接触中毒
H319 Causes serious eye irritation 严重刺激眼睛
H331 Toxic if inhaled 吸入中毒
H332 Harmful if inhaled 吸入有害

Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges Eyeshields, Faceshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US) Eyeshields, Faceshields, Gloves Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P230 Keep wetted with … 保持湿润
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
P250 Do not subject to grinding/shock/…/friction. 不要受研磨/冲击/....../摩擦。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P264+P265
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P310
P301+P312
P301+P316
P301+P317
P302+P352
P304+P340
P305+P351+P338
P307+P311
P308+P316
P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
P316
P319
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
P330 Rinse mouth. 漱口
P333+P313
P337+P313
P337+P317
P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
P361+P364
P362+P364
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P370+P378
P370+P380
P372 Explosion risk in case of fire. 在火中有灾爆炸的危险。
P373 DO NOT fight fire when fire reaches explosives. 火烧到爆炸物时，切勿救火。
P401 Store… 存储
P403+P233
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Danger

Hazard Codes F,T F;T F,Xn F,T,E,Xn

Safety Statements

S35 This material and its container must be disposed of in a safe way 该物料及其容器必须以安全方式处置；
S37 Wear suitable gloves 戴适当手套；
S36 Wear suitable protective clothing 穿戴适当的防护服；
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
S25 Avoid contact with eyes 避免眼睛接触；

Risk Statements

R4 Forms very sensitive explosive metallic compounds 生成非常敏感的易爆炸金属化合物
R1 Explosive when dry 干燥时易爆
R2 Risk of explosion by shock, friction, fire or other sources of ignition 遇到震动、摩擦、火焰或者其它引燃物有爆炸危险
R11 Highly flammable 非常易燃
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
R36 Irritating to eyes 刺激眼睛

UN Number UN 1344 4.1/PG 1 1344

Packing GroupI

Hazard Class4.1

Storage condition Store at RT.

RTECSTJ7875000

Warnings 危化品目录(2015) 危险化学品

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 60 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HBAMAK "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." (Leipzig,
   Ger. Dem. Rep.)  Volume(issue)/page/year: 4,1289,1935

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HBAMAK "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." (Leipzig,
   Ger. Dem. Rep.)  Volume(issue)/page/year: 4,1289,1935

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXP

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Bird - pigeon
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HBAMAK "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." (Leipzig,
   Ger. Dem. Rep.)  Volume(issue)/page/year: 4,1289,1935

TYPE OF TEST

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 56300 ug/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   NYKZAU Nippon Yakurigaku Zasshi.  Japanese Journal of Pharmacology. (Nippon
   Yakuri Gakkai, c/o Kyoto Daigaku Igakubu Yakurigaku Kyoshitsu, Konoe-cho,
   Yoshida, Sakyo-ku, Kyoto 606, Japan) V.40-    1944- Volume(issue)/page/year:
   56,450,1960

TYPE OF TEST            : LDLo

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 1800 ppm
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 47,75,1978

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 5 umol/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 90,91,1981

TYPE OF TEST            : Sex chromosome loss and nondisjunction
ROUTE OF EXPOSURE       : Parenteral
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 1500 ppm
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 7,677,1985

TYPE OF TEST            : Sex chromosome loss and nondisjunction
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 1250 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 90,91,1981

其他信息

灭火剂:水
蒸气压:1 mm Hg ( 195 °C)
外观性质:淡黄色晶状固体，无臭，味苦。
上游原料:硫酸 --> 硝酸 --> 苯酚 --> 2,4-二硝基氯苯
职业标准:TLV-TWA 0.1 毫克/ 立方米; STEL 0.3 毫克/ 立方米
下游产品:L-脯氨酸 --> L-赖氨酸 --> 4-咪唑甲醛 --> A,A二苯基Β苦基肼基游离基 --> 4-羟甲基咪唑盐酸盐 --> 尿刊酸 --> 4-咪唑乙酸盐酸盐 --> 4(5)-腈甲基咪唑 --> 反式-2,5-二甲基哌嗪 --> 2,3,4,5-四氢-5-甲基-1H-吡啶并[4,3-b]吲哚-1-酮 --> 5,6-二氢-4-(2-甲基-2-苯基肼基)-2-1H-吡啶酮 --> 2,4-哌啶二酮 --> 5-氨基-1H-咪唑-4-酰胺 --> 媒介棕 49 --> 2-甲基-1-丁硫醇 --> 8-羟基-5-甲基喹啉 --> 氯化苦
MOL 文件:88-89-1.mol
用途一:用作分析试剂
MSDS 信息:2,4,6-三硝基苯酚(88-89-1).msds
凝固型固定剂:苦味酸对于组织渗透缓慢，且能使组织强烈收缩。但可使蛋白质。核酸等沉淀，并防止过度硬化，对以后增进染色能力很大。一般很少单独使用，常与其他药剂混合使用。固定后需要用50％或70％酒精洗涤。特点：渗透力弱，易使组织发生收缩，易爆炸。注意事项：一般用50%或70%酒精洗涤。
Sigma Aldrich:88-89-1(sigmaaldrich)
爆炸物危险特性:高热、震动、撞击、摩擦可爆
储运特性:轻装轻放; 库房通风、远离明火、高温、阳光; 与氧化剂、易燃物分开存放
苦味酸价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 10015714 苦味酸(*)(XZ) 25g 20元
用途三:比色分析测定钾、重量分析测定铋，检定氰化物、有机分析检定芳香烃、胺、酚、生物碱、芳香族的酯，和杂环化合物
毒性分级:高毒
蒸气密度:7.9 (vs air)
可燃性危险特性:燃烧产生有毒氮氧化物烟雾
急性毒性:口服- 大鼠 LD50: 200 毫克/ 公斤; 腹注- 小鼠 LD50: 56.3 毫克/ 公斤
用途二:用于制红光硫化黑及酸性染料、照相药品、炸药及农药等，医药上用作外科收敛剂
图谱信息:苦味酸(88-89-1)红外图谱(IR1) 苦味酸(88-89-1)红外图谱(IR2) 苦味酸(88-89-1)质谱(MS)
类别:爆炸物品