CAS 5443-49-2 MFCD00006965-Alpha-Bromocinnamaldehyde a-溴肉桂醛 TAO{mole}

Alpha-Bromocinnamaldehyde a-溴肉桂醛

CAS 5443-49-2 MFCD00006965

化学结构图

SMILES: O=C/C(Br)=C/c1ccccc1

化学属性

Mol. Formula	C9H7BrO
Mol. Weight	211.06
Melting Point	66-68°C
Density	1.499
TSCA	No
Appearance	白色针状晶体。熔点72-73℃，沸点148-149℃（1.33kPa）。
Boiling Point	304.4 °C at 760 mmHg

别名和识别编码

Chemical Name	Alpha-Bromocinnamaldehyde
MDL Number	MFCD00006965
PubChem Substance ID	5369403
CAS Number	5443-49-2
EC Number	226-637-6
Beilstein Registry Number	7,358
Reaxys-RN	1072037
Synonym	2-Bromo-3-phenylacrylaldehyde {LY} 2-Bromo-3-phenylacrylaldehyde {} {LY} 2-Bromo-3-phenylacrylaldehyde {} {} {LY} 2-Bromo-3-phenylacrylaldehyde {} {} {} {LY} 2-Bromo-3-phenylacrylaldehyde {} {} {} {} {LY} 2-Bromo-3-phenylacrylaldehyde {} {} {} {} {} {LY} 2-Bromo-3-phenylacrylaldehyde {} {} {} {} {} {} {LY} 2-Bromo-3-phenylacrylaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-3-phenylacrylaldehyde {} {} {} {} {} {} {} {} {LY} 2-Bromo-3-phenylacrylaldehyde {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-3-phenylacrylaldehyde {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-3-phenylacrylaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-3-phenylacrylaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-3-phenylacrylaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-3-phenylacrylaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-3-phenylacrylaldehyde {} {} {}
Chemical Name Translation	a-溴肉桂醛
InChIKey	WQRWNOKNRHCLHV-TWGQIWQCSA-N
Wiswesser Line Notation	VHYEU1R
LabNetwork Molecule ID	LN00226236
InChI	InChI=1S/C9H7BrO/c10-9(7-11)6-8-4-2-1-3-5-8/h1-7H/b9-6-
Canonical SMILES	O=C/C(Br)=C/C1=CC=CC=C1

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

安全信息

WGK Germany3

GHS Symbol

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P312+P330
P302+P352+P332+P313+P362+P364
P305+P351+P338
P305+P351+P338+P337+P313
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H335 May cause respiratory irritation 可能导致呼吸道刺激
H302 Harmful if swallowed 吞食有害
H319 Causes serious eye irritation 严重刺激眼睛

Hazard Codes Xn

RTECSGD6480000

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

Signal word Warning

Safety Statements

S22 Do not breathe dust 不要吸入粉尘；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；

Risk Statements

R22 Harmful if swallowed 吞咽有害
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 470 mg/kg
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - ptosis
   Behavioral - ataxia
   Gastrointestinal - hypermotility, diarrhea
REFERENCE :
   SRTCAC Science Reports of the Research Institutes, Tohoku University, Series
   C: Medicine. (Tohoku University, Research Institute for Tuberculosis and
   Cancer, 4-1 Seiryo-machi, Sendai, Japan)  V.1-   1949-
   Volume(issue)/page/year: 36(1-4),10,1989

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 5 nmol/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 110,1,1983

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

用途二:有机合成中间体。
方法一:将肉桂醛和冰乙酸激烈搅拌，冷却下加溴反应。然后加入无水碳酸钾，将反应物加热回流半小时，冷却，析出粗品。粗品用乙醇溶解，重结晶，得成品，产率约80%。
Acros Organics:alpha-Bromocinnamaldehyde, 98%(5443-49-2)
Alfa Aesar:a-溴肉桂醛,98% alpha-Bromocinnamaldehyde, 98%(5443-49-2)
MOL 文件:5443-49-2.mol
用途一:用作有机合成原料
上游原料:乙酸 --> 碳酸钾 --> 肉桂醛
alpha-溴代肉桂醛价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 B1253 α-溴肉桂醛 alpha-Bromocinnamaldehyde 25G 383元 2010/06/21 171270500 alpha-溴代肉桂醛 alpha-Bromocinnamaldehyde 98% 50 GR 880元 2010/06/21 171272500 alpha-溴代肉桂醛 alpha-Bromocinnamaldehyde 98% 250 GR 3475元
Sigma Aldrich:5443-49-2(sigmaaldrich)
TCI Shanghai:α-溴肉桂醛 alpha-Bromocinnamaldehyde,>;98.0%(T)(5443-49-2)