Amygdalin 扁桃苷
CAS 29883-15-6 MFCD00006598
化学结构图
SMILES: N#CC(O[C@@H]1O[C@H](CO[C@@H]2O[C@H](CO)[C@@H](O)[C@H](O)[C@H]2O)[C@@H](O)[C@H](O)[C@H]1O)C1C=CC=CC=1
化学属性
| Mol. Formula | C20H27NO11 |
|---|---|
| Mol. Weight | 457 |
| Melting Point | 223-226 |
| TSCA | No |
| Density | 1.59 |
别名和识别编码
| Chemical Name | Amygdalin |
|---|---|
| Synonym | Amygdaloside D-Mandelonitrile-beta-D-glucosido-6-beta-D-glucoside D-扁桃腈-β-龙胆二糖苷 D-扁桃腈-β-龙胆二糖苷 D-扁桃腈6-O-β-D-葡糖基-β-D-葡萄糖苷 苦杏仁苷 R-Amygdalin 扁桃苷 苦杏仁苷 |
| MDL Number | MFCD00006598 |
| PubChem Substance ID | 87562069 |
| Beilstein Registry Number | 66856 |
| EC Number | 249-925-3 |
| CAS Number | 29883-15-6 |
| Merck Number | 14,597 |
| Reaxys-RN | 1695110 |
| Chemical Name Translation | 扁桃苷 |
| Wiswesser Line Notation | T6OTJ BOYR&CN CQ DQ EQ F1O- BT6OTJ CQ DQ EQ F1Q -D(-) |
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分类
- {SNA} Carbohydrates A to Z, Carbohydrates A-C, Disaccharide, Other Biochemical, Phytochemicals by Chemical Classification, 生化试剂, 碳水化合物, 细胞生物学, 营养研究
- {SNA} Carbohydrates A to Z, Carbohydrates A-C, Other Biochemical, Phytochemicals by Chemical Classification, 生化试剂, 碳水化合物,
- {SNA} Carbohydrates A to Z, Carbohydrates A-C, Other Biochemical, Phytochemicals by Chemical Classification, 生化试剂, 碳水化合物, 细胞生物学, 营养研究
- {SNA} Other Biochemical, Phytochemicals by Chemical Classification, 细胞
产品应用
- 生氰的糖苷是苦杏仁和杏仁凹点的组成部分。没有科学证据证明扁桃苷是抗癌物。最近的研究：联上瘤单克隆抗体的β−葡糖苷（β−glucoside）在瘤细胞里释放出氰，显示出很明显的细胞毒性。
相关文献及参考
- Merck: 14,597
- Merck: 14,597 Beilstein:17(3/4)3614
安全信息
- H302 Harmful if swallowed 吞食有害
GHS Symbol
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
- R22 Harmful if swallowed 吞咽有害
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P301+P312+P330
- P501 Dispose of contents/container to..… 处理内容物/容器.....
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 405 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Vol
TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Human - infant DOSE/DURATION : 50 mg/kg TOXIC EFFECTS : Behavioral - coma Lungs, Thorax, or Respiration - dyspnea Gastrointestinal - nausea or vomiting REFERENCE : JAMAAP JAMA, Journal of the American Medical Association. (AMA, 535 N. Dearborn St., Chicago, IL 60610) V.1- 1883- Volume(issue)/page/year: 238,482,1977
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 443 mg/kg TOXIC EFFECTS : Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold Lungs, Thorax, or Respiration - respiratory stimulation REFERENCE : YAKUD5 Gekkan Yakuji. Pharmaceuticals Monthly. (Yakugyo Jihosha, Inaoka Bldg., 2-36 Jinbo-cho, Kanda, Chiyoda-ku, Tokyo 101, Japan) V.1- 1959- Volume(issue)/page/year: 29,1291,1987
TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Mammal - dog DOSE/DURATION : 100 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: PB288-559
TYPE OF TEST : Host-mediated assay TEST SYSTEM : Rodent - mouse Bacteria - Salmonella typhimurium DOSE/DURATION : 250 mg/kg REFERENCE : SCIEAS Science. (American Assoc. for the Advancement of Science, 1333 H St., NW, Washington, DC 20005) V.1- 1895- Volume(issue)/page/year: 198,625,1977
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - hamster DOSE : 300 mg/kg SEX/DURATION : female 8 day(s) after conception TOXIC EFFECTS : Reproductive - Specific Developmental Abnormalities - Central Nervous System Reproductive - Specific Developmental Abnormalities - musculoskeletal system REFERENCE : SCIEAS Science. (American Assoc. for the Advancement of Science, 1333 H St., NW, Washington, DC 20005) V.1- 1895- Volume(issue)/page/year: 215,1513,1982
其他信息
- 三水合物为斜方柱状结晶(水), lg溶于900ml乙醇及11ml沸乙醇, 易溶于沸水。UVλMeOHmax nm(ε): 268(179), 262(255), 257(256), 251198), 208(7210); IRνmax cmˉ1: 3330, 2860, 1640, 1590, 1490, 1450, 1270, 1160, 1060, 690[1]。 植物来源：蔷薇科植物桃Prunus persica （L.）Batsch种子，巴旦杏P.amygdalus Batsch
- lg溶于900ml乙醇及11ml沸乙醇, 易溶于沸水。UVλMeOHmax nm(ε): 268(179), 262(255), 257(256), 251198), 208(7210); IRνmax cmˉ1: 3330, 2860, 1640, 1590, 1490, 1450, 1270, 1160, 1060, 690[1]。 水中溶解度:83 G/L (25°C)，溶于醇、醚 植物来源：蔷薇科植物桃Prunus persica （L.）Batsch种子，巴旦杏P.am
