N-Methylpiperidine N-甲基哌啶
CAS 626-67-5 MFCD00006491
信息真实价格透明
资金保障
专业采购外包团队在线服务
信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
一流品牌服务
分类
- {SNA} Building Blocks, C5 to C7, Chemical Synthesis, Heterocyclic Building Blocks, Piperidines
- {SNA} A-D, Alphabetical Listings, Flavors and Fragrances, Halal Certified Products, Kosher Certified Products, M-N
- {Chemicalbook} 农药中间体: 植物生长调节剂中间体
- {SNA} Molecular Biology, Protein Sequencing, Protein Structural Analysis, Proteomics, Reagents for Protein Sequencing
- {uni_hamburg} no charge; nitrogen heterocycle; alicycle; 6RingOnly; 6ring; 1fragment
- {SNA} Protein Sequencing, Protein Structural Analysis, Proteomics, Reagents for Protein Sequencing
- {SNA} Protein Sequencing, Protein Structural Analysis, Reagents for Protein Sequencing, 分子生物学, 蛋白质组学
产品应用
- Reactant for:
- ·sp3 C-H Bond activation with ruthenium(II) catalysts and C(3)-alkylation of cyclic amines
- ·One-pot synthesis of Z-cinnamic acids
- Reactant for synthesis of:
- ·Unsymmetrical ureas
- ·Antibacterial imidazolium, pyrrolidinium, and piperidinium salts
- ·C1-C16 segment of goniodomin A via palladium-catalyzed organostannane thioester coupling
- ·Multi-targeted inhibitors of insulin-like growth factor-1 receptor and members of ErbB-family receptor kinases
相关文献及参考
- Short: III/20a
- Beilstein:20,16
- Short: III/35D3
- Short: III/20c
安全信息
GHS Symbol
- S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S7 Keep container tightly closed 保存在严格密闭容器中;
- R10 Flammable 易燃
- R11 Highly flammable 非常易燃
- R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
- R22 Harmful if swallowed 吞咽有害
- R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
- R34 Causes burns 会导致灼伤
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性:吸入,皮肤接触和吞食都会产生十分严重的不可逆危险
- R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
- P241+P242+P243
- P242 Use only non-sparking tools. 只能使用无火花工具。
- P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P264+P265
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P310
- P301+P312
- P301+P330+P331
- P301+P330+P331+P310
- P302+P352
- P302+P361+P354
- P303+P361+P353
- P303+P361+P353+P310+P363
- P304+P340
- P304+P340+P310
- P305+P351+P338
- P305+P351+P338+P310
- P305+P354+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
- P316
- P317
- P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
- P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
- P330 Rinse mouth. 漱口
- P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P370+P378
- P403+P233
- P403+P235
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H301 Toxic if swallowed 吞食有毒
- H302 Harmful if swallowed 吞食有害
- H311 Toxic in contact with skin 皮肤接触中毒
- H312 Harmful in contact with skin 皮肤接触有害
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H318 Causes serious eye damage 严重伤害眼睛
- H331 Toxic if inhaled 吸入中毒
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
- H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Subcutaneous SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 400 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : BDCGAS Berichte der Deutschen Chemischen Gesellschaft. (Leipzig, Ger. Dem. Rep.) V.1-61, 1868-1928. For publisher information, see CHBEAM. Volume(issue)/page/year: 34,2408,1901
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 400 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : BEXBAN Bulletin of Experimental Biology and Medicine (English Translation). Translation of BEBMAE. (Plenum Pub. Corp., 233 Spring St., New York, NY 10013) V.41- 1956- Volume(issue)/page/year: 86,1325,1978
其他信息
- N-甲基哌啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0403 1-甲基哌啶 1-Methylpiperidine 500ML 993元 2014/06/02 M0403 1-甲基哌啶 1-Methylpiperidine 25ML 137元 2010/06/21 127482500 N-甲基哌啶 N-Methylpiperidine 99% 250 ML 756元
- MSDS 信息:N-甲基哌啶(626-67-5).msds
- 和水混溶。溶于甲醇、乙醇、丙酮和甲苯。
- 灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
- 用途三:药物和有机合成中间体。
- MOL 文件:626-67-5.mol
- 类别:易燃液体
- 方法一:其制备方法是在反应釜中加入哌啶、甲醛,最后加甲酸,加热,保持温度90℃,反应6h,冷却,向混合物加入盐酸,升温加热蒸出过量甲醛和甲酸,残留物冷却,加入氢氧化钠,升温蒸出1-甲基哌啶和水混合物,此混合物经固体氢氧化钠干燥,放到蒸馏釜中蒸馏得产品。
- 急性毒性:腹腔-小鼠 LD50: 400 毫克/ 公斤; 皮下- 兔子 LDL0: 300 毫克/ 公斤
- Acros Organics:N-甲基哌啶 N-Methylpiperidine, 99%(626-67-5)
- 用途一:用作药物和有机合成中间体
- F:3-10
- 可燃性危险特性:遇明火、高温、氧化剂易燃; 燃烧产生有毒氮氧化物烟雾
- Alfa Aesar:1-甲基哌啶,97% 1-Methylpiperidine, 99%(626-67-5)
- 上游原料:固体氢氧化钠
- Sigma Aldrich:626-67-5(sigmaaldrich)
- 毒性分级:高毒
- 用途二:1-甲基哌啶是植物生长调节剂甲哌鎓的中间体。
- 图谱信息:N-甲基哌啶(626-67-5)核磁图( 1 HNMR) N-甲基哌啶(626-67-5)核磁图( 13 CNMR) N-甲基哌啶(626-67-5)质谱(MS) N-甲基哌啶(626-67-5)红外图谱(IR1)
- 储运特性:库房通风低温干燥; 与氧化剂、酸类分开存放
- 外观性质:无色液体。
- 海关编码:29333999
- TCI Shanghai:1-甲基哌啶 1-Methylpiperidine,>;99.0%(GC)(626-67-5)
- 下游产品:缩节胺