3-Bromopyridine 3-溴吡啶

CAS 626-55-1 MFCD00006373

化学结构图

626-55-1
SMILES: Brc1cccnc1

化学属性

Mol. FormulaC5H4BrN
Mol. Weight158.00
Boiling Point168.2°C at 760 mmHg
Density1.640
Refractive index1.5680 to 1.5720
Flash Point52°C
TSCAYes
Melting Point-27°C
Stability对光敏感

别名和识别编码

Chemical Name3-Bromopyridine
CAS Number626-55-1
Alfabeta NameBROMOPYRIDINE 3-
MDL NumberMFCD00006373
Synonym 3-Bromopyridine {LY} 3-Bromopyridine {} {LY} 3-Bromopyridine {} {} {LY} 3-Bromopyridine {} {} {} {LY} 3-Bromopyridine {} {} {} {} {LY} 3-Bromopyridine {} {} {} {} {} {LY} 3-Bromopyridine {} {} {} {} {} {} {LY} 3-Bromopyridine {} {} {} {} {} {} {} {LY} 3-Bromopyridine {} {} {} {} {} {} {} {} {LY} 3-Bromopyridine {} {} {} {} {} {} {} {} {} {LY} 3-Bromopyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromopyridine {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromopyridine {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromopyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromopyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromopyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromopyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromopyridine {} {} {} {} {} {} {} {} {} {} {} {}
EC Number210-952-0
Beilstein Registry Number105880
PubChem Substance ID12286
Reaxys-RN105880
Chemical Name Translation3-溴吡啶
LabNetwork Molecule IDLN00170216
InChIInChI=1S/C5H4BrN/c6-5-2-1-3-7-4-5/h1-4H
Canonical SMILESBrC1=CC=CN=C1
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {SNA} Building Blocks, C5, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Pyridines
  • {SNA} Baran Sulfinate Building Block Collection, Building Blocks, C5, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Pyridines, {Untitled Section}
  • Heterocycles
  • {SNA} Baran Sulfinate Building Block Collection, Building Blocks, C5, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Pyridines
  • {uni_hamburg} no charge; nitrogen heterocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • Aromatics

产品应用

  • Pyridine as novel substrate for regioselective oxygenation with aromatic peroxygenase from Agrocybe aegerita.

相关文献及参考

  • Beilstein:20,233
  • Colby, J., et al.: Biochem. J., 165, 395 (1977),
  • Short: II/14a
  • Short: III/35B
  • Short: III/38B
  • Undergoes lithiation with LDA at low temperatures in the 4-position: Heterocycles, 35, 151 (1993). Formation of the Grignard by Mg exchange with i-PrMgCl: Tetrahdron Lett., 40, 4339 (1999). Transmetallation of the lithiated derivative with ZnCl2 followed by treatment with an electrophile has been described, as a route to 4-substituted 3-bromopyridines: Org. Lett., 3, 835 (2001).

安全信息

Warnings LIGHT SENSITIVE, IRRITANT-HARMFUL, FLAMMABLE
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
Risk Statements
  • R10 Flammable 易燃
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P312
  • P301+P312+P330
  • P302+P352
  • P302+P352+P312+P362+P364
  • P303+P361+P353
  • P304+P312
  • P304+P340
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H301 Toxic if swallowed 吞食有毒
  • H302 Harmful if swallowed 吞食有害
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupIII
UN Number 1993 UN2810
Hazard Codes 3
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Class3

其他信息

  • 储运特性:库房通风低温干燥; 与酸,氧化剂分开存放
  • MOL 文件:626-55-1.mol
  • 下游产品:3-吡啶甲醛 --> 3-苯基哌啶 --> 3-吡啶-3-基苯甲酸 --> 3-(3-吡啶基)丙酸 --> 吡啶-3-硼酸 --> 3-(3-吡啶)丙烯酸 --> 3-溴吡啶-4-醛
  • MSDS 信息:3-Pyridyl bromide(626-55-1).msds
  • 灭火剂:泡沫、二氧化碳、雾状水
  • 用途一:抗抑郁药盐酸齐美定的中间体。
  • 爆炸物危险特性:有强碱性; 与乙酸-过氧化氢混合物反应爆炸(50℃以上时)
  • Acros Organics:3-溴吡啶 3-Bromopyridine, 99%(626-55-1)
  • Hazard Note:Toxic/Flammable/Irritant
  • 图谱信息:3-溴吡啶(626-55-1)质谱(MS) 3-溴吡啶(626-55-1)核磁图( 1 HNMR) 3-溴吡啶(626-55-1)红外图谱(IR1) 3-溴吡啶(626-55-1)核磁图( 13 CNMR)
  • Sigma Aldrich:626-55-1(sigmaaldrich)
  • 可燃性危险特性:热分解排出有毒氮氧化物和溴化物
  • 3-溴吡啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0651 3-溴吡啶(含稳定剂铜屑) 3-Bromopyridine (stabilized with Copper chip) 25G 463元 2010/06/21 107411000 3-溴吡啶 3-Bromopyridine 99% 100 ML 2200元 2010/06/21 107410250 3-溴吡啶 3-Bromopyridine 99% 25 ML 721元
  • TCI Shanghai:3-溴吡啶(含稳定剂铜屑) 3-Bromopyridine (stabilized with Copper chip),>;98.0%(GC)(626-55-1)
  • 水中溶解度:31 g/l (25 C),溶于大多数有机溶剂。
  • 海关编码:29333999
  • Alfa Aesar:3-溴吡啶,98+% 3-Bromopyridine, 98+%(626-55-1)
  • 存储注意事项:光敏感
  • 检测方法:GC,HPLC,NMR
  • F:8
  • 类别:爆炸物品

系列性分类


相关产品推荐