N-Ethylmorpholine N-乙基吗啡啉
CAS 100-74-3 MFCD00006177
信息真实价格透明
资金保障
专业采购外包团队在线服务
信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
一流品牌服务
分类
- {uni_hamburg} no charge; oxygen heterocycle; nitrogen heterocycle; alicycle; 6RingOnly; 6ring; ether; 1fragment
- {SNA} Protein Sequencing, Reagents for Protein Sequencing, 分子生物学, 蛋白质组学, 蛋白质结构分析
- {SNA} Molecular Biology, Protein Sequencing, Protein Structural Analysis, Proteomics, Reagents for Protein Sequencing
- {SNA} Building Blocks, C4 to C10, Chemical Synthesis, Heterocyclic Building Blocks, Morpholines/Thiomorpholines
- {SNA} Protein Sequencing, Protein Structural Analysis, Reagents for Protein Sequencing, 分子生物学, 蛋白质组学
产品应用
- 在PU 领域中可作为催化剂使用,常用作油类和树脂类的溶剂,也可用作有机合成的中间体等。
相关文献及参考
- Short: IV/18B
- Beilstein:27,6
- Short: EINECS
- Base for use in peptide and similar coupling reactions. For example, has been used in conjunction with ethyl chloroformate for the mild coupling of substituted aromatic acids with primary amines or for the coupling of N-hydroxysuccinimide active esters with peptide residues: J. Med. Chem., 34, 2328 (1991). Compare 4-Methylmorpholine, A12158. For peptide reagents, see Appendix 6.
安全信息
GHS Symbol
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R10 Flammable 易燃
- R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
- R34 Causes burns 会导致灼伤
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241+P242+P243
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331+P310
- P303+P361+P353
- P303+P361+P353+P310+P363
- P304+P340+P310
- P305+P351+P338
- P305+P351+P338+P310
- P308+P311
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H302+H332
- H311 Toxic in contact with skin 皮肤接触中毒
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 180 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#04778
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Mammal - species unspecified DOSE/DURATION : 1200 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 39(4),86,1974
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 18000 mg/m3/2H TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 15,116,1979
TYPE OF TEST : LCLo - Lowest published lethal concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 2000 ppm/4H TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU.
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Bacteria - Salmonella typhimurium DOSE/DURATION : 6667 ug/plate REFERENCE : ENMUDM Environmental Mutagenesis. (New York, NY) V.1-9, 1979-87. For publisher information, see EMMUEG. Volume(issue)/page/year: 9(Suppl 9),1,1987
其他信息
- 毒性分级:中毒
- 下游产品:水处理剂 --> 群多普利
- 有氨样臭。能与水、乙醇、丙酮、苯和乙醚混溶。易燃。低毒,半数致死量(大鼠,经口)1780mg/kg。有腐蚀性。
- 图谱信息:N-乙基吗啉(100-74-3)核磁图( 1 HNMR) N-乙基吗啉(100-74-3)红外图谱(IR2) N-乙基吗啉(100-74-3)红外图谱(IR1) N-乙基吗啉(100-74-3)核磁图( 13 CNMR) N-乙基吗啉(100-74-3)质谱(MS)
- 灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
- Alfa Aesar:4-乙基吗啉,99% 4-Ethylmorpholine, 98%(100-74-3)
- 刺激数据:皮肤- 兔子 453 毫克 轻度; 眼睛- 兔子 200 毫克 重度
- Sigma Aldrich:100-74-3(sigmaaldrich)
- 用途一:生产防腐剂、乳化剂和涂料。本产品溶于水、醇、醚,可作溶剂、催化剂、染料、药品、表面活性剂的中间体。
- MOL 文件:100-74-3.mol
- 用途二:用作溶剂,也用于有机合成
- 类别:易燃液体
- 有氨样臭。能与水、乙醇、丙酮、苯和乙醚混溶。易燃。低毒,半数致死量(大鼠,经口)1781mg/kg。有腐蚀性。
- 方法一:由吗啉与溴乙烷的应而得。
- 用途四:在PU 领域中可作为催化剂使用,常用作油类和树脂类的溶剂,也可用作有机合成的中间体等。
- N-乙基吗啉价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 E0145 N-乙基吗啉 4-Ethylmorpholine 25ML 129元 2014/06/02 E0145 N-乙基吗啉 4-Ethylmorpholine 500ML 327元 2010/06/21 149400025 N-乙基吗啉 N-Ethylmorpholine 99% 2.5 LT 1758元
- 急性毒性:口服- 大鼠 LD50: 1780 毫克/ 公斤; 口服- 小鼠 LD50: 1200 毫克/ 公斤
- F:8-23
- 用途三:用作油类和树脂类的溶剂,也可用作有机合成的中间体。
- 可燃性危险特性:遇明火、高温、氧化剂较易燃; 燃烧产生有毒氮氧化物烟雾
- 上游原料:氨 --> 溴乙烷 --> 二乙二醇
- Acros Organics:N-乙基吗啉 N-Ethylmorpholine, 99%(100-74-3)
- MSDS 信息:N-乙基吗啉(100-74-3).msds
- 凝固点:-63℃
- TCI Shanghai:N-乙基吗啡啉 4-Ethylmorpholine,>;99.0%(GC)(100-74-3)
- 敏感性:Air Sensitive
- 储运特性:库房通风低温干燥; 与氧化剂、酸类分开存放
- 海关编码:29349990
- 外观性质:无色液体,有氨味。