2-Methylpiperidine 2-甲基哌啶

CAS 109-05-7 MFCD00005982

化学结构图

109-05-7
SMILES: CC1CCCCN1

化学属性

Mol. FormulaC6H13N
Mol. Weight99.17
Density0.844
Refractive index1.4450 to 1.4500
Boiling Point118-119
Flash Point10°C(lit.)
TSCAYes
Melting Point-4.6°C
Solubility与水混溶。

别名和识别编码

Chemical Name2-Methylpiperidine
CAS Number109-05-7
EC Number203-642-1
Beilstein Registry Number79804
MDL NumberMFCD00005982
Synonym 2-Pipecoline {uni_hamburg} piperidine,2-methyl- 2-PIPECOLINE Pipecoline, alpha ALPHA-PIPECOLINE 2-METHYLPIPERIDINE 2-pipecoline (±)-2-methyl-piperidine alpha-Pipecolin Γ-甲氧基丙胺(3-甲氧基丙胺) 2-Methylpiperidine Piperidine, 2-methyl- NSC 31047 2-methyl-piperidin piperidine, 2-methyl- α-methylpiperidine AKOS BBS-00003594 2-pipecoline(alpha-) A-Pipecolin D-A-PIPECOLINE PIPECOLINE, ALPHA Pipicoline α-甲基哌啶 2-哌可啉 2-甲基哌啶 2-哌可啉 2-Methyl hexahydropyridine ALPHA-2-PIPECOLINE (±)-2-Methylpiperidine (±)-α-Pipecoline 2-甲哌啶
PubChem Substance ID7974
Reaxys-RN79804
Chemical Name Translation2-甲基哌啶
Wiswesser Line NotationT6MTJ B1
LabNetwork Molecule IDLN00220422
InChIInChI=1S/C6H13N/c1-6-4-2-3-5-7-6/h6-7H,2-5H2,1H3
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分类

  • {SNA} Building Blocks, C5 to C7, Chemical Synthesis, Heterocyclic Building Blocks, Piperidines
  • {SNA} Alphabetical Listings, Flavors and Fragrances, M-N
  • {uni_hamburg} no charge; nitrogen heterocycle; alicycle; 6RingOnly; 6ring; racemate; 1fragment

相关文献及参考

  • Beilstein:20,95
  • A useful method for the oxidation of secondary amines to nitrones by means of H2O2 catalyzed by Sodium tungsten oxide dihydrate, 87371 is illustrated for this amine. For method and list of examples, see: Org. Synth. Coll., 9, 632 (1998).
  • Short: III/35D3
  • Short: III/35B
  • {

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R11 Highly flammable 非常易燃
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H318 Causes serious eye damage 严重伤害眼睛
  • H302 Harmful if swallowed 吞食有害
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSTN1240000
Packing GroupII
UN Number 1993 2399/1993
Hazard Codes 3
Hazard Class3
Storage condition 密封阴凉保存 Flammables area
Warnings 危化品目录(2015) 
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 300 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   BDCGAS Berichte der Deutschen Chemischen Gesellschaft.  (Leipzig, Ger. Dem.
   Rep.)  V.1-61, 1868-1928. For publisher information, see CHBEAM.
   Volume(issue)/page/year: 34,2408,1901

Restrict 危险品

其他信息

  • 急性毒性:皮下- 兔子 LDL0: 300 毫克/ 公斤
  • 外观性质:无色液体，有刺激性气味。
  • 毒性分级:高毒
  • TCI Shanghai:2-甲基哌啶 2-Pipecoline,>;98.0%(GC)(109-05-7)
  • Acros Organics:2-甲基哌啶 2-Methylpiperidine, 99%(109-05-7)
  • FEMA:4244
  • 可燃性危险特性:遇明火、高温、氧化剂易燃; 燃烧产生有毒氮氧化物烟雾
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类分开存放
  • 图谱信息:2-甲基哌啶(109-05-7)红外图谱(IR1) 2-甲基哌啶(109-05-7)质谱(MS) 2-甲基哌啶(109-05-7)核磁图( 13 CNMR) 2-甲基哌啶(109-05-7)核磁图( 1 HNMR)
  • 溶解水。和乙醇混溶。
  • 海关编码:29333999
  • Alfa Aesar:2-甲基哌啶,99% 2-Methylpiperidine, 99%(109-05-7)
  • 灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
  • Sigma Aldrich:109-05-7(sigmaaldrich)
  • 用途一:用作有机合成试剂
  • 2-甲基哌啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0443 2-甲基哌啶 2-Pipecoline 500ML 1080元 2014/06/02 P0443 2-甲基哌啶 2-Pipecoline 25ML 111元 2010/06/21 127491000 2-甲基哌啶 2-Methylpiperidine 99% 100 ML 375元
  • 类别:易燃液体
  • MSDS 信息:2-甲基哌啶(109-05-7).msds
  • MOL 文件:109-05-7.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Homopiperidines 同哌啶
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Piperazines 哌嗪
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Piperidines 哌啶