L-Pipecolic Acid L-哌啶-2-甲酸

CAS 3105-95-1 MFCD00005981

化学结构图

3105-95-1
SMILES: O=C(O)[C@@H]1CCCCN1

化学属性

Mol. FormulaC6H11NO2
Mol. Weight129.16
Melting Point272 °C
TSCANo
Solubility可溶
Refractive index-27 ° (C=4, H2O)
Density1.125
Boiling Point265.8°C at 760 mmHg

别名和识别编码

Chemical NameL-Pipecolic Acid
MDL NumberMFCD00005981
CAS Number3105-95-1
Synonym L-Pipecolic acid {LY} L-Pipecolic acid {} {LY} L-Pipecolic acid {} {} {LY} L-Pipecolic acid {} {} {} {LY} L-Pipecolic acid {} {} {} {} {LY} L-Pipecolic acid {} {} {} {} {} {LY} L-Pipecolic acid {} {} {} {} {} {} {LY} L-Pipecolic acid {} {} {} {} {} {} {} {LY} L-Pipecolic acid {} {} {} {} {} {} {} {} {LY} L-Pipecolic acid {} {} {} {} {} {} {} {} {} {LY} L-Pipecolic acid {} {} {} {} {} {} {} {} {} {} {LY} L-Pipecolic acid {} {} {} {} {} {} {} {} {} {} {} {LY} L-Pipecolic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Pipecolic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Pipecolic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Pipecolic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Pipecolic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID439227
Beilstein Registry Number81093
EC Number221-462-1
Merck Number7458
Chemical Name TranslationL-哌啶-2-甲酸
Reaxys-RN81093
LabNetwork Molecule IDLN00147063
InChIInChI=1S/C6H11NO2/c8-6(9)5-3-1-2-4-7-5/h5,7H,1-4H2,(H,8,9)/t5-/m0/s1
Canonical SMILESO=C([C@H]1NCCCC1)O
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分类

  • {SNA} Chemical Biology, Chemical Synthesis, Nutrition Research, Peptide Chemistry, Phytochemicals by Plant (Food/Spice/Herb), Proline Derivatives, Unnatural Amino Acid Derivatives, Zingiber officinale (Ginger)
  • {SNA} Amino Acids, Biochemicals and Reagents, Chemical Biology, Chemical Synthesis, I - Z, Modified Amino Acids, Peptide Chemistry, Phytochemicals by Plant (Food/Spice/Herb), Proline Derivatives, Unnatural Amino Acid Derivatives, Zingiber officinale (Ginger), 细胞生物学, 营养研究
  • {SA} Amino Acids, Biochemicals and Reagents, Chemical Biology, Chemical Synthesis,
  • {SNA} Chemical Biology,

相关文献及参考

  • Merck: 13,7539
  • Merck: 13,7539 Beilstein:22(5)1,220
  • [1]. Mihalik SJ, et al. Peroxisomal L-pipecolic acid oxidation is deficient in liver from Zellweger syndrome patients. Pediatr Res. 1989 May;25(5):548-52.

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Hazard Codes Xi
Storage condition 2-8°C {LY} 2-8°C Store at RT. {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C

其他信息

  • TCI Shanghai:D-(+)-2-哌啶酸 D-Pipecolic Acid,>;98.0%(T)(1723-00-8)
  • MSDS 信息:D(+)-Pipecolinic acid(1723-00-8).msds
  • 比旋光度:-27.5 ° (c=5, H2O 24 °C)
  • MOL 文件:1723-00-8.mol
  • Acros Organics:D(+)-2-哌啶酸 D(+)-Pipecolinic acid, 99%(1723-00-8)
  • D-(+)-2-哌啶酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010136 D-哌啶-2-羧酸 10g 360元 2011/04/16 P1830 D-(+)-2-哌啶酸 D-Pipecolic Acid 5G 869元 2011/04/16 P1830 D-(+)-2-哌啶酸 D-Pipecolic Acid 25G 2560元
  • 下游产品:罗哌卡因
  • 溶于水,溶于稀酸,微溶于无水乙醇、丙酮和氯仿;不溶于醚。存在于种子,麦芽,食用菌,水果等
  • Sigma Aldrich:3105-95-1(sigmaaldrich)
  • MSDS 信息:L(-)-Pipecolinic acid(3105-95-1).msds
  • Sigma Aldrich:1723-00-8(sigmaaldrich)
  • Alfa Aesar:L-哌啶-2-甲酸,99% L-Pipecolinic acid, 99%(3105-95-1)
  • 比旋光度:26.5 ° (c=5,water 25 °C)
  • TCI Shanghai:L-2-哌啶甲酸 L-Pipecolic Acid,>;97.0%(T)(3105-95-1)
  • MOL 文件:3105-95-1.mol
  • 图谱信息:L-2-哌啶酸(3105-95-1)质谱(MS) L-2-哌啶酸(3105-95-1)核磁图( 13 CNMR) L-2-哌啶酸(3105-95-1)红外图谱(IR2) L-2-哌啶酸(3105-95-1)红外图谱(IR1)
  • L-2-哌啶酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010135 L-哌啶-2-羧酸 10g 360元 2011/04/16 P1404 L-2-哌啶甲酸 L-Pipecolic Acid 5G 3570元 2011/04/16 P1404 L-2-哌啶甲酸 L-Pipecolic Acid 1G 1020元
  • Acros Organics:L(-)-2-哌啶酸 L(-)-Pipecolinic acid, 99%(3105-95-1)

系列性分类


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