CAS 826-36-8 MFCD00005975-2,2,6,6-Tetramethyl-4-Oxopiperidine 2,2,6,6-四甲基-4-哌啶酮 TAO{mole}

2,2,6,6-Tetramethyl-4-Oxopiperidine 2,2,6,6-四甲基-4-哌啶酮

CAS 826-36-8 MFCD00005975

化学结构图

SMILES: CC1(C)CC(=O)CC(C)(C)N1

化学属性

Mol. Formula	C9H17NO
Mol. Weight	155.24
Boiling Point	102-105°C at 760 mmHg
Melting Point	34-38°C
Flash Point	73°C
Appearance	白色或淡黄色粉末，熔点43℃，沸点205℃，能溶于丙酮，醇，醚和水。
pH	:A

别名和识别编码

Chemical Name	2,2,6,6-Tetramethyl-4-Oxopiperidine
CAS Number	826-36-8
Synonym	Triacetonamine {LY} Triacetonamine {} {LY} Triacetonamine {} {} {LY} Triacetonamine {} {} {} {LY} Triacetonamine {} {} {} {} {LY} Triacetonamine {} {} {} {} {} {LY} Triacetonamine {} {} {} {} {} {} {LY} Triacetonamine {} {} {} {} {} {} {} {LY} Triacetonamine {} {} {} {} {} {} {} {} {LY} Triacetonamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triacetonamine {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} Triacetonamine {} {} {} {} {} {} {} {} {} {} {} {LY} Triacetonamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triacetonamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triacetonamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triacetonamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triacetonamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
MDL Number	MFCD00005975
PubChem Substance ID	13220
EC Number	212-554-2
Chemical Name Translation	2,2,6,6-四甲基-4-哌啶酮
Wiswesser Line Notation	T6N DVTJ B1 B1 F1 F1
Beilstein Registry Number	0112665
LabNetwork Molecule ID	LN00222518
InChI	InChI=1S/C9H17NO/c1-8(2)5-7(11)6-9(3,4)10-8/h10H,5-6H2,1-4H3
Canonical SMILES	O=C1CC(C)(C)NC(C)(C)C1

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安全信息

WGK Germany2

GHS Symbol

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P305+P351+P338

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H335 May cause respiratory irritation 可能导致呼吸道刺激
H302 Harmful if swallowed 吞食有害
H319 Causes serious eye irritation 严重刺激眼睛

RTECSTO0127900

Signal word

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

Hazard Codes Xn C,Xn

Risk Statements

R34 Causes burns 会导致灼伤
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R22 Harmful if swallowed 吞咽有害

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S22 Do not breathe dust 不要吸入粉尘；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；

Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light Refrigerator (+4°C) {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 385 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   APPFAR Acta Poloniae Pharmaceutica (English Translation).  Translation of
   APPHAX.  (Warsaw, Poland) V.20-29, 1963-72.  Discontinued.
   Volume(issue)/page/year: 24,652,1967

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   APPFAR Acta Poloniae Pharmaceutica (English Translation).  Translation of
   APPHAX.  (Warsaw, Poland) V.20-29, 1963-72.  Discontinued.
   Volume(issue)/page/year: 24,652,1967

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1539 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 28(5),53,1984

其他信息

三丙酮胺:三丙酮胺有抗心律失常及抗心肌缺氧作用。以三丙酮胺为原料，以乙醇为溶剂，在催化剂作用下加氢(常压或3～4MPa)，可制得受阻胺类光稳定剂原料2，2，6，6-四甲基哌啶醇。
MSDS 信息:2,2,6,6-Tetramethyl-4-piperidone(826-36-8).msds
用途二:该品是受阻胺光稳定剂的中间体和制药中间体。
MOL 文件:826-36-8.mol
图谱信息:四甲基哌啶酮(826-36-8)核磁图( 13 CNMR) 四甲基哌啶酮(826-36-8)质谱(MS) 四甲基哌啶酮(826-36-8)红外图谱(IR1) 四甲基哌啶酮(826-36-8)红外图谱(IR2) 四甲基哌啶酮(826-36-8)核磁图( 1 HNMR)
用途一:用于合成抗阻胺类光稳定剂
Acros Organics:2,2,6,6-四甲基-4-哌啶酮 2,2,6,6-Tetramethyl-4-piperidone monohydrate, 98%(826-36-8)
四甲基哌啶酮价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 T1424 2,2,6,6-四甲基-4-哌啶酮 2,2,6,6-Tetramethyl-4-piperidone 500G 1890元 2014/06/02 T1424 2,2,6,6-四甲基-4-哌啶酮 2,2,6,6-Tetramethyl-4-piperidone 25G 278元 2010/06/21 AC42061EA 四甲基哌啶酮 2,2,6,6-tetramethyltetrahydro-4(1H)-pyridinone 10 GR 1065元
TCI Shanghai:2,2,6,6-四甲基-4-哌啶酮 2,2,6,6-Tetramethyl-4-piperidone,>;98.0%(T)(826-36-8)
Sigma Aldrich:826-36-8(sigmaaldrich)