Tetrachlorophthalic Anhydride 四氯邻苯二甲酸酐
CAS 117-08-8 MFCD00005920
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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分类
- {SNA} Anhydride Monomers, Materials Science, Monomers, Polymer Science
- {uni_hamburg} no charge; oxygen heterocycle; carbocycle; aromatic; large ring; fused rings; 5ring; 6ring; 9ring; carbo-anhydride; 1fragment
- {SNA} Anhydride Monomers, Monomers, Polymer Science, 材料科学
相关文献及参考
- {un
- Short: II/3
- Short: III/20b
- Short: III/10a
- Beilstein: 17,V,11,260
- Protection of amines as their tetrachlorophthalimide derivatives, by reaction with the anhydride in the presence of triethylamine, has been found to be useful in oligosaccharide chemistry. The group is stable to a wide range of reagents but can be selectively cleaved with ethylenediamine at lower temperatures than for the parent phthalimide derivatives; in particular, carboxylic esters are not cleaved under these conditions: J. Am. Chem. Soc., 117, 3302 (1995); J. Org. Chem., 61, 432 (1996).
安全信息
GHS Symbol



- S22 Do not breathe dust 不要吸入粉尘;
- S24 Avoid contact with skin 避免皮肤接触;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S53 Avoid exposure - obtain special instructions before use 避免接触,使用前获得特别指示说明;
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
- R42/43
- R45 May cause cancer 可能致癌
- R48/22
- R50/53
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P284 Wear respiratory protection.? 佩戴呼吸保护装置。
- P285 In case of inadequate ventilation wear respiratory protection. 在通风不足的情况下,戴呼吸防护。
- P302+P350
- P302+P352+P333+P313+P362+P364
- P304+P340+P342+P311
- P305+P351+P338
- P305+P351+P338+P310
- P308+P313
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H317 May cause an allergic skin reaction 可能导致皮肤过敏
- H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
- H350 May cause cancer 可能致癌
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- H318 Causes serious eye damage 严重伤害眼睛
- H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : >5 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : NTPTR* National Toxicology Program Technical Report Series. (Research Triangle Park, NC 27709) No.206- Volume(issue)/page/year: NIH-93-3351
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : >15800 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : NTPTR* National Toxicology Program Technical Report Series. (Research Triangle Park, NC 27709) No.206- Volume(issue)/page/year: NIH-93-3351
TYPE OF TEST : LC - Lethal concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : >3600 mg/m3/4H TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : NTPTR* National Toxicology Program Technical Report Series. (Research Triangle Park, NC 27709) No.206- Volume(issue)/page/year: NIH-93-3351
其他信息
- 参考检测标准:检验项目 检测标准 外观 白色结晶体或粉末 含量 99.0% min 主杂质 0.5%max 熔点 255-257℃ 干燥失重 0.5% min 色度 50# max 游离酸 0.1% max 游离氯 10PPMmax 六氯苯 0.1% max 铁 10PPM max 碱不溶物 0.5% max 溶解度 全溶(All)
- 用途一:用作酞菁类绿色颜料及占吨系染料中间体,也是醇酸树脂的原料
- Sigma Aldrich:117-08-8(sigmaaldrich)
- 四氯苯二甲酸酐价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 157790010 四氯苯二甲酸酐 Tetrachlorophthalic anhydride 98% 1 KG 617元 2010/06/21 157792500 四氯苯二甲酸酐 Tetrachlorophthalic anhydride 98% 250 GR 301元 2010/06/21 157790050 四氯苯二甲酸酐 Tetrachlorophthalic anhydride 98% 5 GR 247元
- 图谱信息:四氯苯二甲酸酐(117-08-8)红外图谱(IR2) 四氯苯二甲酸酐(117-08-8)红外图谱(IR1) 四氯苯二甲酸酐(117-08-8)质谱(MS) 四氯苯二甲酸酐(117-08-8)Raman光谱
- 下游产品:酸性红 92 --> 溶剂红 135 --> 六氢邻苯二甲酸酐 --> 六氢苯酐;六氢邻苯二甲酸酐;HHPA
- 上游原料:氯 --> 发烟硫酸 --> 氯磺酸 --> 苯酐 --> 碘 --> 1,2-二甲苯
- 用途二:用作染料中间体及增塑剂
- 外观:白色结晶或无色棱型针状。
- MSDS 信息:4,5,6,7-Tetrachloro-1,3-isobenzofurandione(117-08-8).msds
- 方法一:由苯酐在发因硫酸中通氯反应而得。也可由呷氯苯二甲酸在98℃加热脱水制得。
- 溶于二氧六环,难溶于醚,不溶于冷水,在热水中分解成四氯苯二甲酸。无气味。
- F:10-21
- 蒸气压:0.16 mm Hg ( 145 °C)
- TCI Shanghai:四氯邻苯二甲酸酐 Tetrachlorophthalic Anhydride,>;98.0%(GC)(T)(117-08-8)
- MOL 文件:117-08-8.mol
- Alfa Aesar:四氯邻苯二甲酸酐,98% Tetrachlorophthalic anhydride, 98%(117-08-8)
- 敏感性:Moisture Sensitive
- 用途三:该品为反应型阻燃剂,可用于聚酯、环氧树脂,但效果不如四溴苯酐。四氯苯二甲酸酐也是农药(稻瘟酞)、染料、药物、增塑剂、防火漆等有机合成的中间体。
- Acros Organics:四氯邻苯二甲酸酐 Tetrachlorophthalic anhydride, 98%(117-08-8)