2-Hydroxyisoindoline-1,3-dione N-羟基邻苯二甲酰亚胺
CAS 524-38-9 MFCD00005891
信息真实价格透明
资金保障
专业采购外包团队在线服务
信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
一流品牌服务
分类
- {uni_hamburg} no charge; nitrogen heterocycle; carbocycle; aromatic; large ring; fused rings; 5ring; 6ring; 9ring; amide; lactame; 1fragment
- {SNA} Active Esters/Additives, Chemical Biology, Chemical Synthesis, Coupling, Peptide Chemistry, Peptide Coupling, Synthetic Reagents
产品应用
- 用作阿米卡星等药物中间体。
相关文献及参考
- O-Alkylation followed by hydrazinolysis gives O-alkylhydroxylamines: Bull. Soc. Chim. Fr., 833 (1976). Copper-promoted coupling with arylboronic acids, followed by hydrazinolysis, affords O-arylhydroxylamines: Org. Lett., 3, 139 (2001).
- Merck: 14,4838
- O-Alkylation followed by hydrazinolysis gives O-alkylhydroxylamines: Bull. Soc. Chim. Fr., 833 (1976). Copper-promoted coupling with arylboronic acids, followed by hydrazinolysis, affords O-arylhydroxylamines: Org. Lett., 3,
- Short: EINECS
- Short: III/31a
- Merck: 14,4838 Beilstein:21,500
- Efficient electron carrier for electrochemical oxidation of alcohols: J. Chem. Soc., Chem. Commun., 479 (1983). Has also been found to be an efficient catalyst for non-electrochemical oxidation of benzylic groups in benzonitrile solution with atmospheric pressure oxygen: J. Org. Chem., 60, 3934 (1995). The method can be extended to alkanes by the use of a catalyst such as 0.5-1 mol% Co(acac)2. Thus cyclohexane is oxidized to cyclohexanone and adipic acid; adamantane gives mainly 1-adamantanol with minor amounts of 2-adamantanone and 1,3-adamantanediol: J. Org. Chem., 61, 4520 (1996). Under similar conditions alkynes can be oxygenated to ɑß-acetylenic ketones in good yields: Chem. Commun., 2037 (1998).
- Additive in the carbodiimide method of peptide coupling, leading to decreased racemization: J. Am. Chem. Soc., 89, 7151 (1967). For alternative reagents, see N,N'-Dicyclohexylcarbodiimide, A10973, and Appendix 6.
安全信息
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36 Wear suitable protective clothing 穿戴适当的防护服;
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352
- P302+P352+P332+P313+P362+P364
- P304+P340
- P305+P351+P338
- P305+P351+P338+P337+P313
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
- P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
- P332+P313
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 178 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#00747
其他信息
- 下游产品:邻-(2,3,4,5,6-全氟苯基)羟基氨,盐酸盐 --> 1,3-金刚烷二醇 --> 1-金刚烷醇 --> 合成鞣剂HV --> 合成鞣剂742号 --> 5-羟基对萘醌
- Acros Organics:N-羟基邻苯二甲酰亚胺 N-Hydroxyphthalimide, 98%(524-38-9)
- TCI Shanghai:N-羟基苯邻二甲酰亚胺 N-Hydroxyphthalimide,>;99.0%(T)(524-38-9)
- 海关编码:29251995
- Sigma Aldrich:524-38-9(sigmaaldrich)
- 用途一:用作阿米卡星等药物中间体,也用作烷基氧化剂、催化剂、选矿捕收剂
- 外观性质:白色至淡黄色针状结晶粉末。熔点:233-235 °C
- N-羟基邻苯二甲酰亚胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010092 N-羟基邻苯二甲酰亚胺(NOP) 100g 220元 2011/04/16 H0395 N-羟基苯邻二甲酰亚胺 N-Hydroxyphthalimide 500G 1460元 2011/04/16 H0395 N-羟基苯邻二甲酰亚胺 N-Hydroxyphthalimide 25G 182元
- Alfa Aesar:N-羟基邻苯二甲酰亚胺,98+% N-Hydroxyphthalimide, 98+%(524-38-9)
- 用途二:用作阿米卡星等药物中间体。
- 图谱信息:N-羟基邻苯二甲酰亚胺(524-38-9)红外图谱(IR1) N-羟基邻苯二甲酰亚胺(524-38-9)质谱(MS) N-羟基邻苯二甲酰亚胺(524-38-9)红外图谱(IR2)
- 检测方法:HPLC,NMR
- MOL 文件:524-38-9.mol
- MSDS 信息:N-Hydroxyphthalimide(524-38-9).msds