2-Iodothiophene 2-碘噻吩

CAS 3437-95-4 MFCD00005424

化学结构图

3437-95-4
SMILES: Ic1cccs1

化学属性

Mol. FormulaC4H3IS
Mol. Weight210.04
Boiling Point73 °C at 15 mmHg
Melting Point-40°C
TSCAT
Refractive index1.6500 to 1.6540
Density1.902
Flash Point77°C
pH:A

别名和识别编码

Chemical Name2-Iodothiophene
CAS Number3437-95-4
Alfabeta NameIODOTHIOPHENE 2-
MDL NumberMFCD00005424
PubChem Substance ID18921
EC Number222-342-1
Beilstein Registry Number104666
Synonym 2-Iodothiophene {LY} 2-Iodothiophene {} {LY} 2-Iodothiophene {} {} {LY} 2-Iodothiophene {} {} {} {LY} 2-Iodothiophene {} {} {} {} {LY} 2-Iodothiophene {} {} {} {} {} {LY} 2-Iodothiophene {} {} {} {} {} {} {LY} 2-Iodothiophene {} {} {} {} {} {} {} {LY} 2-Iodothiophene {} {} {} {} {} {} {} {} {LY} 2-Iodothiophene {} {} {} {} {} {} {} {} {} {LY} 2-Iodothiophene {} {} {} {} {} {} {} {} {} {} {LY} 2-Iodothiophene {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Iodothiophene {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Iodothiophene {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Iodothiophene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Iodothiophene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Iodothiophene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Iodothiophene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Iodothiophene {} {} {} {} {} {} {} {} {}
Chemical Name Translation2-碘噻吩
Reaxys-RN104666
InChIKeyROIMNSWDOJCBFR-UHFFFAOYSA-N
LabNetwork Molecule IDLN00116731
InChIInChI=1S/C4H3IS/c5-4-2-1-3-6-4/h1-3H
Canonical SMILESIC1=CC=CS1
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分类

  • Building Blocks, C4 to C6, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Thiophenes
  • {SNA} Building Blocks, C4 to C6, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Thiophenes

相关文献及参考

  • Beil. 17 ,V,1,309
  • Aldrich MSDS 1 , 1103:D / Corp MSDS 1 (1), 2008:C / FT-IR 1 (2), 593:B / FT-IR 2 (3), 3469:B / FT-NMR 1 (3), 45:B / IR-Spectra (3), 1207:E / NMR-Reference 2 (2), 468:B / RegBook 1 (2), 2331:K / Structure Index 1 , 367:A:3 / Vapor Phase 3 , 1468:C
  • In contrast to 2-Bromothiophene, A11959 which requires a copper catalyst, reaction with a variety of thiols, including Thiophene-2-thiol, B22642 to give 2,2'-dithienyl sulfide, proceeds in high yield in the absence of catalyst, base or solvent: Tetrahedron Lett., 36, 8439 (1995).

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Hazard Codes 3
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H318 Causes serious eye damage 严重伤害眼睛
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P302+P352
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P333+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
Storage condition -20°C, protect from light {LY} -20°C, protect from light Light Sensitive {} {LY} -20°C, protect from light {} {} {LY} -20°C, protect from light {} {} {} {LY} -20°C, protect from light {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect fro
UN Number 1993
Packing GroupIII

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Thiazolines/Thiazolidines 噻唑啉/噻唑烷
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Thiophenes 噻吩
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Halogenated Heterocycles 卤代杂环
  5. Thiophenes - Halogenated Heterocycles
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Halogenated Heterocycles 卤代杂环
  5. Thiophenes - Halogenated Heterocycles
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Thiophenes 噻吩
  5. C4 to C6 - Thiophenes
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Halogenated Heterocycles 卤代杂环
  5. Thiazolines/Thiazolidines

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