CAS 6012-97-1 MFCD00005422-Perchlorothiophene 四氯噻吩 TAO{mole}

Perchlorothiophene 四氯噻吩

CAS 6012-97-1 MFCD00005422

化学结构图

SMILES: Clc1sc(Cl)c(Cl)c1Cl

化学属性

Mol. Formula	C4Cl4S
Mol. Weight	221.92
Refractive index	n20/D 1.591(lit.)
Boiling Point	75 °C at 2 mmHg
Density	1.704 g/mL at 25 °C(lit.)
Melting Point	28-30 °C
Flash Point	113 ºC
TSCA	No

别名和识别编码

Chemical Name	Perchlorothiophene
CAS Number	6012-97-1
PubChem Substance ID	22344
EC Number	227-866-4
MDL Number	MFCD00005422
Beilstein Registry Number	0118374
Synonym	Perchlorothiophene {LY} Perchlorothiophene {} {LY} Perchlorothiophene {} {} {LY} Perchlorothiophene {} {} {} {LY} Perchlorothiophene {} {} {} {} {LY} Perchlorothiophene {} {} {} {} {} {LY} Perchlorothiophene {} {} {} {} {} {} {LY} Perchlorothiophene {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {LY} Perchlorothiophene {} {} {} {} {} {} {} {} {LY} Perchlorothiophene {} {} {} {} {} {} {} {} {} {LY} Perchlorothiophene {} {} {} {} {} {} {} {} {} {} {LY} Perchlorothiophene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Perchlorothiophene {} {} {} {} {} {} {} {} {} {} {} {} {LY} Perchlorothiophene {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Perchlorothiophene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Perchlorothiophene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Perchlorothiophene {} {} {} {} {} {} {} {} {} {} {
Chemical Name Translation	四氯噻吩
Wiswesser Line Notation	T5SJ BG CG DG EG
LabNetwork Molecule ID	LN00199914
InChI	InChI=1S/C4Cl4S/c5-1-2(6)4(8)9-3(1)7
Canonical SMILES	C1(=C(Cl)SC(=C1Cl)Cl)Cl

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安全信息

GHS Symbol

WGK Germany3

Hazard Codes T

Hazard statements

H301 Toxic if swallowed 吞食有毒
H301+H311+H331
H311 Toxic in contact with skin 皮肤接触中毒
H331 Toxic if inhaled 吸入中毒

Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

RTECSXN0350000

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P310
P302+P352
P304+P340
P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
P330 Rinse mouth. 漱口
P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P403+P233
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Danger

UN Number UN 2811 6.1/PG 3 2811 UN2811

Risk Statements

R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
R50/53

Safety Statements

S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；

Packing GroupIII

Hazard Class6.1(b)

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 70 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ARSIM* Agricultural Research Service, USDA Information Memorandum.
   (Beltsville, MD 20705)  Volume(issue)/page/year: 20,17,1966

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 256 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   WRPCA2 World Review of Pest Control.  (London, UK)  V.1-10, 1962-71.
   Discontinued.  Volume(issue)/page/year: 9,119,1970

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 75 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#00063

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 146 ppm
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   28ZEAL "Pesticide Index," Frear, E.H., ed., State College, PA, College
   Science Pub., 1969  Volume(issue)/page/year: 5,219,1976

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

储运特性:库房通风低温干燥; 与食品原料分开储运
可燃性危险特性:燃烧产生有毒硫氧化物和氯化物气体
类别:农药
毒性分级:高毒
下游产品:3,4,5-三氯噻吩-2-羰基氯
Sigma Aldrich:6012-97-1(sigmaaldrich)
MOL 文件:6012-97-1.mol
灭火剂:干粉、泡沫、砂土
急性毒性:口服- 大鼠 LD50: 70 毫克/ 公斤