CAS 3003-84-7 MFCD00005370-2-(Chloromethyl)tetrahydrofuran 2-(氯甲基)四氢呋喃 TAO{mole}

2-(Chloromethyl)tetrahydrofuran 2-(氯甲基)四氢呋喃

CAS 3003-84-7 MFCD00005370

化学结构图

SMILES: ClCc1ccco1

化学属性

Mol. Formula	C5H9ClO
Mol. Weight	120.58
Refractive index	1.4550 to 1.4580
Boiling Point	151°C(lit.)
Density	1.11 g/mL at 25 °C(lit.)
Flash Point	45°C(lit.)
TSCA	Yes
Appearance	无色液体。沸点47-48℃（2.0kPa），相对密度（20/4℃）1.107，折光率（nD20）1.457。

别名和识别编码

Chemical Name	2-(Chloromethyl)tetrahydrofuran
Synonym	AKOS BBS-00003854 氯化氢糠 2-(Chlormethyl)oxolan 2-Chloromethyltetrahydrofuran 2-氯甲基四氢呋喃 2-(Chloromethyl)t 2-(chloromethyl)tetrahydro-fura 2-chloromethyl-tetrahydro-furan Tetrahydrofurfurylchlorid 2-(Chlormethyl)tetrahydrofuran 四氢呋喃氯 Furan, 2-(chloromethyl)tetrahydro- 四氢糠氯 Tetrahydrofurfurylchloride,98% TETRAHYDROFURFURYL CHLORIDE 2-(CHLOROMETHYL)TETRAHYDROFURAN 2-(chloromethyl)oxolane 氯化四氢糠醇 TIMTEC-BB SBB008957 2-chloromethyl tetrahydrofuran 2-CHLOROMETHYLEN-TETRAHYDROFURAN 2-(氯甲)四氫呋喃 2-(chloromethyl)tetrahydrofuran tetrahydrofurfuryl chloride TETRAHYDRODURFURYL CHLORIDE
CAS Number	3003-84-7
PubChem Substance ID	18150
EC Number	221-102-3
Beilstein Registry Number	102716
MDL Number	MFCD00005370
Reaxys-RN	102716
Chemical Name Translation	2-(氯甲基)四氢呋喃
Wiswesser Line Notation	T5OTJ B1G
LabNetwork Molecule ID	LN00225904
InChI	InChI=1S/C5H9ClO/c6-4-5-2-1-3-7-5/h5H,1-4H2

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

产品应用

有机合成中间体。

安全信息

GHS Symbol

WGK Germany3

Hazard Codes Xi

Hazard statements

H226 Flammable liquid and vapour 易燃液体和蒸气
H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSLU0350000

Precautionary statements

P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P501 Dispose of contents/container to..… 处理内容物/容器.....
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P332+P313
P337+P313
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P305+P351+P338
P302+P352+P332+P313+P362+P364
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P303+P361+P353
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。

Signal word Warning {} {} {TCI}

UN Number 1993 UN 1993 3/PG 3 UN1993

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R10 Flammable 易燃

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
S37 Wear suitable gloves 戴适当手套；

Storage condition Moisture Sensitive 密封避光温度 2-8°C保存 2-8°C

Packing GroupIII

Hazard Class3

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 250 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Washington, DC 20418)
   Volume(issue)/page/year: 4,319,1952

其他信息

2-氯甲基四氢呋喃价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 T0800 四氢呋喃氯 Tetrahydrofurfuryl Chloride 25G 493元 2014/06/02 T0800 四氢呋喃氯 Tetrahydrofurfuryl Chloride 100G 1460元 2010/06/21 279501000 2-氯甲基四氢呋喃 Tetrahydrofurfuryl chloride 98+% 100 GR 1945元
急性毒性:腹腔-小鼠 LDL0: 250 毫克/公斤
毒性分级:中毒
储运特性:库房低温, 通风, 干燥
无色液体。对湿度敏感，
MOL 文件:3003-84-7.mol
上游原料:二氯甲烷 --> 氧氯化硫 --> 苯骈三氮唑 --> 四氢糠醇
F:21-10
图谱信息:2-氯甲基四氢呋喃(3003-84-7)红外图谱(IR2) 2-氯甲基四氢呋喃(3003-84-7)核磁图( 1 HNMR) 2-氯甲基四氢呋喃(3003-84-7)核磁图( 13 CNMR) 2-氯甲基四氢呋喃(3003-84-7)质谱(MS) 2-氯甲基四氢呋喃(3003-84-7)红外图谱(IR1)
可燃性危险特性:易燃; 火场放出有毒氯化物烟雾
用途一:有机合成中间体。
类别:易燃液体
海关编码:29321900
灭火剂:水, 二氧化碳, 干粉, 砂土
Acros Organics:2-（氯甲基）四氢呋喃 Tetrahydrofurfuryl chloride, 98+%(3003-84-7)
Alfa Aesar:氯化氢糠,98% Tetrahydrofurfuryl chloride, 98%(3003-84-7)
Sigma Aldrich:3003-84-7(sigmaaldrich)
MSDS 信息:Tetrahydrofurfuryl chloride(3003-84-7).msds
敏感性:Moisture Sensitive
TCI Shanghai:2-氯甲基四氢呋喃 Tetrahydrofurfuryl Chloride,>;98.0%(GC)(3003-84-7)
方法一:将2-四氢呋喃甲醇和吡啶混合，搅拌冷却，滴加氯化亚砜，随着反应的进行，析出糊状物质并放热使温度上升，控制温度在60℃以下。继续滴加氯化亚砜，反应物溶解成棕黑色液体。反应3-4h后，用乙醚提取反应液。乙醚提取液蒸除乙醚后进行减压蒸馏，收集47-48℃（2.0kPa）馏分，为2-氯甲基四氢呋喃。产率73%-75%。