CAS 2133-34-8 MFCD00005166-(S)-(-)-2-Azetidinecarboxylic Acid (S)-(-)-2-羧基环丁胺 TAO{mole}

(S)-(-)-2-Azetidinecarboxylic Acid (S)-(-)-2-羧基环丁胺

CAS 2133-34-8 MFCD00005166

化学结构图

SMILES: O=C(O)[C@@H]1CCN1

化学属性

Mol. Formula	C4H7NO2
Mol. Weight	101.10
Melting Point	217°C
TSCA	No
Solubility	5 G/100 ML
Appearance	白色结晶。熔点217℃。
Refractive index	-122 ° (C=4, H2O)
Density	1.422
Boiling Point	189.47 °C at 760 mmHg

别名和识别编码

Chemical Name	(S)-(-)-2-Azetidinecarboxylic Acid
CAS Number	2133-34-8
Alfabeta Name	AZETIDINECARBOXYLICACID S2(())-----
MDL Number	MFCD00005166
Synonym	L-Azetidine-2-carboxylic acid {LY} L-Azetidine-2-carboxylic acid {} {LY} L-Azetidine-2-carboxylic acid {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {} {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {} {} {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {} {} {} {} {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Azetidine-2-carbox
PubChem Substance ID	16486
Beilstein Registry Number	80678
EC Number	218-362-5
Merck Number	908
Chemical Name Translation	(S)-(-)-2-羧基环丁胺
Reaxys-RN	80678
Wiswesser Line Notation	T4MTJ BVQ -L
LabNetwork Molecule ID	LN00009449
InChI	InChI=1S/C4H7NO2/c6-4(7)3-1-2-5-3/h3,5H,1-2H2,(H,6,7)/t3-/m0/s1
Canonical SMILES	O=C([C@H]1NCC1)O

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安全信息

Warnings IRRITANT

WGK Germany3

Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

RTECSCM4310500

Safety Statements

S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；

Hazard Codes Xi

Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr

Signal word Warning

GHS Symbol

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P264+P265
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P302+P352
P304+P340
P305+P351+P338
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P319
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P332+P313
P332+P317
P337+P313
P337+P317
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P362+P364
P403+P233
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GDA2 "CRC Handbook of Antibiotic Compounds," Vols.1- ,  Berdy, J., Boca
   Raton, FL, CRC Press, 1980-  Volume(issue)/page/year: 8(1),101,1982

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 300 mg/kg
SEX/DURATION            : female 8-10 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   TJADAB Teratology, The International Journal of Abnormal Development. (Alan
   R. Liss, Inc., 41 E. 11th St., New York, NY 10003)  V.1-    1968-
   Volume(issue)/page/year: 14,248,1976

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 300 mg/kg
SEX/DURATION            : female 8 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - litter size (e.g. # fetuses per litter; measured
   before birth)
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Effects on Embryo or Fetus - fetal death
REFERENCE :
   SEIJBO Senten Ijo.  Congenital Anomalies.  (Nippon Senten Ijo Gakkai, c/o
   Kinki Daigaku Igakubu Kaibagaku Kyoshitsu, 380 Nishiyama, Sayama-cho,
   Miram

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - hamster
DOSE                    : 300 mg/kg
SEX/DURATION            : female 11 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   TJADAB Teratology, The International Journal of Abnormal Development. (Alan
   R. Liss, Inc., 41 E. 11th St., New York, NY 10003)  V.1-    1968-
   Volume(issue)/page/year: 23,365,1981

TYPE OF TEST            : TDLo - Lowest published toxic do

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激

其他信息

MSDS 信息:L-2-Azetidinecarboxylic acid(2133-34-8).msds
可燃性危险特性:可燃; 燃烧产生有毒氮氧化物烟雾
Acros Organics:(S)-(-)-2-Azetidinecarboxylic acid, 99+%(2133-34-8)
比旋光度:-125 ° (c=1, water 25 °C)
类别:有毒物品
毒性分级:中毒
Hazard Note:Irritant
储运特性:通风低温干燥
(S)-(-)-2-羧基环丁胺价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 A1043 L-氮杂环丁烷-2-羧酸[L-脯氨酸的拮抗物] L-Azetidine-2-carboxylic Acid [Antagonist of L-Proline] 100MG 727元 2014/06/02 A1043 L-氮杂环丁烷-2-羧酸[L-脯氨酸的拮抗物] L-Azetidine-2-carboxylic Acid [Antagonist of L-Proline] 1G 4160元 2010/06/21 105142500 (S)-(-)-2-羧基环丁胺 (S)-(-)-2-Azetidinecarboxylic acid 99+% 250 MG 1762元
(S)-(-)-2-羧基环丁胺价格(试剂级):更新日期产品编号产品名称包装价格 2011/04/16 A1043 L-氮杂环丁烷-2-羧酸[L-脯氨酸的拮抗物] L-Azetidine-2-carboxylic Acid [Antagonist of L-Proline] 100MG 735元 2011/04/16 A1043 L-氮杂环丁烷-2-羧酸[L-脯氨酸的拮抗物] L-Azetidine-2-carboxylic Acid [Antagonist of L-Proline] 1G 4210元 2010/06/21 105142500 (S)-(-)-2-羧基环丁胺 (S)-(-)-2-Azetidinecarboxylic acid 99+% 250 MG 1762元
灭火剂:干粉,泡沫,沙土,二氧化碳, 雾状水
TCI Shanghai:(S)-(-)-2-羧基环丁胺[L-脯氨酸的拮抗物] L-Azetidine-2-carboxylic Acid [Antagonist of L-Proline],>;98.0%(T)(2133-34-8)
急性毒性:皮下-小鼠 LD50: 1000 毫克/公斤
上游原料:盐酸 --> 乙酸乙酯 --> 甲醇 --> 乙醚 --> 四氢呋喃 --> 二氯甲烷 --> 氧氯化硫 --> 石油醚 --> 碳酸钾 --> 碳酸氢钠 --> 钯 --> 氯化铵 --> 乙腈 --> 二甲基亚砜 --> 叔丁醇钾 --> S-1-苯乙胺 --> 2-溴乙醇 --> 溴乙腈
Alfa Aesar:(S)-(-)-氮杂环丁烷-2-羧酸,99% (S)-(-)-Azetidine-2-carboxylic acid, 99%(2133-34-8)
MOL 文件:2133-34-8.mol
Sigma Aldrich:2133-34-8(sigmaaldrich)