CAS 122-60-1 MFCD00005133-Glycidyl Phenyl Ether 环氧丙基苯基醚 TAO{mole}

Glycidyl Phenyl Ether 环氧丙基苯基醚

CAS 122-60-1 MFCD00005133

化学结构图

SMILES: c1ccc(OCC2CO2)cc1

化学属性

Mol. Formula	C9H10O2
Mol. Weight	150
Refractive index	1.5290 to 1.5320
Boiling Point	245
Density	1.109
Melting Point	3.5
Flash Point	125°C(lit.)
TSCA	Yes
Vapor Density	5.2 (vs air)
Vapor Pressure	0.03 mmHg ( 20 °C)
Solubility	2.4 G/L (20 ºC)

别名和识别编码

Chemical Name	Glycidyl Phenyl Ether
CAS Number	122-60-1
Alfabeta Name	PHENOXYMETHYLOXIRANE 2()-
MDL Number	MFCD00005133
Synonym	(2,3-epoxypropoxy)benzene (±)-Phenyl glycidyl ether 1,2-EPOXYETHYL PHENYL ETHER 1,2-Epoxy-3-phenoxypropane 1,2-Epoxy-3-phenoxypropane, 2,3-Epoxypropylphenylether 1,2-epoxy-3-phenoxy-propan 1,2-epoxy-3-phenoxy-propane 1,2-环氧-3-苯氧基丙烷 1,2-环氧-3-苯氧基丙烷 2,3-环氧丙基苯基醚缩水甘油苯基醚 1-Phenoxy-2,3-epoxypropane 2,3-EPOXYPROPYL PHENYL ETHER 2,3-Epoxypropyl phenyl ether 2,3-环 2,3-环氧丙基苯醚 2-(PHENOXYMETHYL)OXIRANE Ether, 2,3-epoxypropyl phen Ether, phenylglycidyl Glycidylphenylether Oxirane, (phenoxymethyl)-phenol-glycidaether Phenylglycidether phenyl glycide e {} {} {} {} {Chem {} {} {} {} {Chemi {} {} {} {} {uni_hambur 环氧树脂活性稀释剂690 缩水甘油苯基醚苯基缩水甘油醚
PubChem Substance ID	31217
EC Number	204-557-2
Beilstein Registry Number	2744
Reaxys-RN	2744
Chemical Name Translation	环氧丙基苯基醚
Wiswesser Line Notation	T3OTJ B1OR
LabNetwork Molecule ID	LN00158191
InChI	InChI=1S/C9H10O2/c1-2-4-8(5-3-1)10-6-9-7-11-9/h1-5,9H,6-7H2

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安全信息

Warnings IRRITANT 危化品目录(2015) 危险化学品

GHS Symbol

WGK Germany3

Hazard Codes 6.1 T

Hazard statements

H312+H332
H315 Causes skin irritation 会刺激皮肤
H317 May cause an allergic skin reaction 可能导致皮肤过敏
H335 May cause respiratory irritation 可能导致呼吸道刺激
H350 May cause cancer 可能致癌
H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
H318 Causes serious eye damage 严重伤害眼睛
H303 May be harmfully swallowed 吞食可能有害

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSTZ3675000

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P302+P352
P302+P352+P312+P362+P364
P304+P340
P304+P340+P312
P305+P351+P338+P337+P313
P308+P313
P403+P233
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Danger

Risk Statements

R20 Harmful by inhalation 吸入有害
R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
R45 May cause cancer 可能致癌
R52/53
R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险

Safety Statements

S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；

UN Number 2810

Packing GroupIII

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 12 ppm/6H/2Y-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Sense Organs and Special Senses (Olfaction) - tumors
REFERENCE :
   AJPAA4 American Journal of Pathology.  (Lippincott/Harper, Journal
   Fulfillment Dept., 2350 Virginia Ave., Hagerstown, MD 21740)  V.1-    1925-
   Volume(issue)/page/year: 111,140,1983

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >100 ppm/4H
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - acute pulmonary edema
REFERENCE :
   AMIHAB AMA Archives of Industrial Health.  (Chicago, IL)  V.11-21, 1955-60.
   For publisher information, see AEHLAU.  Volume(issue)/page/year: 14,250,1956

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 760 mg/kg
TOXIC EFFECTS :
   Autonomic Nervous System - smooth muscle relaxant (mechanism undefined,
   spasmolytic)
REFERENCE :
   ARZNAD Arzneimittel-Forschung. Drug Research.  (Editio Cantor Verlag,
   Postfach 1255, W-7960 Aulendorf, Fed. Rep. Ger.)  V.1-    1951-
   Volume(issue)/page/year: 15,1355,1965

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3850 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - changes in motor activity (specific assay)
   Behavioral - ataxia
REFERENCE :
   AMIHAB AMA Archives of Industrial Health.  (Chicago, IL)  V.11-21, 1955-60.
   For publisher information, see AEHLAU.  Volume(issue)/page/year: 14,250,1956

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 1500 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine.
   (Chicago, IL)  V.2-10, 1950-54. For publisher information, see AEHLAU.
   Volume(issue)/page/year: 10,61,1954

TYPE OF TEST

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Rodent - hamster Embryo
DOSE/DURATION           : 6250 ug/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 67,9,1979

TYPE OF TEST            : Host-mediated assay
TEST SYSTEM             : Rodent - mouse Bacteria - Salmonella typhimurium
DOSE/DURATION           : 2500 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 67,9,1979

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 300 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 231,205,1990

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 20 umol/L
REFERENCE :
   ARTODN Archives of Toxicology.  (Springer-Verlag, Heidelberger Pl. 3, D-1000
   Berlin 33, Fed. Rep. Ger.)  V.32-    1974-  Volume(issue)/page/year:
   46,277,1980

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 33 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 172,105,1986

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 400 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/pa

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 11 ppm/6H
SEX/DURATION            : male 19 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Fertility - male fertility index (e.g. # males impregnating
   females per # males exposed to fertile nonpregnant females)
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   64,204,1982

其他信息

毒性分级:中毒
用途一:用作有机合成中间体。
方法一:由苯酚、环氧氯丙烷在氢氧化钠存在下缩合而得。将苯酚、氢氧化钠、混合搅拌至全部溶解，冷却至5-6℃，缓缓加入环氧氯丙烷。加毕，于25℃搅拌45h，反应物用乙醚提取，提取液加无水碳酸钾干燥，过滤。滤液回收乙醚，经减压蒸馏，收集120-123℃（1.46kPa）馏分即为环氧丙基苯基醚。
海关编码:29109000
蒸气密度:5.2 (vs air)
类别:有毒物品
职业标准:TWA 6 毫克/ 立方米; STEL 60 毫克/ 立方米
储运特性:库房通风低温干燥; 与食品、氧化剂分开储运
TCI Shanghai:环氧丙基苯基醚 Glycidyl Phenyl Ether,>;99.0%(GC)(122-60-1)
Acros Organics:苯基缩水甘油醚 Glycidyl phenyl ether, 99%(122-60-1)
MOL 文件:122-60-1.mol
爆炸物危险特性:可形成过氧化物；后者可爆
MSDS 信息:苯缩水甘油醚(122-60-1).msds
Sigma Aldrich:122-60-1(sigmaaldrich)
苯基缩水甘油醚价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 G0098 环氧丙基苯基醚 Glycidyl Phenyl Ether 25G 224元 2014/06/02 G0098 环氧丙基苯基醚 Glycidyl Phenyl Ether 500G 583元 2010/06/21 135352500 苯基缩水甘油醚 Glycidyl phenyl ether 99% 250 GR 914元
可燃性危险特性:明火可燃; 遇热放出有毒蒸气
急性毒性:口服-大鼠 LD50: 3850 毫克/ 公斤; 口服- 小鼠 LD50: 1400 毫克/ 公斤
上游原料:碳酸钾 --> 环氧氯丙烷
灭火剂:泡沫、干粉、二氧化碳、雾状水
Alfa Aesar:缩水甘油基苯基醚,99% Glycidyl phenyl ether, 99%(122-60-1)
外观性质:无色液体。
图谱信息:苯基缩水甘油醚(122-60-1)质谱(MS)
蒸气压:0.03 mm Hg ( 20 °C)
刺激数据:皮肤-兔子 10 毫克/ 24小时重度; 眼睛-兔子 111 毫克轻度