CAS 3132-64-7 MFCD00005130-Epibromohydrin 环氧溴丙烷 TAO{mole}

Epibromohydrin 环氧溴丙烷

CAS 3132-64-7 MFCD00005130

化学结构图

SMILES: BrCC1CO1

化学属性

Mol. Formula	C3H5BrO
Mol. Weight	136.98
Refractive index	1.4790 to 1.4840
Boiling Point
Density	1.601
Melting Point	N/A
Stability	对光敏感
Flash Point	-
Solubility	不溶于水，溶于热乙醇、乙醚、苯、氯仿。

别名和识别编码

Chemical Name	Epibromhydrin
CAS Number	3132-64-7
Synonym	######## (±)-(Brommethyl)oxiran (±)-(Bromomethyl)oxirane (±)-3-Bromo-1,2-epoxypropane (±)-Epibromohydrin 1,2-Epoxy-3-bromopropane 1,2-環氧-3-溴丙烷 1-bromo-2,3-epoxy-propan 1-bromo-2,3-epoxy-propane 2-(Bromomethyl)oxirane 3-BROMOPROPYLENE OXIDE 3-Bromopropylene oxide 3-bromo-1,2-epoxy-propan 3-溴-1,2-环氧丙烷 BROMOMETHYLOXIRANE Epibromhydrin Epibromohydrin {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID	18430
EC Number	221-525-3
Beilstein Registry Number	79786
MDL Number	-
Reaxys-RN	79786
Chemical Name Translation	环氧溴丙烷
Wiswesser Line Notation	T3OTJ B1E
LabNetwork Molecule ID	LN00239728
InChI	InChI=1S/C3H5BrO/c4-1-3-2-5-3/h3H,1-2H2
Canonical SMILES	-

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品牌质保精细包装现货库存一流品牌服务

产品应用

Bromohydrin pyrophosphate enhances antibody-dependent cell-mediated cytotoxicity induced by therapeutic antibodies.

安全信息

GHS Symbol

WGK Germany2

Hazard Codes 6.1 Xn

Hazard statements

H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
H226 Flammable liquid and vapour 易燃液体和蒸气
H302 Harmful if swallowed 吞食有害
H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激
H351 Suspected of causing cancer 怀疑致癌

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSTX4115000

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
P203
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P233 Keep container tightly closed. ?保持容器密闭。
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
P242 Use only non-sparking tools. 只能使用无火花工具。
P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P264+P265
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P281 Use personal protective equipment as required. 使用所需的个人防护装备。
P301+P310
P301+P312
P301+P316
P301+P317
P302+P352
P303+P361+P353
P304+P340
P305+P351+P338
P305+P351+P338+P337+
P308+P313
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P316
P318
P319
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
P330 Rinse mouth. 漱口
P332+P313
P332+P317
P337+P313
P337+P317
P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
P361+P364
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P362+P364
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P370+P378
P403+P233
P403+P235
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Warning {} {} {} {} {} {} {} {} {TCI}

UN Number 2558

Storage condition +4°C 2-8°C 4 4°C 4°C, Inert atmosphere 密封避光保存

Packing GroupI

Hazard Class6.1/3

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；

Risk Statements

R22 Harmful if swallowed 吞咽有害
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用

Warnings 危化品目录(2015)

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 300 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ARZNAD Arzneimittel-Forschung. Drug Research.  (Editio Cantor Verlag,
   Postfach 1255, W-7960 Aulendorf, Fed. Rep. Ger.)  V.1-    1951-
   Volume(issue)/page/year: 17,145,1967

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 50 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 249,55,1991

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 1 mmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 231,205,1990

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 20 umol/L
REFERENCE :
   ARTODN Archives of Toxicology.  (Springer-Verlag, Heidelberger Pl. 3, D-1000
   Berlin 33, Fed. Rep. Ger.)  V.32-    1974-  Volume(issue)/page/year:
   46,277,1980

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 10 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 172,105,1986

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Klebsiella pneumoniae
DOSE/DURATION           : 100 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 89,269,1981

TYPE OF TEST            : DNA inhibition
TEST SYSTEM             : Human HeLa cell
DOSE/DURATION           : 1500 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 92,427,1982

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Restrict 危险品

其他信息

方法一:将1000ml1，3-二溴-2-丙醇和1500ml水混匀，分次加入400g氢氧化钙（88%），边加边搅拌。然后再一次加入400g氢氧化钙，减压蒸出环氧溴丙烷，馏出物经无水硫酸钠干燥，蒸馏，收集134-136℃馏分为成品，得1130-1200g，收率84-89%。
储运特性:包装完整、轻装轻放; 库房通风、远离明火、高温、与氧化剂分开存放
TCI Shanghai:环氧溴丙烷 Epibromohydrin,>;97.0%(GC)(3132-64-7)
毒性分级:高毒
外观性质:无色或淡黄色透明液体, 易挥发。
环氧溴丙烷价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 E0011 环氧溴丙烷 Epibromohydrin 500G 824元 2014/06/02 E0011 环氧溴丙烷 Epibromohydrin 25G 291元
可燃性危险特性:遇明火、高温、强氧化剂易燃; 受热分解有毒溴化氢气体
用途二:有机合成中间体，溶剂。
灭火剂:泡沫、二氧化碳、干粉、砂土、1211
MSDS 信息:环氧溴丙烷(3132-64-7).msds
图谱信息:环氧溴丙烷(3132-64-7)红外图谱(IR1) 环氧溴丙烷(3132-64-7)质谱(MS) 环氧溴丙烷(3132-64-7)核磁图( 13 CNMR) 环氧溴丙烷(3132-64-7)Raman光谱环氧溴丙烷(3132-64-7)红外图谱(IR2) 环氧溴丙烷(3132-64-7)核磁图( 1 HNMR)
MOL 文件:3132-64-7.mol
上游原料:二溴
急性毒性:腹腔- 大鼠 LD50: 300 毫克/ 公斤
类别:易燃液体
Sigma Aldrich:3132-64-7(sigmaaldrich)
用途一:用作有机合成中间体