3,6-Dibromocarbazole 3,6-二溴咔唑

CAS 6825-20-3 MFCD00004961

化学结构图

6825-20-3
SMILES: Brc1ccc2[nH]c3ccc(Br)cc3c2c1

化学属性

Mol. FormulaC12H7Br2N
Mol. Weight325.00
Melting Point204-206°C
TSCANo
Density1.93
Boiling Point459°C at 760 mmHg

别名和识别编码

Chemical Name3,6-Dibromocarbazole
CAS Number6825-20-3
Alfabeta NameDIBROMOCARBAZOLE H369---,
MDL NumberMFCD00004961
PubChem Substance ID274874
Reaxys-RN170481
Beilstein Registry Number20,439
Synonym 3,6-Dibromocarbazole {LY} 3,6-Dibromocarbazole {} {LY} 3,6-Dibromocarbazole {} {} {LY} 3,6-Dibromocarbazole {} {} {} {LY} 3,6-Dibromocarbazole {} {} {} {} {LY} 3,6-Dibromocarbazole {} {} {} {} {} {} {} {} {} {} {LY} 3,6-Dibromocarbazole {} {} {} {} {} {} {LY} 3,6-Dibromocarbazole {} {} {} {} {} {} {} {LY} 3,6-Dibromocarbazole {} {} {} {} {} {} {} {} {LY} 3,6-Dibromocarbazole {} {} {} {} {} {} {} {} {} {LY} 3,6-Dibromocarbazole {} {} {} {} {} {} {} {} {} {} {LY} 3,6-Dibromocarbazole {} {} {} {} {} {} {} {} {} {} {} {LY} 3,6-Dibromocarbazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3,6-Dibromocarbazole {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3,6-Dibromocarbazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3,6-Dibromocarbazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3,6-Dibromocarbazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
EC Number250-023-7
Chemical Name Translation3,6-二溴咔唑
LabNetwork Molecule IDLN00176941
InChIInChI=1S/C12H7Br2N/c13-7-1-3-11-9(5-7)10-6-8(14)2-4-12(10)15-11/h1-6,15H
Canonical SMILESBrC1=CC(C2=C3C=CC(Br)=C2)=C(N3)C=C1
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分类

  • {SNA} Building Blocks, Carbazoles, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks
  • Building Blocks, Carbazoles, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks
  • {uni_hamburg} no charge; nitrogen heterocycle; carbocycle; aromatic; large ring; fused rings; 5ring; 6ring; 9ring; 13ring; 1fragment

相关文献及参考

  • Short: III/35C3
  • Beilstein:20,439

安全信息

Warnings IRRITANT
WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • Sigma Aldrich:6825-20-3(sigmaaldrich)
  • 硅胶法:3,6-二溴咔唑是一种重要的医药中间体,可以通过N-溴代丁二酰亚胺法、液溴法和硅胶法三种方法进行合成,但目前主要通过硅胶法进行合成,合成使用的主要原料包括咔唑、N-溴代丁二酰亚胺、溶剂二氯甲烷、催化剂硅胶,产率可达89.5%。
  • 图谱信息:3,6-二溴咔唑(6825-20-3)红外图谱(IR1) 3,6-二溴咔唑(6825-20-3)质谱(MS)
  • TCI Shanghai:3,6-二溴咔唑 3,6-Dibromocarbazole,>;98.0%(GC)(6825-20-3)
  • MOL 文件:6825-20-3.mol
  • 3,6-二溴咔唑价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D2983 3,6-二溴咔唑 3,6-Dibromocarbazole 5G 861元 2014/06/02 D2983 3,6-二溴咔唑 3,6-Dibromocarbazole 25G 2610元 2014/06/02 D2983 3,6-二溴咔唑 3,6-Dibromocarbazole 1G 284元

系列性分类


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