Triphenylphosphine sulfide 三苯基膦硫
CAS 3878-45-3 MFCD00004917
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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分类
- {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
- {SA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Phosphorus Compounds, Synthetic Reagents
- {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Phosphorus Compounds, Synthetic Reagents
相关文献及参考
- Short: III/35D2
- In the presence of TFA, converts epoxides to episulfides (thiiranes) of the same stereochemistry: J. Am. Chem. Soc., 94, 2880 (1972).
- The Pd-catalyzed bisalkoxycarbonylation of olefins gives improved yields in the presence of triphenylphosphine sulfide as a ligand. The phosphine oxide and selenide were significantly less effective, and no product was obtained with triphenylphosphine itself: Tetrahedron Lett, 39, 7529 (1998):
安全信息
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P264+P265
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P312+P330
- P301+P317
- P302+P352
- P302+P352+P312+P362+P364
- P304+P340
- P305+P351+P338
- P305+P351+P338+P337+P313
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
- P317
- P319
- P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
- P330 Rinse mouth. 漱口
- P332+P313
- P332+P317
- P337+P317
- P362+P364
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
GHS Symbol

- H302 Harmful if swallowed 吞食有害
- H302+H312
- H312 Harmful in contact with skin 皮肤接触有害
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 180 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#05727
其他信息
- Acros Organics:三苯基瞵硫 Triphenylphosphine sulfide, 99+%(3878-45-3)
- Sigma Aldrich:3878-45-3(sigmaaldrich)
- MOL 文件:3878-45-3.mol
- TCI Shanghai:三苯基膦硫 Triphenylphosphine Sulfide,>;99.0%(GC)(3878-45-3)
- Alfa Aesar:三苯基硫化膦,98% Triphenylphosphine sulfide, 98%(3878-45-3)
- 三苯基瞵硫价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1066 三苯基膦硫 Triphenylphosphine Sulfide 500G 2470元 2014/06/02 T1066 三苯基膦硫 Triphenylphosphine Sulfide 25G 305元 2010/06/21 159030100 三苯基瞵硫 Triphenylphosphine sulfide 99+% 10 GR 555元