CAS 3688-92-4 MFCD00003888-Thorin 吐啉 TAO{mole}

Thorin 吐啉

CAS 3688-92-4 MFCD00003888

化学结构图

SMILES: O=S(=O)(O)c1ccc2c(/N=N/c3ccccc3[As](=O)(O)O)c(O)c(S(=O)(=O)O)cc2c1.[NaH]

化学属性

Mol. Formula	C16H11AsN2Na2O10S2
Mol. Weight	576.30
Melting Point	>300 °C
TSCA	Yes
Stability	对湿度敏感

别名和识别编码

Chemical Name	Thorin
MDL Number	MFCD00003888
CAS Number	3688-92-4
Synonym	Thorin, IND {LY} Thorin, IND thorin thoron (reagent) {} {LY} Thorin, IND {} {} {LY} Thorin, IND {} {} {} {LY} Thorin, IND {} {} {} {} {LY} Thorin, IND {} {} {} {} {} {LY} Thorin, IND {} {} {} {} {} {} {LY} Thorin, IND {} {} {} {} {} {} {} {LY} Thorin, IND {} {} {} {} {} {} {} {} {LY} Thorin, IND {} {} {} {} {} {} {} {} {} {LY} Thorin, IND {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Thorin, IND {} {} {} {} {} {} {} {} {} {} {} {LY} Thorin, IND {} {} {} {} {} {} {} {} {} {} {} {} {LY} Thorin, IND {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Thorin, IND {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Thorin, IND {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Thorin, IND {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Thorin, IND {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID	77269
Beilstein Registry Number	16(3)1143
EC Number	222-993-1
Chemical Name Translation	吐啉
InChIKey	DCSRPHQBFSYJNN-BUFQOAPZSA-L
LabNetwork Molecule ID	LN01742504
Canonical SMILES	O=S(C1=C(O)C(/N=N/C2=CC=CC=C2[As](O)(O)=O)=C3C=CC(S(=O)(O[Na])=O)=CC3=C1)(O[Na])=O
InChI	InChI=1S/C16H13AsN2O10S2.2Na/c20-16-14(31(27,28)29)8-9-7-10(30(24,25)26)5-6-11(9)15(16)19-18-13-4-2-1-3-12(13)17(21,22)23;;/h1-8,20H,(H2,21,22,23)(H,24,25,26)(H,27,28,29);;/q;2*+1/p-2

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产品应用

检定和测定钍、铪、钽、钛、铀和锆。比色测定和分光测定氟离子、铪、锂、盥、稀土金属、钌、锆和钍。用高氯酸钡滴定有机硫化物和硫酸盐时的指示剂。

安全信息

Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

GHS Symbol

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P273 Avoid release to the environment. 避免释放到环境中。
P301+P310
P301+P310+P330
P301+P316
P304+P340
P304+P340+P311
P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
P316
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P330 Rinse mouth. 漱口
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P403+P233
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H301 Toxic if swallowed 吞食有毒
H301+H331
H331 Toxic if inhaled 吸入中毒
H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。

Signal word Danger

Safety Statements

S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
S20/21 When using do not eat, drink or smoke 使用时，不得进食，饮水或吸烟；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；

Packing GroupII

UN Number UN3465 3465 UN 3465 6.1/PG 3

Risk Statements

R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
R50/53

WGK Germany3

Hazard Codes T,N

Hazard Class6.1

Storage condition 2-8°C, stored under nitrogen, away from moisture {LY} 2-8°C, stored under nitrogen, away from moisture {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {} {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {} {} {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen, away from mois

其他信息

MOL 文件:3688-92-4.mol
用途一:检定和测定钍、铪、钽、钛、铀和锆。比色测定和分光测定氟离子、铪、锂、盥、稀土金属、钌、锆和钍。用高氯酸钡滴定有机硫化物和硫酸盐时的指示剂。
外观性质:鲜红色结晶。易溶于水，不溶于有机溶剂。
TCI Shanghai:钍试剂水合物[用于钍等的测定] Thorin Hydrate [for Determination of Th, etc.],>;90.0%(T)(3688-92-4)
Acros Organics:钍指示剂 Thorin I, indicator grade, pure(3688-92-4)
Alfa Aesar:1-(2-胂酸苯偶氮)-2-萘酚-3,6-二磺酸二钠盐 Thorin(3688-92-4)
图谱信息:吐啉(3688-92-4)红外图谱(IR1) 吐啉(3688-92-4)红外图谱(IR2)
Sigma Aldrich:3688-92-4(sigmaaldrich)
易溶于水，不溶于有机溶剂。
吐啉价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 L1029701 钍试剂;1-(2-胂酸苯偶氮)-2-萘酚-3,6-二磺酸二钠盐;2-(2-羟基-3,6-二磺酸-1-萘基偶氮)苯砷酸二钠盐 5g 410元 2011/04/16 H0240 钍试剂水合物[用于钍等的测定] Thorin Hydrate [for Determination of Th, etc.] 25G 3480元 2011/04/16 H0240 钍试剂水合物[用于钍等的测定] Thorin Hydrate [for Determination of Th, etc.] 1G 343元