CAS 90-11-9 MFCD00003868-1-Bromonaphthalene 1-溴萘 TAO{mole}

1-Bromonaphthalene 1-溴萘

CAS 90-11-9 MFCD00003868

化学结构图

SMILES: Brc1cccc2ccccc12

化学属性

Mol. Formula	C10H7Br
Mol. Weight	207.07
Density	1.48
Refractive index	1.6550 to 1.6600
Boiling Point	133-134°C at 760 mmHg
Melting Point	-2--1°C
Flash Point	110°C
TSCA	Yes
Solubility	略溶于水
Stability	对光敏感
Appearance	无色或微黄色液体。不溶于水，能与醇、醚、苯和氯仿混溶。
pH	:A

别名和识别编码

Chemical Name	1-Bromonaphthalene
CAS Number	90-11-9
EC Number	201-965-2
Beilstein Registry Number	5,547
MDL Number	MFCD00003868
Synonym	1-Bromonaphthalene {LY} 1-Bromonaphthalene {} {LY} 1-Bromonaphthalene {} {} {LY} 1-Bromonaphthalene {} {} {} {LY} 1-Bromonaphthalene {} {} {} {} {LY} 1-Bromonaphthalene {} {} {} {} {} {LY} 1-Bromonaphthalene {} {} {} {} {} {} { {} {} {} {} {} {} {LY} 1-Bromonaphthalene {} {} {} {} {} {} {} {LY} 1-Bromonaphthalene {} {} {} {} {} {} {} {} {LY} 1-Bromonaphthalene {} {} {} {} {} {} {} {} {} {LY} 1-Bromonaphthalene {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromonaphthalene {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromonaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromonaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromonaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromonaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromonaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromonaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID	87563626
Merck Number	1425
Chemical Name Translation	1-溴萘
Reaxys-RN	1906414
Wiswesser Line Notation	L66J BE
LabNetwork Molecule ID	LN00195982
InChI	InChI=1S/C10H7Br/c11-10-7-3-5-8-4-1-2-6-9(8)10/h1-7H
Canonical SMILES	BrC1=C2C=CC=CC2=CC=C1

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产品应用

有机合成原料，分析试剂，用作冷冻剂以及分子量大的物质的溶剂。也是干燥物品的热载体。亦可用于折射率测定。

安全信息

Signal word

GHS Symbol

WGK Germany3

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36 Wear suitable protective clothing 穿戴适当的防护服；

Risk Statements

R36 Irritating to eyes 刺激眼睛
R22 Harmful if swallowed 吞咽有害
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Precautionary statements

P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P312+P330
P305+P351+P338
P305+P351+P338+P337+P313
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H302 Harmful if swallowed 吞食有害
H319 Causes serious eye irritation 严重刺激眼睛

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSQJ1545000

Hazard Codes Xn Xn,Xi

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

Packing GroupIII

Hazard Class6.1(b)

UN Number 2810

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 810 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 20(12),52,1976

其他信息

MSDS 信息:alpha-Bromonaphthalene(90-11-9).msds
检测方法:GC
急性毒性:腹腔- 小鼠 LD50: 810 毫克/ 公斤
图谱信息:1-溴化萘(90-11-9)核磁图( 1 HNMR) 1-溴化萘(90-11-9)Raman光谱 1-溴化萘(90-11-9)质谱(MS) 1-溴化萘(90-11-9)红外图谱(IR2) 1-溴化萘(90-11-9)红外图谱(IR1) 1-溴化萘(90-11-9)核磁图( 13 CNMR)
用途一:用作有机合成原料，用作冷冻剂以及分子量大的物质的溶剂，也是干燥物品的热载体
用途二:用于折光率的测定、染料及有机化合物的合成，也用作干燥物的传热介质
上游原料:溴 --> 四氯化碳
毒性分级:中毒
MOL 文件:90-11-9.mol
类别:易燃液体
灭火剂:干粉、泡沫、砂土、水
海关编码:29036990
Acros Organics:1-溴萘 1-Bromonaphthalene, 96%(90-11-9)
储运特性:库房通风低温干燥
Sigma Aldrich:90-11-9(sigmaaldrich)
下游产品:N,N'-二苯基-N,N'-(1-萘基)-1,1'-联苯-4,4'-二胺 --> 1-萘甲酸 --> 1-奈硫酚 --> 1-萘硼酸 --> 1-萘甲腈
TCI Shanghai:1-溴萘 1-Bromonaphthalene,>;95.0%(GC)(90-11-9)
蒸馏后能保持无色，但久置后变黑色。能与醇、醚、四氯化碳相混溶，微溶于水。能随水蒸汽挥发。
color:slightly yellow to deep brownish-yellow
Alfa Aesar:1-溴萘,97% 1-Bromonaphthalene, 97%(90-11-9)
F:8
方法一:由萘与溴反应而得。在反应锅中加入四氯化碳和萘，搅拌加热，在45℃慢慢加入溴素。加完后于70-80℃保温反应3-4h。蒸馏回收四氯化碳，将反应物洗涤、减压蒸馏、再洗涤、过滤、干燥而得成品。
用途三:有机合成原料，分析试剂，用作冷冻剂以及分子量大的物质的溶剂。也是干燥物品的热载体。亦可用于折射率测定。
可燃性危险特性:易燃; 燃烧产生有毒溴化物气体
1-溴化萘价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 30027428 1-溴代萘 500ml 178元 2011/04/16 B0618 1-溴萘 1-Bromonaphthalene 500G 1140元 2011/04/16 B0618 1-溴萘 1-Bromonaphthalene 25G 153元