CAS 100-60-7 MFCD00003832-N-Methylcyclohexylamine N-甲基环己胺 TAO{mole}

N-Methylcyclohexylamine N-甲基环己胺

CAS 100-60-7 MFCD00003832

化学结构图

SMILES: CNc1ccccc1

化学属性

Mol. Formula	C7H15N
Mol. Weight	113
Density	0.868
Refractive index	1.4550 to 1.4580
Flash Point	29°C(lit.)
TSCA	Yes
Boiling Point	149
Melting Point	-9 - -7
Vapor Density	4 (vs air)
Vapor Pressure	11 mmHg ( 40 °C)
Solubility	5.4 G/100 ML (20 ºC)
Stability	对空气敏感
Appearance	无色透明液体。与多种有机溶剂混溶，微溶于水。

别名和识别编码

Chemical Name	N-Methylcyclohexylamine
CAS Number	100-60-7
EC Number	202-869-3
Beilstein Registry Number	1523664
MDL Number	MFCD00003832
Synonym	Cyclohexanamine, N-methyl- Cyclohexanamine,N-methyl- Cyclohexylamine, N-methyl- METHYLAMINOCYCLOHEXANE Methylcyclohexylamine N-CYCLOHEXYLMETHYLAMINE N-Cyclohexyl-N-methylamine N-Cyclohexylmethylamine N-METHYLCYCLOHEXYLAMINE N-Methyl-N-cyclohexylamine N-Methylcyclohexanamine N-Methylcyclohexylamine N-methyl-Cyclohexanamine N-环己基甲胺 N-环己基甲胺; N-环己基甲胺;N-甲环己胺 N-甲基环己胺 N-甲環己胺 cyclohexyl(methyl)amine cyclohexyl-methyl-amine methyla methylcyclohexylamine,[corrosivelabel] methylcyclohexylamine,[flammableliquidandcorrosivelabels] methylcyclohexylamine,[flammableliquidlabel] n-methyl-cyclohexanamin n-methyl-cyclohexylamin
PubChem Substance ID	87572293
Chemical Name Translation	N-甲基环己胺
Reaxys-RN	1523664
LabNetwork Molecule ID	LN00221427
InChI	InChI=1S/C7H15N/c1-8-7-5-3-2-4-6-7/h7-8H,2-6H2,1H3

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安全信息

Signal word Danger

GHS Symbol

WGK Germany1

Safety Statements

S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；

Risk Statements

R10 Flammable 易燃
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
R34 Causes burns 会导致灼伤
R35 Causes severe burns 会导致严重灼伤

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P233 Keep container tightly closed. ?保持容器密闭。
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P241+P242+P243
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P330+P331+P310
P303+P361+P353
P303+P361+P353+P310+P363
P304+P340+P310
P305+P351+P338
P305+P351+P338+P310
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P370+P378
P403+P235
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

RTECSGX1529000

Packing GroupII

UN Number 2734 UN 2734 8/PG 2

Storage condition Flammables area 充氩保存 Air Sensitive

Hazard statements

H226 Flammable liquid and vapour 易燃液体和蒸气
H302 Harmful if swallowed 吞食有害
H302+H312
H312 Harmful in contact with skin 皮肤接触有害
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H331 Toxic if inhaled 吸入中毒

Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Hazard Codes 8 C

Hazard Class8/3

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 2 gm/kg
TOXIC EFFECTS :
   Skin and Appendages - corrosive (after topical exposure)
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,388,1969

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 7000 mg/m3/1H
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - lacrimation
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,388,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 400 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - tremor
   Behavioral - ataxia
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,388,1969

其他信息

TCI Shanghai:N-甲基环己胺 N-Methylcyclohexylamine,>;99.0%(T)(100-60-7)
下游产品:盐酸溴己新
上游原料:环己酮 --> 铝 --> 环己胺 --> 氯化汞
Sigma Aldrich:100-60-7(sigmaaldrich)
敏感性:Air Sensitive
蒸气密度:4 (vs air)
用途一:用作医药及染料的中间体
蒸气压:11 mm Hg ( 40 °C)
用途二:药物及染料中间体。用作药物盐酸溴已胺的中间体。
Hazard Note:Corrosive
方法一:1.以环己胺为原料制得。2.由环己酮与甲胺反应而得。将铝片浸泡在甲醇中，再加氯化高汞，继续浸泡2h，升温不超过55℃，除去浸泡液。向上述活化好的铝片加乙醇，在搅拌下滴加甲胺、环己酮的混合液，加热回流，放置过夜。加入10%氢氧化钠溶液碱化，用苯提取两次，经水洗后进行蒸馏，回收苯后即馏出N-甲基环己胺。收率约80%。
MSDS 信息:N-Cyclohexylmethylamine(100-60-7).msds
海关编码:29213099
Acros Organics:N-甲基环己胺 N-Methylcyclohexylamine, 98%(100-60-7)
MOL 文件:100-60-7.mol
N-甲基环己胺价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 M0202 N-甲基环己胺 N-Methylcyclohexylamine 500G 953元 2014/06/02 M0202 N-甲基环己胺 N-Methylcyclohexylamine 25G 196元 2010/06/21 146990050 N-甲基环己胺 N-Methylcyclohexylamine 98% 5 ML 278元
图谱信息:N-甲基环己胺(100-60-7)核磁图( 1 HNMR) N-甲基环己胺(100-60-7)质谱(MS) N-甲基环己胺(100-60-7)核磁图( 13 CNMR) N-甲基环己胺(100-60-7)红外图谱(IR1)
Alfa Aesar:N-甲基环己胺,98% N-Methylcyclohexylamine, 98%(100-60-7)