CAS 7775-41-9 MFCD00003410-Silver fluoride 氟化银 TAO{mole}

Silver fluoride 氟化银

CAS 7775-41-9 MFCD00003410

化学结构图

SMILES: F[Ag]

化学属性

Mol. Formula	AgF
Mol. Weight	126.87
Boiling Point	1150 °C at 760 mmHg
TSCA	T
Melting Point	≥300°C
Density	5.85
Solubility	Soluble in HF, ammonia, CH3CN
Flash Point	1150°C
Appearance	它是黄棕色固体，熔点435℃，暴露于潮湿空气时变黑。与其他卤化银不同，氟化银可溶于水，溶解度为1.8 kg/L[1]，也可溶于乙腈。Ag-F键长:246pm,小于其它卤化银．共价半径为246pm，与Ag-F键长相同，应区别于其它卤化银．键型为离子键，也与其它卤化银相异．晶格类型类似于氯化钠，与氯化银／溴化银相同（碘化银晶格类型类似于硫化锌．）（其它卤化银均有共价键倾向：氯化银／溴化银的键型为过渡键，碘化银键型为共价键）

别名和识别编码

Chemical Name	Silver fluoride
CAS Number	7775-41-9
Alfabeta Name	SILVERFLUORIDE I()
MDL Number	MFCD00003410
EC Number	231-895-8
PubChem Substance ID	165912
Synonym	Silver(I) fluoride {LY} Silver(I) fluoride {} {LY} Silver(I) fluoride {} {} {LY} Silver(I) fluoride {} {} {} {LY} Silver(I) fluoride {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} { {} {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {} {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {} {} {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver(I) fluoride {} {} {} {} {} {} {} {} {} {} {}
Merck Number	14,8514
Beilstein Registry Number	2384789
Chemical Name Translation	氟化银
LabNetwork Molecule ID	LN00117348
InChI	InChI=1S/Ag.FH/h;1H/q+1;/p-1
Canonical SMILES	[Ag]F

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产品应用

用于由大位阻的三烷基甲硅烷基乙炔制备溴乙炔.也用于乙酰苯胺与三烷氧基硅烷的钯催化交叉偶联反应.

安全信息

Warnings HYGROSCOPIC, CORROSIVE

GHS Symbol

WGK Germany3

Hazard Codes 8 C

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H318 Causes serious eye damage 严重伤害眼睛
H301+H311+H331
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤

Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

RTECSVW4250000

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P310
P303+P361+P353
P304+P340+P310
P305+P351+P338
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。

Signal word Danger

Safety Statements

S25 Avoid contact with eyes 避免眼睛接触；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；

UN Number 3260

Risk Statements

R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
R34 Causes burns 会导致灼伤
R35 Causes severe burns 会导致严重灼伤
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Light & Moisture Sensitive & Hygroscopic {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {

Packing GroupII

其他信息

敏感性:Moisture Sensitive & Hygroscopic
F:3-8-10-21
Sigma Aldrich:7775-41-9(sigmaaldrich)
Alfa Aesar:氟化银,98% Silver(I) fluoride, 98%(7775-41-9)
TSCA:T
Acros Organics:氟化银 Silver(I) fluoride, 99+%(7775-41-9)
储运特性:库房低温通风干燥; 与氧化剂分开存放
MSDS 信息:Silver monofluoride(7775-41-9).msds
可燃性危险特性:不燃; 火场释放含银和氟化物烟雾
毒性分级:高毒
水中溶解度(g/100ml):不同温度(℃)时每100毫升水中的溶解克数: 85.9g/0℃;120g/10℃;172g/20℃;190g/30℃;203g/40℃
类别:腐蚀物质
Hazard Note:Corrosive
灭火剂:水, 干粉, 二氧化碳, 泡沫
MOL 文件:7775-41-9.mol
氟化银价格(试剂级):更新日期产品编号产品名称包装价格 2010/06/21 210450250 氟化银 Silver(I) fluoride 99+% 25 GR 4105元 2010/06/21 210450050 氟化银 Silver(I) fluoride 99+% 5 GR 1183元 2010/05/25 11609 氟化银, 98% Silver(I) fluoride, 98% 5g 620元
职业标准:TWA 0.01 毫克/立方米; STEL 0.03 毫克/立方米