CAS 79-09-4 MFCD00002756-Propionic acid 丙酸g TAO{mole}

Propionic acid 丙酸g

CAS 79-09-4 MFCD00002756

化学结构图

SMILES: CCC(=O)O

化学属性

Mol. Formula	C3H6O2
Mol. Weight	74.08
Density	0.99
Autoignition Point	955 °F
Refractive index	1.3850 to 1.3880
Vapor Density	2.55 (vs air)
Boiling Point	141
Vapor Pressure	2.4 mmHg ( 20 °C)
Melting Point	-22
Flash Point	51.67°C
TSCA	Yes
Solubility	995 G/L (20 ºC)
Stability	对湿度敏感

别名和识别编码

Chemical Name	Propionic acid
Synonym	Propanoic acid {LY} Propanoic acid Propanoic acid Propanyl acid 初油酸 Propanyl acid Propionic acid grain preserver Pseudoacetic acid RARECHEM AL BO 0158 Sentry grain preserver acidepropionique acidepropionique[french] {} {LY} Propanoic acid {} {} {LY} Propanoic acid {} {} {} {LY} Propanoic acid {} {} {} {} {LY} Propanoic acid {} {} {} {} {} {} {} {} {} {} {LY} Propanoic acid {} {} {} {} {} {} {LY} Propanoic acid {} {} {} {} {} {} {} {LY} Propanoic acid {} {} {} {} {} {} {} {} {LY} Propanoic acid {} {} {} {} {} {} {} {} {} {LY} Propanoic acid {} {} {} {} {} {} {} {} {} {} {LY} Propanoic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Propanoic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Propanoic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Propanoic acid {} {} {} {} {} {} {} {} {} {}
MDL Number	MFCD00002756
CAS Number	79-09-4
EC Number	201-176-3
Beilstein Registry Number	506071
PubChem Substance ID	1032
Merck Number	7825
Chemical Name Translation	丙酸g
Reaxys-RN	506071
Wiswesser Line Notation	QV2
LabNetwork Molecule ID	LN00195950
InChI	InChI=1S/C3H6O2/c1-2-3(4)5/h2H2,1H3,(H,4,5)
Canonical SMILES	OC(CC)=O

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

产品应用

测定芳香族二胺类，气相色谱分析标准。
昆虫细胞培养级用于昆虫细胞培养中抑制霉菌的生长。

安全信息

Signal word Danger

GHS Symbol

WGK Germany1

Safety Statements

S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36 Wear suitable protective clothing 穿戴适当的防护服；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；

Risk Statements

R34 Causes burns 会导致灼伤

Precautionary statements

P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P303+P361+P353
P304+P340+P310
P305+P351+P338
P305+P351+P338+P310
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P370+P378
P403+P233
P403+P235
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H226 Flammable liquid and vapour 易燃液体和蒸气
H335 May cause respiratory irritation 可能导致呼吸道刺激

Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSUE5950000

Packing GroupII

UN Number 3463 UN3463

Hazard Codes 8 C Xn

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

Hazard Class8/3

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Parenteral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de
   Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France)
   V.1-  1947-  Volume(issue)/page/year: 26,5,1972

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1510 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - excitement
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 35(3),96,1970

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 625 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   APTOA6 Acta Pharmacologica et Toxicologica.  (Copenhagen, Denmark)  V.1-59,
   1945-86.  For publisher information, see PHTOEH  Volume(issue)/pa

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1370 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - excitement
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 35(3),96,1970

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 2500 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 279,75,1992

Warnings 危化品目录(2015) 危险化学品

其他信息

上游原料:氧 --> 一氧化碳 --> 石蜡 --> 醋酸铜 --> 丙醛 --> 环己基氨基磺酸钠 --> 环烷酸钴 --> 羰基镍 --> 环烷酸锰
所属类别三:饲料添加剂: 饲料贮存添加剂
方法二:其制备方法是以乙烯与一氧化碳、氢气为原料，在环烷酸钴等催化剂存在下，于100～200℃、20～30 MPa条件下在极性溶剂中反应生成丙醛，进一步经空气或氧气氧化，催化剂用环烷酸钴、环烷酸锰、乙酸铜等，反应温度为60℃，常压氧化反应而制得丙酸，丙醛的转化率为95％～98％。反应方程式：CH 2 ＝CH 2 +CO+H 2 →CH 3 CH 2 CHO 2CH 3 CH 2 CHO+O 2 →2CH 3 CH 2 COOH 该方法是国外生产丙酸的主要方法。
可燃性危险特性:遇明火、高温、强氧化剂可燃; 燃烧排放刺激烟雾
用途五:丙酸是重要的化工原料，是杀菌剂甲霜灵、苯霜灵，除草剂敌稗、喹禾灵、嗯唑禾草灵、吡氟禾草灵、噻唑禾草灵、氟吡氯禾灵、乳氟禾草灵、丙草胺、敌草胺等的中间体，也是医药中间体，并可作为食品工业防腐剂、青饲料的保鲜剂等。
外观性质:无色液体，有刺激性气味。
下游产品:丙酸甲酯 --> 甲霜灵 --> 3,4-二氨基喹啉 --> 丙酸乙酯 --> 环丙沙星 --> 4-氨基-3-硝基喹啉 --> DL-丙氨酸 --> 富马酸二甲酯 --> 5-羧基-异二氢吲哚 --> 丙酸钠 --> 2-溴乙酸乙酯 --> 4-氯-3-硝基喹啉 --> 异二氢吲哚-5-甲酸甲酯 --> 3-苯基环氧乙烷甲酸乙酯 --> 2-溴蒽 --> 3-氯丙酸 --> 敌稗 --> 5-溴异二氢吲哚 --> 2-甲基己酸 --> 4-溴异二氢吲哚 --> 3-甲基喹啉 --> 2-氯丙酸 --> 硫普罗宁 --> 6-溴-1,2,3,4-四氢-2-喹啉酮 --> 敌草胺 --> 2-氯丙酸乙酯 --> 6-氨基-2-(2,4-二甲苯基)-1H-苯并[DE]异喹啉-1,3(2H)-二酮 --> 2-溴丙酸 --> 2-氯丙酰
用途六:丙酸是重要的精细化学品，也是其他许多精细化学品的中间体。主要用作食品和饲料添加剂，其次用于家药珍重草剂及医药、香料等。在谷物和饲料添加剂方面，丙酸的应用效果显著，消费量增长很快。（1）食口添加剂。丙酸钙和丙酸钠能防止由于微生物作用而引起的食物腐败变质，延长食品保存时间，行之有效用于面包和糕点的保存。（2）谷物保存剂。丙酸用于谷物的防霉烂和防结块获得成功，为谷物的长期贮藏保鲜提供了新方法。（3）饮料保藏剂。试验证明，丙酸、丙酸钠、丙酸钙都是较好的饲料保藏剂，多用于保藏猪、牛、羊和家禽用饲料，其中以丙酸钙效果最好。丙酸盐类中的丙酸锌和丙酸镉是生产对苯二甲酸酯的聚酯用催化剂；丙酸酯类品种很多，具有各自的用
稍有刺鼻的恶臭气味。能与水混溶，溶于乙醇、氯仿和乙醚。易燃。低毒，半数致死量（大鼠，经口）4.29g/kg。有腐蚀性。爆炸极限2.1%-12%。
用途四:防腐剂；防霉剂；香料。用于啤酒等的粘性物质抑阻剂。
蒸气压:2.4 mm Hg ( 20 °C)
含量分析:取试样3g(准确至0.1mg)，放入250ml烧瓶中，加水50ml，混合。加酚酞试液(TS-167)数滴，用lmol/L氢氧化钠滴定至最初出现微红色并维持30s以上。每毫升lmol/L氢氧化钠相当于丙酸(C3H6O2)74.08mg。
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食品添加剂最大允许使用量最大允许残留量标准:添加剂中文名称允许使用该种添加剂的食品中文名称添加剂功能最大允许使用量（g/kg）最大允许残留量（g/kg）丙酸食品食品用香料用于配制香精的各香料成分不得超过在GB 2760中的最大允许使用量和最大允
类别:易燃液体
使用限量:FAO/WHO(1984)：加工干酪3000
FEMA:2924
Sigma Aldrich:79-09-4(sigmaaldrich)
刺激数据:皮肤- 兔子 495 毫克重度; 眼- 兔子 990 微克重度
方法一:(1)丙醛氧化法。丙醛在钴、铜或锰盐