(E)-hex-2-enoic acid 反式-2-己烯酸

CAS 13419-69-7 MFCD00002705

化学结构图

13419-69-7
SMILES: CCC/C=C\C(O)=O

化学属性

Mol. FormulaC6H10O2
Mol. Weight114
Refractive indexn20/D 1.438(lit.)
Vapor Density>;1 (vs air)
Boiling Point217
Density0.965
Melting Point33-35
Flash Point125°(257°F)
TSCAYes

别名和识别编码

Chemical Name(E)-hex-2-enoic acid
PubChem Substance ID87570791
EC Number236-528-5
Beilstein Registry Number1720443
MDL NumberMFCD00002705
CAS Number13419-69-7
Synonym 2-己烯酸 Β-丙基丙烯酸 hex-2-enoic acid ISOHYDROSORBIC ACID TIMTEC-BB SBB009088 TRANS-2-HEXENOIC ACID BETA-PROPYLACRYLIC ACID β-propylacrylic acid FEMA 3169 HEX-2(TRANS)-ENOIC ACID 2-HEXENOIC ACID Butylideneacetic acid T2 HEXENOIC ACID FEMA NUMBER 3169 反式-2-己烯酸
Chemical Name Translation反式-2-己烯酸
Reaxys-RN1720443
InChIKeyNIONDZDPPYHYKY-SNAWJCMRSA-N
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分类

  • {SNA} Building Blocks, C6, Carbonyl Compounds, Carboxylic Acids, Chemical Synthesis, Organic Building Blocks
  • {SNA} Alphabetical Listings, Certified Food Grade Products, E-H, Flavors and Fragrances, G-H, Halal Certified Products, Kosher Certified Products
  • {S
  • {SNA}

相关文献及参考

  • Alkylation of the dilithio-derivative occurs predominantly at the ɑ-carbon, in contrast to crotonic acid, which gives both ɑ- and -alkylation: Tetrahedron Lett., 1163 (1973); J. Org. Chem., 36, 3290 (1971).

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Packing GroupII
UN Number 3261
Risk Statements
  • R34 Causes burns 会导致灼伤
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Hazard Codes 8 C
Hazard Class8

其他信息

  • 蒸气密度:>;1 (vs air)
  • MOL 文件:1191-04-4.mol
  • 下游产品:Β-丙基丙烯酸甲酯

系列性分类


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