CAS 3588-17-8 MFCD00002702-(2E,4E)-Hexa-2,4-Dienedioic Acid (2E,4E)-己-2,4二烯二酸 TAO{mole}

(2E,4E)-Hexa-2,4-Dienedioic Acid (2E,4E)-己-2,4二烯二酸

CAS 3588-17-8 MFCD00002702

化学结构图

SMILES: O=C(O)/C=C/C=C/C(=O)O

化学属性

Mol. Formula	C6H6O4
Mol. Weight	142.11
Boiling Point	320 °C at 760 mmHg
Melting Point	290 °C
TSCA	No
Solubility	不溶
Appearance	白色棱柱形结晶。熔点301℃。1g能溶于约5L15℃水，溶于热乙醇、冰乙酸。

别名和识别编码

Chemical Name	(2E,4E)-Hexa-2,4-Dienedioic Acid
CAS Number	3588-17-8
Synonym	trans-trans-Muconic acid {LY} trans-trans-Muconic acid {} {LY} trans-trans-Muconic acid {} {} {LY} trans-trans-Muconic acid {} {} {} {LY} trans-trans-Muconic acid {} {} {} {} {LY} trans-trans-Muconic acid {} {} {} {} {} {LY} trans-trans-Muconic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} trans-trans-Muconic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} trans-trans-Muconic acid {} {} {} {} {} {} {} {} {LY} trans-trans-Muconic acid {} {} {} {} {} {} {} {} {} {LY} trans-trans-Muconic acid {} {} {} {} {} {} {} {} {} {} {LY} trans-trans-Muconic acid {} {} {} {} {} {} {} {} {} {} {} {LY} trans-trans-Muconic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} trans-trans-Muconic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} trans-trans-Muconic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} trans-trans-Muconic acid {} {} {} {} {} {} {} {} {}
MDL Number	MFCD00002702
PubChem Substance ID	87572522
EC Number	222-724-8
Beilstein Registry Number	2,803
Merck Number	6299
Reaxys-RN	8133661
Chemical Name Translation	(2E,4E)-己-2,4二烯二酸
LabNetwork Molecule ID	LN00774675
InChI	InChI=1S/C6H6O4/c7-5(8)3-1-2-4-6(9)10/h1-4H,(H,7,8)(H,9,10)/b3-1+,4-2+
Canonical SMILES	O=C(O)/C=C/C=C/C(O)=O

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品牌质保精细包装现货库存一流品牌服务

产品应用

A metabolite found in urine, which determines biological exposure index for workers exposed to Benzene.

安全信息

GHS Symbol

WGK Germany3

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

RTECSMM2235070

Precautionary statements

P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P302+P352+P332+P313+P362+P364
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P305+P351+P338
P332+P313
P305+P351+P338+P337+P313
P302+P350
P337+P313

Signal word Warning

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S37 Wear suitable gloves 戴适当手套；
S36 Wear suitable protective clothing 穿戴适当的防护服；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Hazard Codes Xi

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 10 mg/L
REFERENCE :
   EVHPAZ EHP, Environmental Health Perspectives.  (U.S. Government Printing
   Office, Supt of Documents, Washington, DC 20402)  No.1-    1972-
   Volume(issue)/page/year: 81,77,1989

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

Alfa Aesar:反,反-已二烯二酸,98+% trans,trans-1,3-Butadiene-1,4-dicarboxylic acid, 98+%(3588-17-8)
MOL 文件:3588-17-8.mol
用途一:用于有机合成。
反式,反式-1,3-丁二烯-1,4-二羧酸价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 M0473 反,反-粘康酸 trans,trans-Muconic Acid 1G 409元 2010/06/21 128070010 反式,反式-1,3-丁二烯-1,4-二羧酸 trans,trans-Muconic acid 97% 1 GR 365元 2010/06/21 128070050 反式,反式-1,3-丁二烯-1,4-二羧酸 trans,trans-Muconic acid 97% 5 GR 1229元
图谱信息:反式,反式-1,3-丁二烯-1,4-二羧酸(3588-17-8)红外图谱(IR2) 反式,反式-1,3-丁二烯-1,4-二羧酸(3588-17-8)红外图谱(IR1) 反式,反式-1,3-丁二烯-1,4-二羧酸(3588-17-8)Raman光谱反式,反式-1,3-丁二烯-1,4-二羧酸(3588-17-8)核磁图( 13 CNMR) 反式,反式-1,3-丁二烯-1,4-二羧酸(3588-17-8)质谱(MS)
Acros Organics:反,反-粘康酸/己二烯二酸 trans,trans-Muconic acid, 97%(3588-17-8)
上游原料:溴化钾 --> 二溴 --> 已二酸二乙酯
TCI Shanghai:反式,反式-粘糠酸 trans,trans-Muconic Acid,>;98.0%(T)(3588-17-8)
Sigma Aldrich:3588-17-8(sigmaaldrich)
方法一:将3kg氢氧化钾溶于5L甲醇，搅拌，滴加1130g热至100℃的α,δ-二溴已二酸二乙酯。调节加料速度，使反应物较激烈地回流。加料后继续加热搅拌2h。在室温放置过夜，滤出2,4-已二烯二酸钾盐和溴化钾。将滤饼溶于8L热水，加30g活性炭煮沸，过滤。滤液冷却后加浓盐酸酸化。滤出产物，洗涤，干燥，得165-195g2，4-已二烯二酸。收率37%-43%。