CAS 445-29-4 MFCD00002405-2-Fluorobenzoic Acid 邻氟苯甲酸 TAO{mole}

2-Fluorobenzoic Acid 邻氟苯甲酸

CAS 445-29-4 MFCD00002405

化学结构图

SMILES: O=C(O)c1ccccc1F

化学属性

Mol. Formula	C7H5FO2
Mol. Weight	140.11
Melting Point	122-125
TSCA	T
Density	1.46
Solubility	微溶于热水，溶于醇、醚。
Appearance	white pwdr.
Boiling Point	244.7°C at 760 mmHg

别名和识别编码

Chemical Name	2-Fluorobenzoic Acid
CAS Number	445-29-4
Alfabeta Name	FLUOROBENZOICACID 2-
MDL Number	MFCD00002405
Synonym	2-Fluorobenzoic acid {LY} 2-Fluorobenzoic acid {} {LY} 2-Fluorobenzoic acid {} {} {LY} 2-Fluorobenzoic acid {} {} {} {LY} 2-Fluorobenzoic acid {} {} {} {} {} {} {} {} {LY} 2-Fluorobenzoic acid {} {} {} {} {} {LY} 2-Fluorobenzoic acid {} {} {} {} {} {} {LY} 2-Fluorobenzoic acid {} {} {} {} {} {} {} {LY} 2-Fluorobenzoic acid {} {} {} {} {} {} {} {} {LY} 2-Fluorobenzoic acid {} {} {} {} {} {} {} {} {} {LY} 2-Fluorobenzoic acid {} {} {} {} {} {} {} {} {} {} {LY} 2-Fluorobenzoic acid {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Fluorobenzoic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Fluorobenzoic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Fluorobenzoic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Fluorobenzoic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Fluorobenzoic acid {} {} {} {} {} {} {} {} {} {} {}
EC Number	207-158-1
Beilstein Registry Number	971265
PubChem Substance ID	9935
Reaxys-RN	971265
Chemical Name Translation	邻氟苯甲酸
Wiswesser Line Notation	QVR BF
LabNetwork Molecule ID	LN00007939
InChI	InChI=1S/C7H5FO2/c8-6-4-2-1-3-5(6)7(9)10/h1-4H,(H,9,10)
Canonical SMILES	O=C(O)C1=CC=CC=C1F

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品牌质保精细包装现货库存一流品牌服务

产品应用

Meclofenamic Acid intermediate.

安全信息

Warnings IRRITANT

Signal word Warning

GHS Symbol

WGK Germany3

Safety Statements

S22 Do not breathe dust 不要吸入粉尘；
S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S37 Wear suitable gloves 戴适当手套；
S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P264+P265
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P302+P352
P304+P340
P305+P351+P338
P319
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P332+P317
P337+P317
P362+P364
P403+P233
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激

RTECSDH0250000

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

Hazard Codes Xi

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 700 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AEPPAE Naunyn-Schmiedeberg's Archiv fuer Experimentelle Pathologie und
   Pharmakologie.  (Berlin, Ger.) V.110-253, 1925-66.  For publisher
   information, see NSAPCC.  Volume(issue)/page/year: 183,427,1936

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 180 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#01726

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

海关编码:29163900
方法一:其制备方法是以2-氨基苯甲酸为原料，在甲氧基乙基甲基醚溶剂中加入无水氟化氢和亚硝酸钠进行重氮化，回流3h，进行后处理得到成品。 2-氟苯甲酸是无色结晶，m.P.123～125℃，溶于苯、酮、醚等有机溶剂。当2-氟苯甲酸与酰氯化剂如SOCl 2 、PCl 3 等反应，可得相应的2-氟苯甲酰氟(2-fluoro benzoyl chloride)。2-氟苯甲酰氯也是杀菌剂粉唑醇的中间体，结构式见图：
下游产品:
邻氟苯甲酸价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 F0035 2-氟苯甲酸 2-Fluorobenzoic Acid 500G 2850元 2014/06/02 F0035 2-氟苯甲酸 2-Fluorobenzoic Acid 25G 319元 2010/06/21 119360250 邻氟苯甲酸 2-Fluorobenzoic acid 99% 25 GR 329元
Acros Organics:邻氟苯甲酸 2-Fluorobenzoic acid, 99%(445-29-4)
Alfa Aesar:2-氟苯甲酸,98+% 2-Fluorobenzoic acid, 98+%(445-29-4)
TSCA:T
MSDS 信息:邻氟苯甲酸(445-29-4).msds
图谱信息:邻氟苯甲酸(445-29-4)核磁图( 13 CNMR) 邻氟苯甲酸(445-29-4)红外图谱(IR2) 邻氟苯甲酸(445-29-4)质谱(MS) 邻氟苯甲酸(445-29-4)核磁图( 1 HNMR) 邻氟苯甲酸(445-29-4)红外图谱(IR3) 邻氟苯甲酸(445-29-4)红外图谱(IR1)
Sigma Aldrich:445-29-4(sigmaaldrich)
Hazard Note:Irritant
MOL 文件:445-29-4.mol
TCI Shanghai:2-氟苯甲酸 2-Fluorobenzoic Acid,>;98.0%(T)(445-29-4)
外观性质:针状结晶。
用途二:2-氟苯甲酸是杀菌剂粉唑醇的中间体。
上游原料:氢氟酸 --> 邻氨基苯甲酸 --> 邻氟苯甲酰氯 --> 甲基醚 --> 粉唑醇 --> 苯甲酰氟
用途一:用作医药、颜料和染料的中间体