4,4-Biphenol 4,4-二羟基联苯

CAS 92-88-6 MFCD00002348

化学结构图

92-88-6
SMILES: Oc1ccc(-c2ccc(O)cc2)cc1

化学属性

Mol. FormulaC12H10O2
Mol. Weight186.21
Density1.228
Melting Point280-282°C
TSCAYes
Solubility微溶
Stability对光敏感
Appearance 白色片状结晶
Boiling Point280.69 °C at 760 mmHg

别名和识别编码

Chemical Name4,4-Biphenol
CAS Number92-88-6
Alfabeta NameDIHYDROXYBIPHENYL 44-,'
MDL NumberMFCD00002348
EC Number202-200-5
Beilstein Registry Number1908886
Synonym 4,4'-Dihydroxybiphenyl {LY} 4,4'-Dihydroxybiphenyl {} {LY} 4,4'-Dihydroxybiphenyl {} {} {LY} 4,4'-Dihydroxybiphenyl {} {} {} {LY} 4,4'-Dihydroxybiphenyl {} {} {} {} {LY} 4,4'-Dihydroxybiphenyl {} {} {} {} {} {LY} 4,4'-Dihydroxybiphenyl {} {} {} {} {} {} {LY} 4,4'-Dihydroxybiphenyl {} {} {} {} {} {} {} {LY} 4,4'-Dihydroxybiphenyl {} {} {} {} {} {} {} {} {LY} 4,4'-Dihydroxybiphenyl {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dihydroxybiphenyl {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dihydroxybiphenyl {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dihydroxybiphenyl {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dihydroxybiphenyl {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dihydroxybiphenyl {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dihydroxybiphenyl {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dihydroxybiphenyl {} {} {} {}
PubChem Substance ID7112
Reaxys-RN1908886
Chemical Name Translation4,4-二羟基联苯
Wiswesser Line NotationQR DR DQ
LabNetwork Molecule IDLN00173947
Canonical SMILESOC1=CC=C(C2=CC=C(O)C=C2)C=C1
InChIInChI=1S/C12H10O2/c13-11-5-1-9(2-6-11)10-3-7-12(14)8-4-10/h1-8,13-14H
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分类

  • {SNA} Bisphenol and Sulfonyldiphenol Monomers, Monomers, Polymer Science, 材料科学
  • {SNA} Bisphenol and Sulfonyldiphenol Monomers, Materials Science, Monomers, Polymer Science
  • {SNA} Bisphenol and Sulfonyldiphenol Monomers, DIG-DY, Materials Science, Monomers, Polymer Science, 生物活性小分子,

产品应用

  • 有机合成。

相关文献及参考

  • Short: II/3
  • Short: II/27C
  • Beilstein:6,991

安全信息

Warnings IRRITANT
Signal word Warning {} {} {} {} {} {} {} {} {} {} {} {TCI}
GHS Symbol
WGK Germany2
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R21 Harmful in contact with skin 与皮肤接触有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P302+P350
  • P302+P352
  • P302+P352+P312+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P308+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P333+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H303 May be harmfully swallowed 吞食可能有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xn
RTECSDV4725000
UN Number 3077
Packing GroupIII
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen RT, stored under nitrogen {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Class9
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 4920 mg/kg
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - other changes
   Liver - other changes
   Kidney, Ureter, Bladder - other changes
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0534530

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 1780 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   28,313,1974

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 5 umol/L
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   45,2471,1985

TYPE OF TEST            : Micronucleus test
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 40 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 208,61,1988

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 100 nmol/L
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   45,2471,1985

其他信息

  • Sigma Aldrich:92-88-6(sigmaaldrich)
  • 可燃性危险特性:可燃; 燃烧产生刺激烟雾
  • Acros Organics:4,4'-联苯酚 4,4'-Biphenol, 97%(92-88-6)
  • Alfa Aesar:4,4'-二羟基联苯,99% 4,4'-Dihydroxybiphenyl, 99%(92-88-6)
  • 毒性分级:高毒
  • 下游产品:氰基联苯酚
  • 类别:有毒物品
  • 用途二:用作橡胶和乳胶的防老剂,可用于浅色橡胶制品、食品包装用胶和医用乳胶制品
  • 溶于乙醇和乙醚,微溶于水和苯。有刺激性。
  • TCI Shanghai:4,4'-联苯酚 4,4'-Biphenol,>;99.0%(GC)(92-88-6)
  • 储运特性:库房通风低温干燥; 与食品原料分开存放
  • MOL 文件:92-88-6.mol
  • 用途一:(1)用做液晶聚合物的中间体原料。   (2)合成高聚物方面,由于其耐热性能极佳,故用作聚酯、聚氨酯、聚碳酸酯、聚砜及环氧树脂的改性单体,用以制造优良的工程塑料和复合材料。   (3)用作橡胶防老剂和塑料抗氧剂。   (4)染料中间体或石油制品的稳定剂。
  • 图谱信息:4,4'-二羟基联苯(92-88-6)红外图谱(IR1) 4,4'-二羟基联苯(92-88-6)红外图谱(IR2)
  • 4,4'-二羟基联苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010362 4,4’-二羟基联苯 50g 198元 2011/04/16 B0464 4,4'-联苯酚 4,4'-Biphenol 25G 332元 2011/04/16 B0464 4,4'-联苯酚 4,4'-Biphenol 500G 2160元
  • 灭火剂:干粉,泡沫,沙土,二氧化碳, 雾状水
  • 检测方法:HPLC,NMR
  • 急性毒性:腹腔-小鼠 LD50: 100 毫克/公斤; 口服-大鼠 LD50: 9850 毫克/公斤
  • 海关编码:29061900
  • MSDS 信息:Biphenyl-4,4'-diol(92-88-6).msds

系列性分类


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