2,4,6-Trichlorophenol 2,4,6-三氯酚
CAS 88-06-2 MFCD00002172
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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分类
- {SNA} Analytical Standards, Chromatography, Environmental Standards, Q-Z, Standards for Personal Care and Cosmetic Products, neats, prohibited substances (EU-REGULATION No 1223/2009), 农残和代谢标准品, 分析/色谱, 按照字母排序
- {SNA} Analytical Standards,
- {
- {SNA} Building Blocks
- {SNA} Alphabetical Index of Analytical Standards, All alphabetically sorted, Analytical Standards, Analytical/Chromatography, Chromatography,
- {Chemicalbook} 农药中间体: 杀菌剂中间体: 三唑类杀菌剂
- {SNA} Additional Standards,
- {SNA} Analytical Standards, Certified Reference Materials (CRMs), Chromatography, Fluka CRMs for Chromatography (neats), Organic CRMs TraceCERT, Standards for Personal Care and Cosmetic Products, neats,
产品应用
- 农药、医药中间体
相关文献及参考
- Merck: 14,9644 Beilstein:6,190
- Merck: 14,9644
安全信息
GHS Symbol
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- H315 Causes skin irritation 会刺激皮肤
- H351 Suspected of causing cancer 怀疑致癌
- H302 Harmful if swallowed 吞食有害
- H319 Causes serious eye irritation 严重刺激眼睛
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P308+P313
- P332+P313
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P301+P312+P330
- P337+P313
- P305+P351+P338
- P273 Avoid release to the environment. 避免释放到环境中。
- P281 Use personal protective equipment as required. 使用所需的个人防护装备。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
- P305+P351+P338+P337+P313
- P302+P352+P312+P361+P364
- P405 Store locked up. 上锁保管。
- P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
- R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
- R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
- R22 Harmful if swallowed 吞咽有害
- R50/53
- R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性:吸入,皮肤接触和吞食都会产生十分严重的不可逆危险
- R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
- R11 Highly flammable 非常易燃
- R52/53
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 185 gm/kg/2Y-C TOXIC EFFECTS : Tumorigenic - Carcinogenic by RTECS criteria Blood - leukemia Blood - lymphoma, including Hodgkin's disease REFERENCE : NCITR* National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD) No.0-205. For publisher information, see NTPTR*. Volume(issue)/page/year: NCI-TR-155,1979
TYPE OF TEST : TD - Toxic dose (other than lowest) ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 882 gm/kg/2Y-C TOXIC EFFECTS : Tumorigenic - Carcinogenic by RTECS criteria Liver - tumors REFERENCE : NCITR* National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD) No.0-205. For publisher information, see NTPTR*. Volume(issue)/page/year: NCI-TR-155,1979
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 441 gm/kg/2Y-C TOXIC EFFECTS : Tumorigenic - Carcinogenic by RTECS criteria Liver - tumors REFERENCE : NCITR* National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD) No.0-205. For publisher information, see NTPTR*. Volume(issue)/page/year: NCI-TR-155,1979
TYPE OF TEST : TD - Toxic dose (other than lowest) ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 374 gm/kg/2Y-C TOXIC EFFECTS : Tumorigenic - Carcinogenic by RTECS criteria Blood - leukemia Blood - lymphoma, including Hodgkin's disease REFERENCE : NCITR* National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD) No.0-205. For publisher information, see NTPTR*. Volume(issue)/page/y
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - guinea pig DOSE/DURATION : 1 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : FMCHA2 Farm Chemicals Handbook. (Meister Pub., 37841 Euclid Ave., Willoughy, OH 44094) Volume(issue)/page/year: -,C310,1991
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Mammal - species unspecified DOSE/DURATION : 454 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 45(10),16,1980
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 820 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : PCOC** Pesticide Chemicals Official Compendium, Association of the American Pesticide Control Officials, Inc., 1966. (Topeka, KS) Volume(issue)/page/year: -,1176,1966
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 276 mg/kg TOXIC EFFECTS : Behavioral - tremor Behavioral - convulsions or effect on seizure threshold Nutritional and Gross Metabolic - body temperature increase REFERENCE : BJPCAL British Journal of Pharmacology and Chemotherapy. (London, UK) V.1-33, 1946-68. For publisher information, see BJPCBM. Volume(issue)/page/year: 13,20,1958
TYPE OF TEST : LD50 - Lethal dose, 50 percent kil
TYPE OF TEST : Micronucleus test TEST SYSTEM : Rodent - hamster Lung DOSE/DURATION : 30 mg/L REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 280,175,1992
TYPE OF TEST : DNA damage TEST SYSTEM : Microorganism - not otherwise specified DOSE/DURATION : 500 umol/L REFERENCE : CBINA8 Chemico-Biological Interactions. (Elsevier Scientific Pub. Ireland Ltd., POB 85, Limerick, Ireland) V.1- 1969- Volume(issue)/page/year: 69,333,1989
TYPE OF TEST : Mutation test systems - not otherwise specified TEST SYSTEM : Rodent - hamster Lung DOSE/DURATION : 100 mg/L REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 303,101,1993
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Yeast - Saccharomyces cerevisiae DOSE/DURATION : 400 mg/L REFERENCE : EVSRBT Environmental Science Research. (Plenum Pub. Corp., 233 Spring St., New York, NY 10013) V.1- 1972- Volume(issue)/page/year: 12,325,1978
TYPE OF TEST : Mutation in mammalian somatic cells TEST SYSTEM : Rodent - mouse Lymphocyte DOSE/DURATION : 80 mg/L REFERENCE : EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 12,85,1988
TYPE OF TEST : Cytogenetic analysis TEST SYSTEM : Rodent - hamster Ovary DOSE/DURATION : 400 mg/L REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 303,101,1993
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TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE : 12500 mg/kg SEX/DURATION : female 2 week(s) pre-mating female 1-21 day(s) after conception TOXIC EFFECTS : Reproductive - Effects on Newborn - growth statistics (e.g.%, reduced weight gain) REFERENCE : FAATDF Fundamental and Applied Toxicology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1981- Volume(issue)/page/year: 6,233,1986
其他信息
- MSDS 信息:2,4,6-三氯苯酚(88-06-2).msds
- 外观性质:无色针状结晶或黄色固体,有强烈的苯酚气味。
- 毒性分级:中毒
- 急性毒性:口服-大鼠 LD50: 820 毫克/公斤; 腹腔-大鼠 LD50: 276 毫克/公斤
- 用途二:2,4,6-三氯苯酚是杀菌剂咪鲜胺和除草剂草枯醚的中间体。
- 用途一:主要用于杀菌剂、保鲜剂咪鲜胺的主要原料
- TCI Shanghai:2,4,6-三氯苯酚 2,4,6-Trichlorophenol,>;96.0%(GC)(88-06-2)
- 类别:有毒物品
- 用途三:医药中间体。
- 方法一:其制备方法是将苯酚放入反应器中,通入氯气,通氯气时间约12h,前期反应温度60~65℃,后期2~3h为70~75℃,通氯气结束后保温1h,通入氯气的量为苯酚物质的量的3倍,中途严格跟踪分析,防止氯气过量,然后通入氮气赶除多余的氯气和氯化氢,反应后的粗品经亚硫酸钠处理,然后蒸馏得产品。
- 溶解度:800 mg/l 水;525 g/100g丙酮; 113g/100g苯;37g/100gCCl4; 335g/100g二丙酮醇; 354g/100g醚;525g/100g甲醇; 163g/100g松油; 100g/100g甲苯;37g/100g松节油,溶于芳香族溶剂和腐蚀性的苏达溶液。
- MOL 文件:88-06-2.mol
- 刺激数据:皮肤-兔子 20 毫克/24小时 中度; 眼睛-兔子 0.25 毫克/24小时 重度
- 可燃性危险特性:明火可燃; 受热放出有毒氯化物气体
- 储运特性:库房通风低温干燥; 与食品原料分开储运
- Acros Organics:2,4,6-三氯苯酚 2,4,6-Trichlorophenol, 98%(88-06-2)
- 蒸气压:1 mm Hg ( 76.5 °C)
- 用途四:农药、医药中间体
- Sigma Aldrich:88-06-2(sigmaaldrich)
- 酚类单一化合物标准液
- 灭火剂:二氧化碳、砂土、泡沫、干粉
- Alfa Aesar:2,4,6-三氯苯酚,98% 2,4,6-Trichlorophenol, 98%(88-06-2)
- 上游原料:盐酸 --> 苯酚 --> 磺酸
- 用途五:用作染料中间体、杀菌剂、防腐剂,也用作聚酯纤维的溶剂。校准仪器和装置;评价方法;工作标准;质量保证/质量控制;其他。
- 图谱信息:2,4,6-三氯酚(88-06-2)红外图谱(IR1) 2,4,6-三氯酚(88-06-2)红外图谱(IR2) 2,4,6-三氯酚(88-06-2)红外图谱(IR3) 2,4,6-三氯酚(88-06-2)核磁图( 13 CNMR) 2,4,6-三氯酚(88-06-2)Raman光谱 2,4,6-三氯酚(88-06-2)质谱(MS) 2,4,6-三氯酚(88-06-2)核磁图( 1 HNMR)
- color:white to slightly brown
- 2,4,6-三氯酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 C139481000 2,4,6-三氯苯酚 100g 551元 2011/08/23 AT5530101 2,4,6-三氯苯酚 98% 50g 342元 2011/08/23 K9134001 2,4,6-三氯苯酚 50g 350元
- 海关编码:29081000
- 下游产品:2,4-二氯酚 --> 2-(2,4,6-三氯苯氧基)乙基氯 --> 2-(2,4,6-三氯苯氧基)乙基溴 --> 咪酰胺 --> 4-氰基四氢吡喃