CAS 87-86-5 MFCD00002162-Pentachlorophenol 五氯酚;PCP TAO{mole}

Pentachlorophenol 五氯酚;PCP

CAS 87-86-5 MFCD00002162

化学结构图

SMILES: Oc1c(Cl)c(Cl)c(Cl)c(Cl)c1Cl

化学属性

Mol. Formula	C6HCl5O
Mol. Weight	266.32
Boiling Point	309-310°C
Density	0.7915
Melting Point	165-180°C
Vapor Density	9.2 (vs air)
Vapor Pressure	40 mmHg ( 211.2 °C)
TSCA	Yes
Flash Point	11 °C
Stability	对光敏感
Solubility	微溶于水，溶于稀碱液、乙醇、苯等多数有机溶剂。

别名和识别编码

Chemical Name	Phenol, pentachloro-
CAS Number	87-86-5
PubChem Substance ID	992
EC Number	200-659-6
Beilstein Registry Number	1285380
MDL Number	MFCD00002162
Synonym	######## 'LGC' (1623) 1-(1-phenylcyclohexyl)-piperidin 1-Hydroxy-2,3,4,5,6-pentachlorobenzene 1-Hydroxypentachlorobenzene 2,3,4,5,6-Pentachlorophenol 2,3,4,5,6-五氯酚 AD 73 Acutox BIOCEL CHLOROPHEN(R) CP 1309 Chem-Tol Chlon Chlorophen Chlorophenasic acid Dowicide 7 Dowicide G Durotox EP 30 EP 30 (pesticide) Fungifen Grundier Arbezo Grundier arbezol Lauxtol Lauxtol A Liroprem NCI-C54933 NCI-C55378 NCI-C55389 PCP PCP(R) PENCHLOROL PENTA(R) PKhF Pent Penta-Kil
Merck Number	14,7109
Chemical Name Translation	五氯酚;PCP
Wiswesser Line Notation	QR BG CG DG EG FG
InChI	InChI=1S/C6HCl5O/c7-1-2(8)4(10)6(12)5(11)3(1)9/h12H

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分类

Alphabetic, Analytical Standards, Analytical/Chromatography, Aromatics, Chromatography, Environmental Standards, Fungicides, Herbicides, Insecticides, Method Specific, Molluscicides, Oeko-Tex Standard 100, Organochlorines, Others, P, PA - PEN, Pesticides, Pesticides & Metabolites, Phenols, Plant growth regulators
{uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; alcohol; 1fragment
{SA} Building Blocks, C6 to C8, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds,
{SNA} Alphabetical Index of Analytical Standards,

产品应用

用于ICP-AES、AAS、AFS、ICP-MS、离子色谱等。滴定分析用标准溶液。校准仪器和装置；评价方法；工作标准；质量保证/质量控制；其他。

安全信息

GHS Symbol

WGK Germany1

Hazard statements

H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
H300 Fatal if swallowed 吞食致命
H301 Toxic if swallowed 吞食有毒
H310 Fatal in contact with skin 皮肤接触致命
H311 Toxic in contact with skin 皮肤接触中毒
H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H330 Fatal if inhaled 吸入致命
H331 Toxic if inhaled 吸入中毒
H335 May cause respiratory irritation 可能导致呼吸道刺激
H351 Suspected of causing cancer 怀疑致癌
H370 Causes damage to organs 导致器官损伤
H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。

Hazard Codes F,T T+,N T+,N,T,F,Xn

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
P203
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P264+P265
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P281 Use personal protective equipment as required. 使用所需的个人防护装备。
P284 Wear respiratory protection.? 佩戴呼吸保护装置。
P301+P310
P301+P316
P302+P350
P302+P352
P304+P340
P305+P351+P338
P307+P311
P308+P313
P308+P316
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
P316
P318
P319
P320 Specific treatment is urgent (see … on this label). 紧急具体治疗（见本标签上的）。
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
P330 Rinse mouth. 漱口
P332+P313
P332+P317
P337+P313
P337+P317
P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
P361+P364
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P362+P364
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P403+P233
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Danger

RTECSSM6300000

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)

Safety Statements

S22 Do not breathe dust 不要吸入粉尘；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S52 Not recommended for interior use on large surface areas 建议不在表面积大的区域内部使用；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
S7 Keep container tightly closed 保存在严格密闭容器中；
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；

Packing GroupII

UN Number UN 3155 6.1/PG 2 UN3155

Risk Statements

R26 Very toxic by inhalation 吸入极毒
R24/25 Toxic in contact with skin and if swallowed 皮肤接触及吞食都有毒
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
R50/53
R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
R11 Highly flammable 非常易燃
R52/53

Storage condition 密封阴凉保存。储存温度2-8℃ 密封阴凉避光保存。 0-6°C

Hazard Class6.1(a)

Restrict 剧毒化学品

Warnings 危化品目录(2015) 危险化学品

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 46 mg/kg
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Liver - tumors
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB223-159

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 8736 mg/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Endocrine - tumors
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-349,1989

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 70 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PHPHA6 Phytiatrie-Phytopharmacie.  (Societe Francaise de Phytiatrie et de
   Phytopharmacie, Etoile de Choisy, Route de St-Cyr, 78000 Versailles, France)
    V.1-    1952-  Volume(issue)/page/year: 1,3,1953

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 32 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ARTODN Archives of Toxicology.  (Springer-Verlag, Heidelberger Pl. 3, D-1000
   Ber

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - gerbil
DOSE/DURATION           : 294 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ARTODN Archives of Toxicology.  (Springer-Verlag, Heidelberger Pl. 3, D-1000
   Berlin 33, Fed. Rep. Ger.)  V.32-    1974-  Volume(issue)/page/year:
   40,63,1978

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 70 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
   Vascular - BP elevation not characterized in autonomic section
   Kidney, Ureter, Bladder - urine volume increased
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 76,104,1942

TYPE OF TEST            : LD50 - Lethal dose, 50

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Microorganism - not otherwise specified
DOSE/DURATION           : 10 mg/L
REFERENCE :
   EESADV Ecotoxicology and Environmental Safety.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802)  V.1-    1977-  Volume(issue)/page/year:
   13,7,1987

TYPE OF TEST            : Mutation test systems - not otherwise specified
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 30 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 343,157,1995

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Rodent - hamster Embryo
DOSE/DURATION           : 100 mg/L
REFERENCE :
   AETODY Advances in Modern Environmental Toxicology.  (Senate Press, Inc.,
   P.O. Box 252, Princeton Junction, NJ 08550)  V.1-    1980-
   Volume(issue)/page/year: 1,241,1980

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 40 nmol/plate
REFERENCE :
   AIDZAC Aichi Ika Daigaku Igakka

TYPE OF TEST            : Gene conversion and mitotic recombination
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 190 umol/L
REFERENCE :
   IARCCD IARC Scientific Publications.  (Geneva, Switzerland)  No.1-26,
   1971-78.  For publisher information, see IAPUDO.  Volume(issue)/page/year:
   10,161,1974

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 400 mg/L
REFERENCE :
   EVSRBT Environmental Science Research.  (Plenum Pub. Corp., 233 Spring St.,
   New York, NY 10013) V.1-    1972-  Volume(issue)/page/year: 12,325,1978

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 120 mg/kg
SEX/DURATION            : female 8-11 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - homeostasis
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   28,151,1974

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 450 mg/kg
SEX/DURATION            : female 6-14 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetal death
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB223-160

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 60 mg/kg
SEX/DURATION            : female 9 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo o

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 50 mg/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   28,151,1974

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED

其他信息

{
下游产品:氮 --> 氢 --> 氧 --> 氧化钙 --> 红磷 --> 庚酸 --> 四氯苯醌 --> 月桂酸五氯苯
方法一:利用六六六无效体为原料，经高压水解制得五氯酚钠，再经酸化即为五氯酚。
{Chemi
用途一:用作喷气式发动机燃料
{Ch
图谱信息:五氯苯酚(87-86-5)红外图谱(IR2) 五氯苯酚(87-86-5)质谱(MS) 五氯苯酚(87-86
Alfa Aesar:五氯苯酚,TechnicalGrade,86% Pentachlorophenol, Technical Grade, 86%(87-86-5)
蒸气压:40 mm Hg ( 211.2 °C)
五氯苯酚价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 80096927 五氯苯酚（剧毒） 250g 400元
外观性质:无色结晶体，带有苯酚气味。
职业标准:TWA 0
有特臭，溶于水时生成有腐蚀性的盐酸气；热时有强烈刺激性气味。易溶于乙醇和乙醚，溶于苯，微溶于冷石油醚，几乎不溶于水。中等毒，半数致死量（雄大鼠，雌大鼠，经口）146、175mg/kg。对眼睛、呼吸系统、皮肤有刺激性。在光照下速度分解，脱出氯化氢，颜色变深。常温下不易挥发
上游原料:五氯酚钠
Alfa Aesar:五氯苯酚,TechnicalGrade,86% Pentach
下游产品:氮 --> 氢 --> 氧 --> 氧化钙 --> 红磷 --> 庚酸 --> 四氯苯醌 --> 月桂酸五氯苯酯 --> 单组分湿固化聚氨酯密封胶 --> JHY-905H粘鼠胶 --> 邻四氯苯醌 --> 沙棘黄 --> WD3003建筑结构胶 --> 瞬间堵漏胶 --> 888多用途建
灭火剂:砂土、干粉、泡沫
储运特性:库房通风低温干燥; 与食品原料分开储运
类别:农药
急救治疗:[1]无特殊解毒剂，对症治疗 [2]禁忌用阿托品、阿斯匹林或其它水扬酸盐控制体温
用途二:用于有机合成，稻田防除稗草及木材
刺激数据:皮肤-兔子 10 毫克/24小时中度; 眼睛-兔 0.1 毫升/24小时轻度
概述:五氯苯酚(简称PCP)外观为白色薄片或结晶状固体，常含一分子结晶水，稍热有极强辛辣臭味。溶于水时生成有腐蚀性的盐酸气；工业品为灰黑色粉末或片状固体，熔点187～189℃，，沸点约309-310℃（分解）。难溶于水，溶解度(20℃)20～25mg/L，溶于大多数有机溶剂如乙醇、乙醚，苯等，略溶于冷石油醚，但在四氯化碳和石蜡中溶解度不大。呈酸性，在无湿气存在时，对多数金属无腐蚀作用,与氢氧化钠反应生成能溶于水的白色钠盐晶体。与强氧化剂不相容。稳定性好，在550℃空气中不着火。工业上由苯酚在催化剂存在下直接氯化或用六六六无效体（α，β -异构体）制得。五氯苯酚(PCP)是一种重要的防腐剂,它能阻止真菌的生长、抑制细菌的腐蚀作用,长期以来均被用作皮革品和木材的防霉剂，对防治霉菌与一般虫类（如白蚁）均有效，其钠盐用于消灭血吸虫中间宿主钉螺和防治稗草等。对鱼类等水生物动物敏感等，水中含量达0.1-0.5ppm即致死。有机毒品，可通过皮肤吸收，对肝、肾有损害。误食会中毒，严重时导致死亡。但在过去的十年，医学研究发现若经常与含五氯苯酚(PCP)的产品接触，极有可能影响人体健康，而症状包括头痛、腹痛、呕吐及对中央神经系统有所损害。德国政府已设立法例规定产品含有五氯苯酚(PCP)的成份不得高于5PPM，这条例应用于各种曾受PCP及PCP化合物处理过的产品，如手袋和手表带等。所有出口到德国市场出售的产品，必须通过以上测试。中国的生态纺织标准和国际生态纺织协会的oeko-tex标准100均对纺织品中的PCP残留量规定了不得超过0.5mg/kg(婴幼儿用品不得超过 0.05mg/kg)的限量。
蒸气密度:9.2 (vs air)
可燃性危险特性:不燃; 受热分解有毒氯化物气体
{Ch