CAS 95-56-7 MFCD00002146-2-Bromophenol 2-溴苯酚 TAO{mole}

2-Bromophenol 2-溴苯酚

CAS 95-56-7 MFCD00002146

化学结构图

SMILES: Oc1ccccc1Br

化学属性

Mol. Formula	C6H5BrO
Mol. Weight	173.01
Refractive index	1.5840 to 1.5920
Boiling Point	195
Density	1.492
Melting Point	3-7
Flash Point	42.22°C
TSCA	Yes
Solubility	可溶
Stability	对空气敏感

别名和识别编码

Chemical Name	2-Bromophenol
CAS Number	95-56-7
PubChem Substance ID	7244
EC Number	202-432-7
Beilstein Registry Number	1905115
MDL Number	MFCD00002146
Reaxys-RN	1905115
Merck Number	1428
Synonym	2-Bromophenol {LY} 2-Bromophenol 2-Bromophenol, 98+% 2-Bromphenol 2-Hydroxybrombenzol 2-bromo-pheno 2-bromo-phenol 2-溴苯酚 2-溴苯酚,98+% 2-溴苯酚; 邻溴苯酚 2-溴酚 2-溴酚;邻溴苯酚;邻溴酚 o-Bromophenol o-Bromphenol ortho-bromophenol O-BROMOPHENOL ORTHO-BROMOPHENOL Phenol, 2-bromo- Phenol, o-bromo- Phenol, o-bromo- o-BROMO PHENOL (2-BROMO PHENOL) o-Bromophenol o-bromo-pheno o-bromophenic acid o-bromophenol (2 isomer) {} {LY} 2-Bromophenol {} {} {LY} 2-Bromophenol {} {} {} {LY} 2-Bromophenol {} {} {} {} {LY} 2-Bromophenol {} {} {} {} {} {LY} 2-Bromophenol {} {} {} {} {} {} {LY} 2-Bromophenol {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {LY} 2-Bromo
Alfabeta Name	BROMOPHENOL 2-
Chemical Name Translation	2-溴苯酚
Wiswesser Line Notation	QR BE
LabNetwork Molecule ID	LN00182018
InChI	InChI=1S/C6H5BrO/c7-5-3-1-2-4-6(5)8/h1-4,8H
Canonical SMILES	OC1=CC=CC=C1Br

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产品应用

Usually used in the preparation of anti-benzofurobenzofuran diimides. And also used to study the photodegradation of 2-bromophenol using UV-Vis spectroscopy and HPLC.

安全信息

GHS Symbol

WGK Germany3

Hazard statements

H226 Flammable liquid and vapour 易燃液体和蒸气
H315 Causes skin irritation 会刺激皮肤
H302 Harmful if swallowed 吞食有害
H335 May cause respiratory irritation 可能导致呼吸道刺激
H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
H319 Causes serious eye irritation 严重刺激眼睛

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Hazard Codes 3 Xn,F,Xi

RTECSSJ7875000

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P211 Do not spray on an open flame or other ignition source.? 不要喷洒在明火或其他点火源。
P233 Keep container tightly closed. ?保持容器密闭。
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P241+P242+P243
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P284 Wear respiratory protection.? 佩戴呼吸保护装置。
P301+P312+P330
P302+P352+P332+P313+P362+P364
P304+P340+P310
P305+P351+P338
P305+P351+P338+P337+P313
P337+P313
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P403+P233
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Warning

Safety Statements

S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S29 Do not empty into drains 不要排入下水道；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；

Risk Statements

R10 Flammable 易燃
R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
R22 Harmful if swallowed 吞咽有害
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R50 Very toxic to aquatic organisms 对水生生物极毒

UN Number 1993 2929 UN3082

Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

Packing GroupIII

Warnings 危化品目录(2015) IRRITANT

Hazard Class6.1/3

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 652 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 44(12),19,1979

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 1500 mg/kg
TOXIC EFFECTS :
   Behavioral - tremor
   Behavioral - convulsions or effect on seizure threshold
   Behavioral - muscle weakness
REFERENCE :
   RMSRA6 Revue Medicale de la Suisse Romande.  (Societe Medicale de La Suisse
   Romande, 2 rue Bellefontaine, 1003 Lausanne, Switzerland)  V.1-    1881-
   Volume(issue)/page/year: 16,449,1896

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 1 gm/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 1 gm/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 3

Restrict 危险品

其他信息

MSDS 信息:2-溴苯酚(95-56-7).msds
毒性分级:中毒
Hazard Note:Irritant
2-溴苯酚价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 B0630 2-溴苯酚 2-Bromophenol 500G 1960元 2014/06/02 B0630 2-溴苯酚 2-Bromophenol 25G 180元 2010/06/21 157360100 2-溴苯酚 2-Bromophenol 98% 10 ML 881元
检测方法:GC,NMR
类别:有毒物品
职业标准:STEL 0.3 毫克/ 立方米
储运特性:库房通风低温干燥; 与氧化剂、食品添加剂分开存放
溶于水。和氯仿和醚混溶
下游产品:2-异丙氧基苯硼酸 --> 2,3-二氢苯并呋喃-5-甲醛 --> 2-苄氧基苯硼酸
急性毒性:口服- 小鼠 LD50: 652 毫克/ 公斤; 腹腔-小鼠 LD50: 633 毫克/公斤
TCI Shanghai:2-溴苯酚 2-Bromophenol,>;98.0%(GC)(T)(95-56-7)
Alfa Aesar:2-溴苯酚,98+% 2-Bromophenol, 98%(95-56-7)
F:8-10-23
用途一:用于有机合成
Sigma Aldrich:95-56-7(sigmaaldrich)
外观性质:黄色到红色油状液体，具有不愉快的气味。
灭火剂:雾状水、泡沫、二氧化碳、砂土
MOL 文件:95-56-7.mol
Acros Organics:2-溴苯酚 2-Bromophenol, 98%(95-56-7)
可燃性危险特性:明火可燃; 高热放出有毒溴化物气体
图谱信息:2-溴苯酚(95-56-7)核磁图( 13 CNMR) 2-溴苯酚(95-56-7)红外图谱(IR1) 2-溴苯酚(95-56-7)质谱(MS)