Methylenediphosphonic acid 亚甲基二磷酸

CAS 1984-15-2 MFCD00002139

化学结构图

1984-15-2
SMILES: O=P(O)(O)CP(=O)(O)O

化学属性

Mol. FormulaCH6O6P2
Mol. Weight176
Melting Point201.0 to 207.0 deg-C
TSCANo
Density1.35 (50% AQ.)

别名和识别编码

Chemical NameMethylenediphosphonic acid
Synonym Bis(dihydroxyphosphoryl)methane MDP MDP 亚甲基二膦酸 亚甲磷酸 MDP Medronic acid MDP~Medronicacid METHYLENEBISPHOSPHONIC ACID METHYLENEDIPHOSPHONIC ACID Medronic Methanebisphosphonic Acid Methanediphosphonic Acid Methylene-1,1-bisphosphonic acid Methylenebiphosphonic Acid Methylenebisphosphonic acid, 99+ % Methylenebisphosphonic acid, tech. 90 % Methylenediphosphonic acid, 99+% PHOSPHONOMETHYLPHOSPHONIC ACID Phosphonic acid, methylenedi- [[(Phosphonomethyl)imino]bis[2,1-ethanediylnitrilobis(methylene)]]tetrakis-phosphonic acid; DTPMP bis(dihydroxyphosphoryl)methane disodium methanediphosphonate methane diphosphonate methylene diphosphonate methylene diphosphonate, (32)P-labeled {PubChe
Beilstein Registry Number1(4)3071
PubChem Substance ID16124
CAS Number1984-15-2
MDL NumberMFCD00002139
EC Number217-851-0
Merck Number5792
Chemical Name Translation亚甲基二磷酸
Reaxys-RN1708494
LabNetwork Molecule IDLN01286841
InChIInChI=1S/CH6O6P2/c2-8(3,4)1-9(5,6)7/h1H2,(H2,2,3,4)(H2,5,6,7)
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分类

  • {SNA} Analytical Standards, EP Standards, EP Standards L - M, Pharmacopeia & Metrological Institutes Standards, 分析/色谱
  • {SNA} Analytical Standards, Analytical/Chromatography, Chromatography, EP Standards, EP Standards L - M,
  • {SNA} Analytical Standards, Chromatography, EP Standards, EP Standards L - M,
  • Building Blocks, Chemical Synthesis, Organic Building Blocks, Phosphonic/Phosphinic Acids, Phosphorus Compounds
  • {SNA} Mass Spectrometry (MS), Reagents for Mass Spectrometry (MS), Spectroscopy, 分析/色谱, 分析试剂
  • {SN
  • {SNA} Analytical Reagents, Analytical/Chromatography, Mass Spectrometry (MS), Reagents for Mass Spectrometry (MS), Spectroscopy

相关文献及参考

  • Merck 14 ,5792
  • Beil. 1 ,IV,3071
  • FT-IR 2 (1), 1558:A / FT-IR 1 (1), 915:A / FT-NMR 1 (1), 1475:A / NMR-Reference 2 (2), 878:A / RegBook 1 (1), 1101:F / Sigma FT-IR 1 (2), 729:C / Structure Index 1 , 170:B:2
  • Used as an analogue of inorganic pyrophosphate for preparation of analogues of natural di- and tri-phosphates. See, e.g.: J. Org. Chem., 44, 3997 (1979). Review: Chem. Rev., 77, 872 (1977).
  • The Tc complex is used in bone scintigraphy.

安全信息

Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
WGK Germany3
GHS Symbol
Signal word
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Hazard Codes C
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECSSZ9138000
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Packing GroupIII
UN Number 3261
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Hazard Class8
Storage condition 0-10 0-10°C 2-8°C 储存温度2-8°C

其他信息

  • 图谱信息:亚甲基二磷酸(1984-15-2)红外图谱(IR1) 亚甲基二磷酸(1984-15-2)核磁图( 13 CNMR) 亚甲基二磷酸(1984-15-2)质谱(MS) 亚甲基二磷酸(1984-15-2)核磁图( 1 HNMR) 亚甲基二磷酸(1984-15-2)红外图谱(IR2)
  • MOL 文件:1984-15-2.mol
  • Alfa Aesar:亚甲基二膦酸,99+% Methylenediphosphonic acid, 99+%(1984-15-2)
  • Sigma Aldrich:1984-15-2(sigmaaldrich)
  • 下游产品:替鲁膦酸
  • F:3
  • 亚甲基二磷酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0843 亚甲基二膦酸 Methylenediphosphonic Acid 5G 1830元 2014/06/02 M0843 亚甲基二膦酸 Methylenediphosphonic Acid 1G 513元 2010/06/21 215072500 亚甲基二磷酸 Methylenediphosphonic acid 98% 250 MG 410元
  • 上游原料:盐酸 --> 亚甲基二磷酸四异丙酯
  • TCI Shanghai:亚甲基二膦酸 Methylenediphosphonic Acid,>;95.0%(T)(1984-15-2)
  • Acros Organics:亚甲基二磷酸 Methylenediphosphonic acid, 98%(1984-15-2)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Phosphonic/Phosphinic Acids - Phosphorus Compounds
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Spectroscopy - Analytical Reagents
  4. Mass Spectrometry (MS) - Spectroscopy
  5. Reagents for Mass Spectrometry (MS) - Mass Spectrometry (MS)
  1. Analytical & Chromatography 分析化学与色谱
  2. Ligands for Pharmaceutical Research
  1. Functional Group 官能团索引
  2. phosphonic acid derivative
  1. Functional Group 官能团索引
  2. phosphonic acid

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