4-Bromophenylboronic acid 4-溴苯硼酸
CAS 5467-74-3 MFCD00002104
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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分类
- {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents
- {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
- Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents
产品应用
- 4-Bromophenylboric acid
相关文献及参考
- Weston, G.S., et al.: J. Med. Chem., 41, 4577 (1998),
- Carbonylative cross-coupling with iodobenzenes and CO, catalyzed by trans-Dichlorobis(triphenylphosphine)palladium(II), 10491, gives unsymmetrical diaryl ketones: Tetrahedron Lett., 34, 7595 (1993); J. Org. Chem., 63, 4726 (1998). For reactions of boronic acids, see Appendix 5.
- 7. Zhang, J.; et al. , Ligand-free copper-catalyzed coupling of nitroarenes with arylboronic acids Green Chem. 4th ed., 14 , 912-916, (2012)
- Beilstein:16(2)638
- 5. Qi, Q.; Shen, Q.; Lu, L., Copper-Mediated Aerobic Fluoroalkylation of Arylboronic Acids with Fluoroalkyl Iodides at Room Temperature J. Am. Chem. Soc. 15th ed., 134 , 6548-6551, (2012) 摘要
- GC reagent for diols: J. Chromat., 158, 33 (1978); 186, 307 (1979).
- 6. Shen, K.; Han, X.; Lu, X., Cationic Pd(II)-Catalyzed Highly Enantioselective Arylative Cyclization of Alkyne-Tethered Enals or Enones Initiated by Carbopalladation of Alkynes with Arylboronic Acids Org. Lett. 7th ed., 14 , 1756-1759, (2012) 摘要
安全信息
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P264+P265
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P312
- P302+P350
- P302+P352
- P302+P352+P332+P313+P362+P364
- P304+P340
- P305+P351+P338
- P305+P351+P338+P337+P313
- P319
- P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
- P332+P313
- P332+P317
- P337+P313
- P337+P317
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P362+P364
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
- R22 Harmful if swallowed 吞咽有害
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 180 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#03201
其他信息
- Sigma Aldrich:5467-74-3(sigmaaldrich)
- TCI Shanghai:4-溴苯硼酸(含有数量不等的酸酐) 4-Bromophenylboronic Acid (contains varying amounts of Anhydride)(5467-74-3)
- TSCA:T
- MSDS 信息:4-Bromobenzeneboronic acid(5467-74-3).msds
- 4-溴苯硼酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1858 4-溴苯硼酸(含有数量不等的酸酐) 4-Bromophenylboronic Acid (contains varying amounts of Anhydride) 1G 80元 2014/06/02 B1858 4-溴苯硼酸(含有数量不等的酸酐) 4-Bromophenylboronic Acid (contains varying amounts of Anhydride) 25G 735元 2014/06/02 B1858 4-溴苯硼酸(含有数量不等的酸酐) 4-Bromophenylboronic Acid (contains varying amounts of Anhydride) 5G 210元
- MOL 文件:5467-74-3.mol
- Hazard Note:Irritant
- Acros Organics:4-Bromophenylboronic acid, 98%(5467-74-3)
- Alfa Aesar:4-溴苯硼酸,97+% 4-Bromobenzeneboronic acid, 97+%(5467-74-3)