CAS 138-89-6 MFCD00002063-N,N-Dimethyl-4-nitrosoaniline N,N-二甲基-4-亚硝基苯胺 TAO{mole}

N,N-Dimethyl-4-nitrosoaniline N,N-二甲基-4-亚硝基苯胺

CAS 138-89-6 MFCD00002063

化学结构图

SMILES: CN(C)c1ccc(N=O)cc1

化学属性

Mol. Formula	C₈H₁₀N₂O
Mol. Weight	150.2
Melting Point	85-86°C
Density	1.15
TSCA	Yes
Solubility	不溶于水，溶于乙醇、乙醚。
Boiling Point

别名和识别编码

Chemical Name	N,N-Dimethyl-4-nitrosoaniline
Synonym	1-(Dimethylamino)-4-nitrosobenzene 4-(Dimethylamino)nitrosobenzene 4-NITROSO-N,N-DIMETHYLANILINE 4-Nitroso 4-Nitroso-N,N-dimethylaniline 4-Nitrosodimethylanilin 4-Nitrosodimethylaniline p-(Dimethylamino)nitrosobenzene p-(N,N-Dimethylamino)nitrosobenzene p-Nitrosodimethylanilide p-Nitrosodimethylanilin Accelerene Accelerine Aniline Aniline, N,N-dimethyl Benzenamine, N,N-dimethyl-4-nitroso- Benzenamine,N,N-dimethyl-4-nitroso- Dimethyl(p-nitrosophenyl)amine Dimethyl(p-nitrosophenyl)amine Dimethyl-(4-nitroso-phenyl)-amine Dimethyl-p-nitrosoaniline N,N N,N-DIMETHY N,N-DIMETHYL-4-NITROSOANILINE p-(D
MDL Number	MFCD00002063
CAS Number	138-89-6
PubChem Substance ID	8749
Beilstein Registry Number	607293
EC Number	205-343-1
Merck Number	6638
Chemical Name Translation	N,N-二甲基-4-亚硝基苯胺
Reaxys-RN	607293
Wiswesser Line Notation	ONR DN1&1
LabNetwork Molecule ID	LN01102746
InChI	InChI=1S/C8H10N2O/c1-10(2)8-5-3-7(9-11)4-6-8/h3-6H,1-2H3

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

安全信息

RTECSBX7175000

GHS Symbol

Precautionary statements

P235+P410
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P310
P301+P312+P330
P305+P351+P338
P305+P351+P338+P337+P313
P332+P313
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P407 Maintain air gap between stacks/pallets. 在堆叠/货板间保持气隙。
P420 Store away from other materials. 远离其他材料。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H317 May cause an allergic skin reaction 可能导致皮肤过敏
H301 Toxic if swallowed 吞食有毒
H335 May cause respiratory irritation 可能导致呼吸道刺激
H319 Causes serious eye irritation 严重刺激眼睛
H251 Self-heating: may catch fire 自我放热：可能着火

WGK Germany3

Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

Signal word Danger

Safety Statements

S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S20 When using do not eat or drink 使用时，不得进食，饮水；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；

Packing GroupII

UN Number 1369 UN1369

Risk Statements

R11 Highly flammable 非常易燃
R24/25 Toxic in contact with skin and if swallowed 皮肤接触及吞食都有毒
R25 Toxic if swallowed 吞咽有毒
R33 Danger of cumulative effects 有累积作用的危险
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应

Hazard Codes 4.2 F,T

Hazard Class4.2

Storage condition -20 Flammables area

Warnings 危化品目录(2015)

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 7300 mg/kg/1Y-C
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Gastrointestinal - tumors
   Blood - lymphoma, including Hodgkin's disease
REFERENCE :
   PUOMA5 Proceedings of the University of Otago Medical School.  (Otago
   Medical School Research Soc., Box 913, Dunedin, New Zealand)  V.1-    1922-
   Volume(issue)/page/year: 46,68,1968

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 650 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - convulsions or effect on seizure threshold
   Kidney, Ureter, Bladder - hematuria
REFERENCE :
   JIDHAN Journal of Industrial Hygiene.  (Cambridge, MA)  V.1-17, 1919-35. For
   publisher information, see AEHLAU.  Volume(issue)/page/year: 13,87,1931

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 10 ug/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 8(Suppl
   7),1,1986

Restrict 危险品

其他信息

灭火剂:水、泡沫、砂土、二氧化碳
Acros Organics:N,N-二甲基-4-亚硝基苯胺 N,N-Dimethyl-4-nitrosoaniline, 99%(138-89-6)
用途一:测定二氧化碳时用以吸收氯化氢，苯基葡萄糖的沉淀剂，测定氯化氢、钯和高氯酸盐，分光光度测定铱、钯、铂和铑。
毒性分级:中毒
MSDS 信息:N,N-二甲基对亚硝基苯胺(138-89-6).msds
外观性质:绿色片状固体。
MOL 文件:138-89-6.mol
可燃性危险特性:可燃；遇热分解放出有毒苯胺和氮氧化物和氯化氢气体
急性毒性:口服-大鼠 LD50:650 毫克/公斤
N,N-二甲基-4-亚硝基苯胺价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 N0262 N,N-二甲基-4-亚硝基苯胺 N,N-Dimethyl-4-nitrosoaniline 500G 3830元 2014/06/02 N0262 N,N-二甲基-4-亚硝基苯胺 N,N-Dimethyl-4-nitrosoaniline 25G 396元 2010/06/21 116491000 N,N-二甲基-4-亚硝基苯胺 N,N-Dimethyl-4-nitrosoaniline 99% 100 GR 908元
Sigma Aldrich:138-89-6(sigmaaldrich)
图谱信息:N,N-二甲基-4-亚硝基苯胺(138-89-6)质谱(MS) N,N-二甲基-4-亚硝基苯胺(138-89-6)核磁图( 13 CNMR) N,N-二甲基-4-亚硝基苯胺(138-89-6)红外图谱(IR1) N,N-二甲基-4-亚硝基苯胺(138-89-6)红外图谱(IR2) N,N-二甲基-4-亚硝基苯胺(138-89-6)核磁图( 1 HNMR)
F:4.7-8-9
TCI Shanghai:N,N-二甲基-4-亚硝基苯胺 N,N-Dimethyl-4-nitrosoaniline,>;98.0%(GC)(T)(138-89-6)
类别:自燃物品
下游产品:乙基香兰素 --> 2,4-二硝基苯甲醛 --> 花菁
储运特性:库房通风低温干燥; 与酸分开存放
Alfa Aesar:N,N-二甲基-4-亚硝基苯胺,97% N,N-Dimethyl-4-nitrosoaniline, 98%(138-89-6)
方法一:将30g二甲基苯胺溶于100ml浓盐酸，在冰盐浴中冷却，搅拌下缓缓滴加含18g亚硝酸钠的50ml水溶液，保持反应液温度为0-5℃。加毕，继续搅拌半小时。吸滤，滤饼用水洗涤，真空干燥，得成品。