Trimethylsilyl Isocyanate 三甲基硅基异氰酸酯
CAS 1118-02-1 MFCD00001993
化学结构图
SMILES: C[Si](C)(C)N=C=O
化学属性
| Mol. Formula | C4H9NOSi |
|---|---|
| Mol. Weight | 115 |
| Refractive index | 1.3940 to 1.3970 |
| Boiling Point | 90-92 |
| Density | 0.851 |
| Flash Point | -2°C(lit.) |
| TSCA | Yes |
| Melting Point | -49° |
别名和识别编码
| Chemical Name | Trimethylsilyl Isocyanate |
|---|---|
| Synonym | ISOCYANATOTRIMETHYLSILANE Isocyanatotrimethylsilane Isocyanic acid, trimethylsilyl ester Orgatix SI 130 Silane, isocyanatotrimethyl- TRIMETHYLSILYL ISOCYANATE Trimethylisocyanatosilane Trimethylsilyl isocyanate Trimethylsilylisocyanat Trimethylsilylisocyanate isocyanato-trimethyl-silane isocyanatotrimethyl-silan trimethylsilanyl isocyanate 异氰酸三甲基硅酯 |
| MDL Number | MFCD00001993 |
| CAS Number | 1118-02-1 |
| PubChem Substance ID | 70696 |
| EC Number | 214-256-8 |
| Beilstein Registry Number | 1744962 |
| Reaxys-RN | 1744962 |
| Chemical Name Translation | 三甲基硅基异氰酸酯 |
| InChIKey | NIZHERJWXFHGGU-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN01281285 |
| InChI | InChI=1S/C4H9NOSi/c1-7(2,3)5-4-6/h1-3H3 |
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分类
- {uni_hamburg} no charge; isocyanate; 1fragment
- {SNA} Building Blocks, Chemical Synthesis, Isocyanates, Nitrogen Compounds, Organic Building Blocks
- {SA} Building Blocks, Chemical Synthesis, Isocyanates, Nitrogen Compounds, Organic Building Blocks
相关文献及参考
- Short: II/25C
- Short: II/6
- Short: III/35F
- Convenient protected form of "HNCO". For reactions of isocyanates, see Appendix 3. Reaction with Grignard reagents leads to primary carboxamides: Tetrahedron Lett., 981 (1975).
安全信息
GHS Symbol
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H331 Toxic if inhaled 吸入中毒
- H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
- H319 Causes serious eye irritation 严重刺激眼睛
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P284 Wear respiratory protection.? 佩戴呼吸保护装置。
- P303+P361+P353
- P305+P351+P338
- P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
- P332+P313
- P337+P313
- P342+P311
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P370+P378
- P403+P233
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- R11 Highly flammable 非常易燃
- R23 Toxic by inhalation 吸入有毒
- R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
- R42 May cause sensitisation by inhalation 吸入会产生过敏反应
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
其他信息
- Sigma Aldrich:1118-02-1(sigmaaldrich)
- F:10-19-21
- Acros Organics:三甲基硅基异氰酸酯 Trimethylsilyl isocyanate, 97%(1118-02-1)
- MOL 文件:1118-02-1.mol
- 图谱信息:三甲基硅基异氰酸酯(1118-02-1)核磁图( 1 HNMR) 三甲基硅基异氰酸酯(1118-02-1)红外图谱(IR1)
- TCI Shanghai:异氰酸三甲基硅酯 Trimethylsilyl Isocyanate,>;95.0%(GC)(1118-02-1)
- 三甲基硅基异氰酸酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 L0411902 三甲基硅异氰酸酯，94％ 5g 534元 2011/04/16 T1106 异氰酸三甲基硅酯 Trimethylsilyl Isocyanate 5G 743元 2011/04/16 T1106 异氰酸三甲基硅酯 Trimethylsilyl Isocyanate 25G 1980元
- 敏感性:Moisture Sensitive
- Alfa Aesar:三甲硅烷基异氰酸酯,94% Trimethylsilyl isocyanate, 94%(1118-02-1)
- TSCA:Yes
