CAS 109-75-1 MFCD00001962-3-Butenenitrile 烯丙基腈 TAO{mole}

3-Butenenitrile 烯丙基腈

CAS 109-75-1 MFCD00001962

化学结构图

SMILES: C=CCC#N

化学属性

Mol. Formula	C4H5N
Mol. Weight	67.09
Refractive index	1.4030 to 1.4080
Boiling Point	116-121
Density	0.834
Flash Point	24°C(lit.)
TSCA	Yes
Autoignition Point	851 °F
Melting Point	-87°
Solubility	微溶于水，可混溶于乙醇、乙醚。
Danger-Level	甲类

别名和识别编码

Chemical Name	3-Butenenitrile
Synonym	1-butene-4-nitrile 1-氰基丙烯 2-Propenylcyanide 3-BUTENENITRILE 3-Butenenitrile,Vinylacetonitrile 3-Butenylnitrile 3-Cyano-1-propene 3-Cyanopropene Acetonitrile, vinyl- Allyl Cyanide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number	109-75-1
PubChem Substance ID	8009
EC Number	203-701-1
Beilstein Registry Number	605352
MDL Number	MFCD00001962
Reaxys-RN	605352
Merck Number	290
Chemical Name Translation	烯丙基腈
Wiswesser Line Notation	NC2U1
LabNetwork Molecule ID	LN00116497
InChI	InChI=1S/C4H5N/c1-2-3-4-5/h2H,1,3H2

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安全信息

GHS Symbol

WGK Germany3

Hazard statements

H226 Flammable liquid and vapour 易燃液体和蒸气
H315 Causes skin irritation 会刺激皮肤
H301+H331
H312 Harmful in contact with skin 皮肤接触有害
H319 Causes serious eye irritation 严重刺激眼睛

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Hazard Codes 3 T

RTECSEM8050000

Precautionary statements

P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P310
P302+P352+P312+P362+P364
P303+P361+P353
P305+P351+P338
P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
P332+P313
P370+P378
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Danger

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；

Risk Statements

R10 Flammable 易燃
R21 Harmful in contact with skin 与皮肤接触有害
R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性

UN Number 1992

Packing GroupIII

Hazard Class3/6.1

Storage condition +4°C 4 4℃ 储存温度2-8℃

Warnings 危化品目录(2015)

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 132 mg/kg
TOXIC EFFECTS :
   Behavioral - tremor
   Behavioral - muscle contraction or spasticity
   Gastrointestinal - nausea or vomiting
REFERENCE :
   MELAAD Medicina del Lavoro.  Industrial Medicine.  (Via S. Barnaba, 8, 20122
   Milan, Italy) V.16-    1925-  Volume(issue)/page/year: 47,192,1956

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 2500 mg/m3/4H
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 34(4),36,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 150 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,18,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 115 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 50 ppm/6H
SEX/DURATION            : female 6-20 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - craniofacial
   (including nose and tongue)
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   FAATDF Fundamental and Applied Toxicology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1981-  Volume(issue)/page/year:
   20,365,1993

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 50 ppm/6H
SEX/DURATION            : female 6-20 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
REFERENCE :
   FAATDF Fundamental and Applied Toxicology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1981-  Volume(issue)/page/year:
   20,365,1993

Restrict 危险品

其他信息

下游产品:二烯丙基胺
灭火剂:水、泡沫、砂土、二氧化碳
刺激数据:皮肤- 兔子 10 毫克/ 24小时轻度; 眼- 兔子 500 毫克/ 24小时轻度
外观性质:无色液体，有不愉快的气味。
Sigma Aldrich:109-75-1(sigmaaldrich)
毒性分级:高毒
Alfa Aesar:Allyl cyanide, 90+%(109-75-1)
急性毒性:口服- 大鼠 LD50: 115 毫克/ 公斤; 皮下-大鼠 LD50: 150 毫克/公斤
用途一:用于有机合成。
方法一:由烯丙基溴和氰化亚铜反应得到。
职业标准:STEL 0.3 毫克/ 立方米
图谱信息:烯丙基腈(109-75-1)核磁图( 1 HNMR) 烯丙基腈(109-75-1)核磁图( 13 CNMR) 烯丙基腈(109-75-1)质谱(MS) 烯丙基腈(109-75-1)红外图谱(IR1)
MSDS 信息:3-丁烯腈(109-75-1).msds
F:10
烯丙基腈价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 A0227 烯丙基腈 Allyl Cyanide 25ML 325元 2011/04/16 A0227 烯丙基腈 Allyl Cyanide 500ML 3410元 2010/05/25 44775 Allyl cyanide, 90+% 25g 440元
TCI Shanghai:烯丙基腈 Allyl Cyanide,>;92.0%(GC)(109-75-1)
上游原料:氰化亚铜 --> 3-溴丙烯
储运特性:库房通风低温干燥; 与氧化剂、酸类、食品添加剂分开存放
可燃性危险特性:遇明火、高热可燃; 受热产生有毒氮氧化物烟雾遇酸分解有毒气体
MOL 文件:109-75-1.mol
类别:有毒物品