3-Methylaminopropionitrile 3-甲胺基丙腈
CAS 693-05-0 MFCD00001954
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分类
- Building Blocks, C1 to C5, Chemical Synthesis, Cyanides/Nitriles, Nitrogen Compounds, Organic Building Blocks
- {uni_hamburg} no charge; 1fragment
- {SNA} Building Blocks, C1 to C5, Chemical Synthesis, Cyanides/Nitriles, Nitrogen Compounds, Organic Building Blocks
相关文献及参考
- Beilstein: 4,III,1264
- Short: II/19b
- Short: II/25C
安全信息
GHS Symbol
- H303 May be harmfully swallowed 吞食可能有害
- H312 Harmful in contact with skin 皮肤接触有害
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H332 Harmful if inhaled 吸入有害
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352
- P302+P352+P312+P362+P364
- P304+P312
- P304+P340
- P304+P340+P312
- P305+P351+P338
- P305+P351+P338+P337+P313
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
- P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
- P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
- P332+P313
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R20/21 Harmful by inhalation and in contact with skin 吸入及与皮肤接触有害
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 1400 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : ZAARAM Zentralblatt fuer Arbeitsmedizin und Arbeitsschutz. (Darmstadt, Fed. Rep. Ger.) V.1-25, 1951-75. Volume(issue)/page/year: 19,225,1969
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 2260 mg/kg TOXIC EFFECTS : Behavioral - somnolence (general depressed activity) Behavioral - tremor Skin and Appendages - hair REFERENCE : NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0570990
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 2260 mg/kg TOXIC EFFECTS : Behavioral - somnolence (general depressed activity) Behavioral - tremor Kidney, Ureter, Bladder - hematuria REFERENCE : NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0570990
其他信息
- 用途一:用于有机合成。
- 方法一:由丙烯腈与甲胺经加成而得。将甲胺-乙醇溶液加入反应锅内,搅拌冷却至5℃,滴加丙烯腈-乙醇溶液,保持10-20℃,约3h加完。在15℃以下继续反应1h后,常压蒸去乙醇,再减压蒸馏,收集112-115(13.3kPa)馏分,即分3-甲氨基丙腈。
- Sigma Aldrich:693-05-0(sigmaaldrich)
- MOL 文件:693-05-0.mol
- Acros Organics:3-甲氨基丙腈 N-Methyl-beta-alaninenitrile, 98%(693-05-0)
- 海关编码:29269095
- 上游原料:乙醇溶液 --> 1-氨基乙醇
- 3-甲胺基丙腈价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 126220050 3-甲胺基丙腈 N-Methyl-beta-alaninenitrile 98% 5 GR 155元 2010/06/21 126220500 3-甲胺基丙腈 N-Methyl-beta-alaninenitrile 98% 50 GR 639元
- MSDS 信息:3-Methylaminopropionitrile(693-05-0).msds