(Dimethylamino)Acetonitrile (剧毒品,不能销售)(二甲氨基)乙腈
CAS 926-64-7 MFCD00001890
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分类
- Building Blocks, C1 to C5, Chemical Synthesis, Cyanides/Nitriles, Nitrogen Compounds, Organic Building Blocks
- {uni_hamburg} no charge; 1fragment
- {SA} Building Blocks, C1 to C5, Chemical Synthesis, Cyanides/Nitriles, Nitrogen Compounds, Organic Building Blocks
- {SNA} Building Blocks, C1 to C5, Chemical Synthesis, Cyanides/Nitriles, Nitrogen Compounds, Organic Building Blocks
相关文献及参考
- Beil. 4 ,IV,2368
- Aldrich MSDS 1 , 742:D / Corp MSDS 1 (1), 1329:D / RegBook 1 (1), 1005:M / Sax 6 , 1108 / Structure Index 1 , 157:B:2 / Vapor Phase 3 , 814:C
- Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
- Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
- Formyl anion equivalent. Self-condensation was found to compete with alkylation in the Stork LDA procedure, but the molecule was successfully used to introduce a formyl group by SN2' alkylation in the presence of K2CO3, in a synthesis of -cyclocitral: Tetrahedron Lett., 25, 3457 (1984):
- For a review of the use of ɑ-dialkylaminonitriles as acyl anion equivalents, see: Tetrahedron, 39, 3207 (1983).
安全信息
GHS Symbol
- H310 Fatal in contact with skin 皮肤接触致命
- H319 Causes serious eye irritation 严重刺激眼睛
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H300 Fatal if swallowed 吞食致命
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P301+P310
- P302+P350
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- R27 Very toxic in contact with skin 与皮肤接触极毒
- R25 Toxic if swallowed 吞咽有毒
- R36 Irritating to eyes 刺激眼睛
- R10 Flammable 易燃
- R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
- S38 In case of insufficient ventilation wear suitable respiratory equipment 通风不良时,佩带适当的呼吸器;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
TYPE OF TEST : LCLo - Lowest published lethal concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 250 ppm/4H TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 23,95,1962
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 50 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 23,95,1962
TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Ocular SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 100 mg/kg TOXIC EFFECTS : Sense Organs and Special Senses (Eye) - conjunctive irritation Sense Organs and Special Senses (Eye) - effect, not otherwise specified REFERENCE : EPASR* United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW, Washington, DC 20460) History unknown. Volume(issue)/page/year: FYI-OTS-0483-0238
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 32 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information.
其他信息
- 可燃性危险特性:易燃; 高热放出有毒氮氧化物气体
- Alfa Aesar:二甲氨基乙腈,98% Dimethylaminoacetonitrile, 98%(926-64-7)
- 刺激数据:皮肤-兔子 500 毫克/24小时 轻度; 眼睛-兔子 20 毫克/24小时 中度
- 储运特性:库房通风低温干燥; 与氧化剂, 酸类分开储运
- 毒性分级:剧毒
- Sigma Aldrich:926-64-7(sigmaaldrich)
- 灭火剂:干粉, 二氧化碳, 砂土, 泡沫
- 蒸气压:760 mm Hg ( 137 °C)
- MSDS 信息:N,N-二甲基氨基乙腈(926-64-7).msds
- 类别:易燃液体
- 急性毒性:口服-大鼠 LD50: 50 毫克/公斤; 吸入-大鼠 LCL0: 250 PPM/4小时
- 海关编码:29269095
- 外观性质:无色至淡黄色液体。
- MOL 文件:926-64-7.mol
- 图谱信息:N,N-二甲基氨基乙腈(926-64-7)核磁图( 1 HNMR) N,N-二甲基氨基乙腈(926-64-7)红外图谱(IR1) N,N-二甲基氨基乙腈(926-64-7)质谱(MS) N,N-二甲基氨基乙腈(926-64-7)核磁图( 13 CNMR)
- N,N-二甲基氨基乙腈价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 211490250 N,N-二甲基氨基乙腈 Dimethylaminoacetonitrile 98% 25 GR 512元
- Acros Organics:Dimethylaminoacetonitrile,98%(926-64-7)
- 爆炸物危险特性:蒸气与空气混合可爆