CAS 1194-65-6 MFCD00001781-2,6-Dichlorobenzonitrile, 97% 2，6-二氯苯腈 TAO{mole}

2,6-Dichlorobenzonitrile, 97% 2，6-二氯苯腈

CAS 1194-65-6 MFCD00001781

化学结构图

SMILES: N#Cc1c(Cl)cccc1Cl

化学属性

Mol. Formula	C7H3Cl2N
Mol. Weight	172.01
Density	1.623
Melting Point	143-146°C
TSCA	No
Boiling Point	270 °C at 760 mmHg
Solubility	25 MG/L (25 ºC)
Flash Point	270°C

别名和识别编码

Chemical Name	2,6-Dichlorobenzonitrile, 97%
Synonym	Casoron {LY} Casoron {} {LY} Casoron {} {} {LY} Casoron {} {} {} {LY} Casoron {} {} {} {} {LY} Casoron {} {} {} {} {} {LY} Casoron {} {} {} {} {} {} {LY} Casoron {} {} {} {} {} {} {} {LY} Casoron {} {} {} {} {} {} {} {} {LY} Casoron {} {} {} {} {} {} {} {} {} {LY} Casoron {} {} {} {} {} {} {} {} {} {} {LY} Casoron {} {} {} {} {} {} {} {} {} {} {} {LY} Casoron {} {} {} {} {} {} {} {} {} {} {} {} {LY} Casoron {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Casoron {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Casoron {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Casoron {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Casoron {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Casoron {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Casoron {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number	1194-65-6
EC Number	214-787-5
Beilstein Registry Number	1909167
MDL Number	MFCD00001781
PubChem Substance ID	3031
Merck Number	3042
Chemical Name Translation	2，6-二氯苯腈
Reaxys-RN	1909167
Wiswesser Line Notation	NCR BG FG
LabNetwork Molecule ID	LN00219966
InChI	InChI=1S/C7H3Cl2N/c8-6-2-1-3-7(9)5(6)4-10/h1-3H
Canonical SMILES	N#CC1=C(Cl)C=CC=C1Cl

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

安全信息

Signal word Warning

GHS Symbol

WGK Germany2

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；

Risk Statements

R21 Harmful in contact with skin 与皮肤接触有害
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R51/53

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P302+P350
P302+P352+P312+P362+P364
P305+P351+P338
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P501 Dispose of contents/container to..… 处理内容物/容器.....

RTECSDI3500000

Hazard statements

H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
H312 Harmful in contact with skin 皮肤接触有害
H303 May be harmfully swallowed 吞食可能有害

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

Packing GroupIII

UN Number 3077 UN3077

Hazard Codes 9

Hazard Class9

Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 260 ug/kg/39D-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Liver - tumors
   Tumorigenic - tumors at site of application
REFERENCE :
   AAATAP Annali dell'Accademia di Agricoltura di Torino.  (Accademia de
   Agricoltura di Torino, Via Andrea Doria 10, 10123 Turin, Italy)  1870-
   Volume(issue)/page/year: 122,107,1979

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 260 ug/kg/39D-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Tumorigenic - tumors at site of application
REFERENCE :
   AAATAP Annali dell'Accademia di Agricoltura di Torino.  (Accademia de
   Agricoltura di Torino, Via Andrea Doria 10, 10123 Turin, Italy)  1870-
   Volume(issue)/page/year: 122,107,1979

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2710 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   RREVAH Residue Reviews.  (Springer-Verlag New York, Inc., Service Center, 44
   Hartz Way, Secaucus, NJ 07094)  V.1-    1962-  Volume(issue)/page/year:
   10,97,1965

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECI

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   30ZDA9 "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag
   New York, Inc., 1971  Volume(issue)/page/year: -,145,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 681 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PCOC** Pesticide Chemicals Official Compendium, Association of the American
   Pesticide Control Officials, Inc., 1966.  (Topeka, KS)
   Volume(issue)/page/year: -,337,1966

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 1350 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GUCHAZ Guide to the Chemicals Used in Crop Protection.  (Information Canada,
   171 Slater St., Ottawa, Ont., Canada)  Volume(issue)/page/year: 6,177,1973

TYPE OF TEST

其他信息

外观:类白色结晶粉末,稍带芳香气味.
Acros Organics:2，6-二氯苯腈 2,6-Dichlorobenzonitrile, 97%(1194-65-6)
上游原料:邻二氯苯 --> 脱水剂 --> 2,6-二氯甲苯 --> 2,6-二氯苯胺 --> 2,6-二氯苯甲醛肟 --> 2,6-二氯苄叉二氯
图谱信息:2,6-二氯苄腈(1194-65-6)核磁图( 13 CNMR) 2,6-二氯苄腈(1194-65-6)质谱(MS) 2,6-二氯苄腈(1194-65-6)红外图谱(IR1) 2,6-二氯苄腈(1194-65-6)红外图谱(IR2)
2,6-二氯苄腈价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 D1137 2,6-二氯苯甲腈 2,6-Dichlorobenzonitrile 25G 271元 2011/04/16 D1137 2,6-二氯苯甲腈 2,6-Dichlorobenzonitrile 500G 2290元 2010/06/21 113220050 2,6-二氯苄腈 2,6-Dichlorobenzonitrile 97% 5 GR 289元
Alfa Aesar:2,6-二氯苯甲腈,98% 2,6-Dichlorobenzonitrile, 98%(1194-65-6)
方法一:2，6-二氯苯腈的制备方法较多。 2，6-二氯苯甲醛肟脱水，即 2，6-二氯苯甲醛肟加入脱水剂脱水，经冷却、结晶析出，再经过滤、洗涤、烘干，即得到 2，6-二氯苯腈。我国目前生产上主要采用这条路线。 2，6-二氯甲苯在催化剂存在下通过氨氧化法一步制得 2，6-二氯苯腈。这条路线反应过程大大缩短，减少了污染，并可连续化生产，降低了成本。此外，还有其他多种合成方法，如 2，6-二氯苯甲醛或 2，6-二氯-二氯苄与羟胺反应，2，6-二氯苯胺进行重氮化、腈化反应等，都可以合成 2，6-二氯苯腈。
TCI Shanghai:2,6-二氯苯甲腈 2,6-Dichlorobenzonitrile,>;99.0%(GC)(1194-65-6)
方法二:由邻二氯苯制得。
MSDS 信息:2,6-Dichlorobenzonitrile(1194-65-6).msds
Hazard Note:Irritant/Toxic
下游产品:氟啶脲 --> 2,6-二氟苯腈 --> 氟脲杀
MOL 文件:1194-65-6.mol
用途二:2，6-二氯苯腈本身是一个除草剂品种—敌草腈，同时它也是苯甲酰脲类杀虫剂合成过程中的一个重要中间体，用于合成下一个中间体 2，6-二氟苯腈，最终得到氟铃脲、除虫脲、氟啶脲、虱螨脲等农药品种。
Sigma Aldrich:1194-65-6(sigmaaldrich)
用途三:用作植物的芽前除草剂。该品对于植物有毒害的浓度很低，防除杂草对象广，药效高，毒性低。主要用于多年生禾草作物地芽前除草。还用于生产除草剂草克乐。其主要用于生产除草剂和杀虫剂的重要中间体2,6－二氟苯腈，在工程塑料、电子材料及染料等方面也有所应用。
用途一:是多种除草剂和杀虫剂的中间体，用于生产草克乐、除虫脲、氟幼脲等10余种农药，还用于染料、塑料等