Tricarbonyl(Cyclooctatetraene)Iron(II) 三羰基环辛四烯基铁

CAS 12093-05-9 MFCD00001755

化学结构图

12093-05-9
SMILES: [Fe].[C-]#[O+].[C-]#[O+].[C-]#[O+].C1C=CC=CC=CC=1

化学属性

Mol. FormulaC11H8FeO3
Mol. Weight244.03
Melting Point93-95 °C(lit.)
TSCANo
Appearance red to brown xtl.
Stabilityair sensitive

别名和识别编码

Chemical NameTricarbonyl(Cyclooctatetraene)Iron(II)
Synonym Tricarbonylcyclooctatraeneiron 1,3,5,7-Cyclooctatetraeneiron tricarbonyl Cyclooctatetraenetricarbonyliron NSC 167370 NSC 168049 Tricarbonyl[(1,2,3,4-η)-1,3,5,7-cyclooctatetraene]iron 三羰基环辛四烯基铁 Cyclooctatetraen-eisentricarbonyl Cyclooctatetraene iron tricarbonyl Iron, tricarbonyl[(1,2,3,4η<4>)-1,3,5,7-cyclooctatetraene]- Tricarbonylcyclooctatetraene iron
MDL NumberMFCD00001755
CAS Number12093-05-9
PubChem Substance ID87577508
Beilstein Registry Number5(4)1333
Chemical Name Translation三羰基环辛四烯基铁
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分类

  • {uni_hamburg}
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Iron

相关文献及参考

  • Short: II/2 Title: Magnetic Properties of Coordination and Organometallic Transition Metal Compounds Author: König, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/2 Year: 1966 ISBN: 3-540-03593-1 ISBN: 978-3-540-03593-0 Internet Resource: DOI:10.1007/b19948 RefComment: 170 figs., XII, 578 pages. Hardcover Abstract: The data compiled refer to susceptibility measurements (susceptibility, Curie-constants, magnetic moments, transition temperatures) and ESR-measurements (g-factors and other parameters of the applied spin Hamiltonian). In volume II/2 the literature from 1899 up to 1964 has been considered. Volume II/8 supplements volume II/2, taking into account the data on magnetic susceptibilities and ESR parameters published in the p eriod 1964 to 1968. The following subvolumes II/10,II/11, II/12 supplement data up to 1974.

安全信息

Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
Packing GroupII
UN Number 3466 UN3466
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Storage condition Air Sensitive
WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310+P330
  • P302+P350
  • P302+P352+P312+P361+P364
  • P304+P340+P311
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Hazard statements
  • H301+H311+H331
  • H302 Harmful if swallowed 吞食有害
  • H302+H312+H332
  • H312 Harmful in contact with skin 皮肤接触有害
  • H332 Harmful if inhaled 吸入有害
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xn
Hazard Class6.1

系列性分类


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