CAS 100-40-3 MFCD00001576-4-Vinyl-1-Cyclohexene 4-乙烯基-1-环己烯 TAO{mole}

4-Vinyl-1-Cyclohexene 4-乙烯基-1-环己烯

CAS 100-40-3 MFCD00001576

化学结构图

SMILES: C=CC1CC=CCC1

化学属性

Mol. Formula	C8H12
Mol. Weight	108.18
Autoignition Point	517 °F
Refractive index	1.4630 to 1.4650
Vapor Density	3.76 (vs air)
Boiling Point	128°C
Vapor Pressure	10.2 mmHg ( 25 °C)
Density	0.831 g/mL at 20 °C
Melting Point	-101 °C(lit.)
Flash Point	16°C(lit.)
TSCA	Yes
Solubility	溶于多数有机溶剂。
Stability	对空气敏感

别名和识别编码

Chemical Name	4-Vinyl-1-Cyclohexene
MDL Number	MFCD00001576
CAS Number	100-40-3
Synonym	4-Vinylcyclohexene {uni_hamburg} 4-Ethenyl-1-cyclohexene NSC 15760 4-vinyl-1-cyclohexen 还愿靛蓝 3-Vinylcyclohexene 4-ethenyl-Cyclohexene 4-Vinylcyclohexene-1 4-vinylcyclohexene 4-ethenylcyclohexene 4-Ethenyl-1-cyclohexene 4-乙烯基环己烯 1-Vinyl-3-cyclohexene cyclohexene, 4-ethenyl- 1-Vinylcylohex-3-ene Cyclohexene, 4-vinyl- 1-Vinylcyclohexene-3 4-Ethenylcyclohexene 4-Vinyl-1-cyclohexen (1-3) 靛青 1-Vinylcyclohex-3-ene Cyclohexene, 4-ethenyl- 4-vinyl-cyclohexene 4-Ethenyl-1-1-cyclohexene Vinyl-4 cyclohexene 4-VINYLCYCLOHEXENE 4-Vinyl-1-cyclohexene 4-乙烯-1-環己烯 4-乙烯基-1-环己烯 4-乙烯-1-环己烯 1,2,3,4-Tetrahydrostyrene 4-ethenyl-cyclohexene 靛蓝 1-Cyclohexene, 4-vinyl- 4-VINYLCYCLOHEXENE-1 4-vinyl-1-cyclohexene NCI-C54999 butadienedimer 1-vinyl-3-cyclohexene (3-Cyclohexen-1-yl)-ethylen 4-ethenyl-cyclohexen 4-VINYL-1-CYCLOHEXENE (vch,butadienedimer) 4-vinyl-cyclohexen Butadiene dimer Cyclohexenylethylene
PubChem Substance ID	87577823
EC Number	202-848-9
Beilstein Registry Number	5(1)63
Chemical Name Translation	4-乙烯基-1-环己烯
Reaxys-RN	1901553
Wiswesser Line Notation	L6UTJ D1U1
LabNetwork Molecule ID	LN00201699
InChI	InChI=1S/C8H12/c1-2-8-6-4-3-5-7-8/h2-4,8H,1,5-7H2

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品牌质保精细包装现货库存一流品牌服务

产品应用

用于聚合物制造和有机合成

安全信息

GHS Symbol

WGK Germany2

Hazard statements

H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
H315 Causes skin irritation 会刺激皮肤
H351 Suspected of causing cancer 怀疑致癌

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSGW6650000

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P233 Keep container tightly closed. ?保持容器密闭。
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P241+P242+P243
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P281 Use personal protective equipment as required. 使用所需的个人防护装备。
P301+P310
P301+P310+P331
P302+P352+P332+P313+P362+P364
P305+P351+P338+P310
P308+P313
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P331 Do NOT induce vomiting.. 不要催吐。
P332+P313
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P370+P378
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P403+P235
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Danger

Packing GroupII

UN Number 3295 UN 1993 3/PG 2 UN1992

Risk Statements

R11 Highly flammable 非常易燃
R38 Irritating to skin 刺激皮肤
R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
R45 May cause cancer 可能致癌
R52/53
R62 Possible risk of impaired fertility 有削弱生殖能力的危险

Safety Statements

S33 Take precautionary measures against static discharges 对静电采取预防措施；
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；

Storage condition Air Sensitive 2-8°C 储存温度2-8°C 储存温度2-8℃,充氩保存

Hazard Codes F,Xn

Hazard Class3

Warnings 危化品目录(2015) 危险化学品

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 16 gm/kg/54W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Skin and Appendages - tumors
   Tumorigenic - tumors at site of application
REFERENCE :
   JNCIAM Journal of the National Cancer Institute.  (Washington, DC)  V.1-60,
   1940-78.  For publisher information, see JJIND8.  Volume(issue)/page/year:
   31,41,1963

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 103 gm/kg/2Y-I
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Reproductive - Tumorigenic effects - ovarian tumors
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-303,1986

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 206 gm/kg/2Y-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Blood - lymphoma, including Hodgkin's disease
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-303,1986

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 103 gm/kg/2Y-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Reproductive - Tumorigenic effects - ovarian tumors
REFERENCE :
   JTEHD6 Journal of Toxicology and Environmental Health.  (Hemisphere Pub.,
   1025 Vermont Ave., NW, Washington, DC 20005)  V.1-    1975/76-
   Volume(i

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 8000 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 20 mL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3080 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 27 gm/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals
   to Man.  (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210)
   V.1-    1972-  Volume(issue)/page/year: 11,279,1976

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 19500 mg/kg
SEX/DURATION            : female 30 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Maternal Effects - ovaries, fallopian tubes
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   119,302,1993

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 24 gm/kg
SEX/DURATION            : female 30 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Maternal Effects - ovaries, fallopian tubes
REFERENCE :
   TOXID9 Toxicologist.  (Soc. of Toxicology, Inc., 475 Wolf Ledge Parkway,
   Akron, OH 44311) V.1-    1981-  Volume(issue)/page/year: 12,433,1992

其他信息

Acros Organics:4-乙烯基-1-环己烯 4-Vinyl-1-cyclohexene, stabilized, 99%(100-40-3)
图谱信息:靛蓝(100-40-3)核磁图( 13 CNMR) 靛蓝(100-40-3)Raman光谱靛蓝(100-40-3)红外图谱(IR2) 靛蓝(100-40-3)红外图谱(IR1) 靛蓝(100-40-3)质谱(MS)
毒性分级:中毒
Alfa Aesar:4-Vinyl-1-cyclohexene, 98%, stab. with 100ppm 4-tert-butylcatechol(100-40-3)
急性毒性:口服- 大鼠 LD50: 2563 毫克/ 公斤; 吸入- 小鼠 LC50: 27 克/ 立方米
灭火剂:干粉、干砂、干石粉、二氧化碳、泡沫
蒸气密度:3.76 (vs air)
类别:易燃液体
用途一:用于聚合物制造和有机合成
TCI Shanghai:4-乙烯基环己烯(含稳定剂3,5-二叔丁基-4-羟基甲苯) 4-Vinyl-1-cyclohexene (stabilized with BHT),>;95.0%(GC)(100-40-3)
下游产品:4-乙烯基-1-环己烯二环氧化物,异构体混合物
可燃性危险特性:遇明火、高温、氧化剂易燃; 燃烧产生刺激烟雾
MOL 文件:100-40-3.mol
MSDS 信息:4-乙烯-1-环己烯(100-40-3).msds
Sigma Aldrich:100-40-3(sigmaaldrich)
职业标准:TLV-TWA 0.1 PPM
靛蓝价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 V0023 4-乙烯基-1-环己烯(含稳定剂BHT) 4-Vinyl-1-cyclohexene (stabilized with BHT) 500ML 565元 2014/06/02 V0023 4-乙烯基-1-环己烯(含稳定剂BHT) 4-Vinyl-1-cyclohexene (stabilized with BHT) 25ML 111元 2010/06/21 140885000 靛蓝 4-Vinyl-1-cyclohexene 99%, stabilized 500 ML 1018元
储运特性:库房通风低温干燥; 与氧化剂、酸类分开存放
F:10-23
无色液体，水中溶解度:0.05 g/L (20°C)，溶于苯和醚等多数有机溶剂。
外观性质:无色液体。
蒸气压:10.2 mm Hg ( 25 °C)