Silane, (1-cyclohexen-1-yloxy)trimethyl- 1-环己烯氧基三甲基硅烷
CAS 6651-36-1 MFCD00001541
信息真实价格透明
资金保障
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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分类
- {SNA} Building Blocks, Chemical Synthesis, Enol Ethers, Organic Building Blocks, Oxygen Compounds
相关文献及参考
- Aldrich MSDS 1 , 519:D / Corp MSDS 1 (1), 969:A / FT-IR 2 (3), 4369:A / FT-NMR 1 (3), 662:A / IR-Spectra (3), 1538:G / IR-Spectra (2), 1316:G / NMR-Reference 2 (2), 991:D / RegBook 1 (2), 2969:G / Structure Index 1 , 470:B:1 / Vapor Phase 3 , 1642:C
- Silyl enol ethers undergo crossed aldol condensations with aldehydes and ketones: J. Am. Chem. Soc., 96, 7503 (1974); for tabulated results, see: Org. Synth. Coll., 8, 323 (1993):
- Condensation with aldehydes is also promoted by F-, particularly TBAF: J. Org. Chem., 48, 932 (1983).
- The Lewis acid-catalyzed condensation with nitroalkenes leads to 1,4-diketones: J. Am. Chem. Soc., 98, 4679 (1976); Org. Synth. Coll, 7, 414 (1990).
- For reviews of the chemistry of silyl enol ethers, see: Synthesis, 91 (1977); 85 (1983).
安全信息
GHS Symbol
- H226 Flammable liquid and vapour 易燃液体和蒸气
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
- P241+P242+P243
- P242 Use only non-sparking tools. 只能使用无火花工具。
- P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P303+P361+P353
- P370+P378
- P403+P235
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- R10 Flammable 易燃
- S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
其他信息
- Hazard Note:Flammable/Keep Cold/Moisture Sensitive
- TCI Shanghai:1-(三甲基硅氧基)环己烯 1-(Trimethylsilyloxy)cyclohexene,>;95.0%(GC)(6651-36-1)
- Sigma Aldrich:6651-36-1(sigmaaldrich)
- MOL 文件:6651-36-1.mol
- Alfa Aesar:1-(三甲基硅氧烷)环己烯,99% 1-(Trimethylsiloxy)cyclohexene, 98%(6651-36-1)
- 敏感性:Moisture Sensitive
- 1-环己烯氧基三甲基硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1556 1-(三甲基硅氧基)环己烯 1-(Trimethylsilyloxy)cyclohexene 25ML 688元 2014/06/02 T1556 1-(三甲基硅氧基)环己烯 1-(Trimethylsilyloxy)cyclohexene 10ML 402元 2010/05/25 A16099 1-(三甲基硅氧烷)环己烯, 99% 1-(Trimethylsiloxy)cyclohexene, 98% 250g 8442元
- F:10-21
- 图谱信息:1-环己烯氧基三甲基硅烷(6651-36-1)核磁图( 13 CNMR) 1-环己烯氧基三甲基硅烷(6651-36-1)红外图谱(IR1) 1-环己烯氧基三甲基硅烷(6651-36-1)质谱(MS) 1-环己烯氧基三甲基硅烷(6651-36-1)核磁图( 1 HNMR)
- TSCA:Yes