Ethyl Cyclopropylcarboxylate 环丙基甲酸乙酯

CAS 4606-07-9 MFCD00001282

化学结构图

4606-07-9
SMILES: CCOC(=O)C1CC1

化学属性

Mol. FormulaC6H10O2
Mol. Weight114.14
Refractive index1.4190 to 1.4210
Boiling Point130°C(lit.)
Density0.96 g/mL at 25 °C(lit.)
Flash Point18°C(lit.)
TSCANo
Solubility不溶

别名和识别编码

Chemical NameEthyl Cyclopropylcarboxylate
CAS Number4606-07-9
Synonym Ethyl cyclopropanecarboxylate {LY} Ethyl cyclopropanecarboxylate {} {LY} Ethyl cyclopropanecarboxylate {} {} {LY} Ethyl cyclopropanecarboxylate {} {} {} {LY} Ethyl cyclopropanecarboxylate {} {} {} {} {LY} Ethyl cyclopropanecarboxylate {} {} {} {} {} {LY} Ethyl cyclopropanecarboxylate {} {} {} {} {} {} {LY} Ethyl cyclopropanecarboxylate {} {} {} {} {} {} {} {LY} Ethyl cyclopropanecarboxylate {} {} {} {} {} {} {} {} {LY} Ethyl cyclopropanecarboxylate {} {} {} {} {} {} {} {} {} {LY} Ethyl cyclopropanecarboxylate {} {} {} {} {} {} {} {} {} {} {LY} Ethyl cyclopropanecarboxylate {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl cyclopropanecarboxylate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl cyclopropanecarboxylate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl cyclopropanecarboxylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl cyclopropanecarboxylate {} {} {} {} {} {} {} {} {}
PubChem Substance ID78351
EC Number225-010-4
Beilstein Registry Number9,4
MDL NumberMFCD00001282
Reaxys-RN2039752
Alfabeta NameETHYLCYCLOPROPANECARBOXYLATE
Chemical Name Translation环丙基甲酸乙酯
InChIKeyLDDOSDVZPSGLFZ-UHFFFAOYSA-N
LabNetwork Molecule IDLN00150385
InChIInChI=1S/C6H10O2/c1-2-8-6(7)5-3-4-5/h5H,2-4H2,1H3
Canonical SMILESCCOC(=O)C1CC1
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分类

  • {uni_hamburg} no charge; carbocycle; alicycle; 3ring; ester; 1fragment
  • {SNA} Building Blocks, C6 to C7, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks
  • Building Blocks, C6 to C7, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks

产品应用

  • Reagent used in the addition of cyclopropane.

相关文献及参考

  • Annulation reagent for the conversion of aromatics to 2-methylindanones under Friedel-Crafts conditions: J. Am. Chem. Soc., 99, 5508 (1977); J. Org. Chem., 46, 3758 (1981):
  • Cave, C., et al.: Eur. J. Med. Chem., 25, 75 (1990),
  • Humphries, P., et al.: Bioorg. Med. Chem. Lett., 16, 6120 (2006),
  • Kiyama, R., et al.: Chem. Pharm. Bull., 43, 960 (1995),
  • Short: III/38B
  • Short: IV/16
  • Short: IV/18B

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes F
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+P353
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P403+P235
Signal word Danger {} {} {} {} {TCI}
UN Number 3272 UN3272 UN 3272 3/PG 2
Risk Statements
  • R11 Highly flammable 非常易燃
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
Packing GroupII
Warnings IRRITANT
Hazard Class3
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • TCI Shanghai:环丙基甲酸乙酯 Ethyl Cyclopropanecarboxylate,>;97.0%(GC)(4606-07-9)
  • 环丙基甲酸乙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C1060 环丙基甲酸乙酯 Ethyl Cyclopropanecarboxylate 25ML 378元 2014/06/02 C1060 环丙基甲酸乙酯 Ethyl Cyclopropanecarboxylate 250ML 2090元 2010/06/21 118351000 环丙基甲酸乙酯 Ethyl cyclopropanecarboxylate 99% 100 GR 1053元
  • Acros Organics:Ethyl cyclopropanecarboxylate, 99%(4606-07-9)
  • Alfa Aesar:环丙基甲酸乙酯,98% Ethyl cyclopropanecarboxylate, 98%(4606-07-9)
  • Sigma Aldrich:4606-07-9(sigmaaldrich)
  • Hazard Note:Highly Flammable
  • MOL 文件:4606-07-9.mol

系列性分类


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