9-Anthraldehyde 9-蒽甲醛

CAS 642-31-9 MFCD00001254

化学结构图

642-31-9
SMILES: O=Cc1c2ccccc2cc2ccccc12

化学属性

Mol. FormulaC15H10O
Mol. Weight206.24
Melting Point103-105°C
Density1.217
TSCAYes
Stability对空气敏感
Appearance 黄色晶体。熔点104-105℃。
Boiling Point305.09 °C at 760 mmHg

别名和识别编码

Chemical Name9-Anthraldehyde
Synonym 9-Anthraldehyde {LY} 9-Anthraldehyde {} {LY} 9-Anthraldehyde {} {} {LY} 9-Anthraldehyde {} {} {} {LY} 9-Anthraldehyde {} {} {} {} {LY} 9-Anthraldehyde {} {} {} {} {} {LY} 9-Anthraldehyde {} {} {} {} {} {} {LY} 9-Anthraldehyde {} {} {} {} {} {} {} {LY} 9-Anthraldehyde {} {} {} {} {} {} {} {} {LY} 9-Anthraldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Anthraldehyde {} {} {} {} {} {} {} {} {} {} {LY} 9-Anthraldehyde {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Anthraldehyde {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Anthraldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Anthraldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Anthraldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Anthraldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Anthraldehyde {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00001254
PubChem Substance ID69504
Beilstein Registry Number639167
CAS Number642-31-9
EC Number211-383-0
Reaxys-RN639167
Chemical Name Translation9-蒽甲醛
InChIKeyYMNKUHIVVMFOFO-UHFFFAOYSA-N
LabNetwork Molecule IDLN00193072
InChIInChI=1S/C15H10O/c16-10-15-13-7-3-1-5-11(13)9-12-6-2-4-8-14(12)15/h1-10H
Canonical SMILESO=CC1=C2C=CC=CC2=CC2=CC=CC=C12
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分类

  • {SNA} Aldehydes,
  • {SNA} Aldehydes, Alphabetical, Biochemicals and Reage
  • {SNA} Aldehydes, Building Blocks, C13-C60, Carbonyl Compounds, Chemical Synthesis, Derivatization agents, Organic Building Blocks, 发光化合物及其检测, 生化试剂
  • {SNA} Aldehydes, Alphabetical, Biochemicals and Reagents, Building Blocks, C13-C60, Carbohydrate Labels, Carbohydrate Labels for Chromatography, Carbonyl Compounds, Chemical Synthesis, Derivatization agents, Fluorescence, Fluorescent Indicators and Probes, Fluorescent Labeling of Amines, Fluorescent Labels,
  • {SNA} Aldehydes,

产品应用

  • 染料、医药等中间体

相关文献及参考

  • Short: III/35D2
  • Beilstein:7(3)2527
  • 1-Formyltriptycene, prepared by Diels-Alder reaction of 9-anthraldehyde with benzyne, is the key intermediate for a series of triptycene derivatives which undergo a variety of skeletal transformations on flash vacuum pyrolysis or photolysis: J. Chem. Soc., Perkin 1, 563 (1996).

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word Warning
GHS Symbol
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen Air Sensitive {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {

其他信息

  • Sigma Aldrich:642-31-9(sigmaaldrich)
  • 海关编码:29122900
  • 溶于氯仿
  • 敏感性:Air Sensitive
  • 上游原料:黄磷 --> 蒽
  • TCI Shanghai:9-蒽(甲)醛 9-Anthracenecarboxaldehyde,>;99.0%(GC)(642-31-9)
  • 图谱信息:9-蒽甲醛(642-31-9)红外图谱(IR2) 9-蒽甲醛(642-31-9)核磁图( 13 CNMR) 9-蒽甲醛(642-31-9)红外图谱(IR1) 9-蒽甲醛(642-31-9)质谱(MS) 9-蒽甲醛(642-31-9)核磁图( 1 HNMR)
  • MSDS 信息:9-Anthracenecarboxaldehyde(642-31-9).msds
  • Alfa Aesar:9-蒽醛,98% 9-Anthraldehyde, 98%(642-31-9)
  • 9-蒽甲醛价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0779 9-蒽甲醛 9-Anthracenecarboxaldehyde 500G 5930元 2014/06/02 A0779 9-蒽甲醛 9-Anthracenecarboxaldehyde 25G 636元 2010/06/21 153930250 9-蒽甲醛 9-Anthracenecarboxaldehyde 99% 25 GR 530元
  • 用途三:染料、医药等中间体
  • 用途二:产品 染料、医药等中间体。
  • 用途一:用作染料、医药等中间体
  • 检测方法:HPLC,NMR
  • MOL 文件:642-31-9.mol
  • 下游产品:9-乙烯基蒽 --> 9-氯甲基蒽 --> 9-蒽醇
  • Acros Organics:9-蒽甲醛 9-Anthracenecarboxaldehyde, 99%(642-31-9)
  • 方法一:原材料: 黄磷、液氯。

系列性分类