9-Fluorenemethanol, 99% 9-芴甲醇
CAS 24324-17-2 MFCD00001139
化学结构图
SMILES: OCC1c2ccccc2-c2ccccc21
化学属性
| Mol. Formula | C14H12O |
|---|---|
| Mol. Weight | 196.25 |
| Melting Point | 105-107°C |
| TSCA | Yes |
| Density | 1.422 |
| Boiling Point | 363.9°C at 760 mmHg |
别名和识别编码
| Chemical Name | 9-Fluorenemethanol, 99% |
|---|---|
| CAS Number | 24324-17-2 |
| Alfabeta Name | FLUORENEMETHANOL 9- |
| MDL Number | MFCD00001139 |
| Synonym | 9-Fluorenylmethanol {LY} 9-Fluorenylmethanol {} {LY} 9-Fluorenylmethanol {} {} {LY} 9-Fluorenylmethanol {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Fluoreny |
| PubChem Substance ID | 87569980 |
| Beilstein Registry Number | 6(3)3507 |
| EC Number | 246-167-5 |
| Reaxys-RN | 2330017 |
| Chemical Name Translation | 9-芴甲醇 |
| InChIKey | XXSCONYSQQLHTH-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00173075 |
| Canonical SMILES | C1=CC=CC3=C1C2=CC=CC=C2C3CO |
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分类
- {SNA} Alcohols, Building Blocks, C11 to C30+, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds
- {SA} Alcohols, Building Blocks, C11 to C30+, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds
产品应用
- 在合成脱氧核糖核苷酸时磷酸酯的保护基团；羧基保护基团。
相关文献及参考
- Reagent for protection of carboxyl groups as their 9-fluorenylmethyl (Fm) esters, which improve solubility of the molecule in organic solvents. Fm esters can be formed, e.g. by the DCC-DMAP method: Tetrahedron Lett., 24, 281 (1983), or by imidazole-catalyzed transesterification of active esters of N-protected amino acids: Int. J. Pept. Prot. Res., 21, 196 (1983). Cleavage is by hydrogenolysis. See Appendix 6.
- Can also be used to protect phosphate groups in oligonucleotide synthesis: J. Chem. Soc., Chem. Commun., 803 (1973).
- Beilstein:6(3)3507
安全信息
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
