CAS 593-71-5 MFCD00001078-Chloroiodomethane 氯碘甲烷 TAO{mole}

Chloroiodomethane 氯碘甲烷

CAS 593-71-5 MFCD00001078

化学结构图

SMILES: ClCI

化学属性

Mol. Formula	CH2ClI
Mol. Weight	176.38
Refractive index	1.5800 to 1.5850
Boiling Point	108-109 °C at 760 mmHg
Density	2.422 g/mL at 25 °C(lit.)
Flash Point	None
TSCA	No
Appearance	无色液体。沸点107-109℃，相对密度（20/4℃）2.411，折光率1.5822。
Stability	对光线敏感
Danger-Level	-
pH	-:-
Redox	-

别名和识别编码

Chemical Name	Chloroiodomethane
Synonym	Iodochloromethane {LY} Iodochloromethane {} {LY} Iodochloromethane {} {} {LY} Iodochloromethane {} {} {} {LY} Iodochloromethane {} {} {} {} {LY} Iodochloromethane {} {} {} {} {} {} {} {} {} {} {LY} Iodochloromethane {} {} {} {} {} {} {LY} Iodochloromethane {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {LY} Iodochloromethane {} {} {} {} {} {} {} {} {LY} Iodochloromethane {} {} {} {} {} {} {} {} {} {LY} Iodochloromethane {} {} {} {} {} {} {} {} {} {} {LY} Iodochloromethane {} {} {} {} {} {} {} {} {} {} {} {LY} Iodochloromethane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Iodochloromethane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Iodochloromethane {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Iodochloromethane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Iodochloromethane {} {} {} {} {} {} {} {} {} {}
MDL Number	MFCD00001078
CAS Number	593-71-5
PubChem Substance ID	11644
EC Number	209-804-8
Beilstein Registry Number	1,71
Alfabeta Name	CHLOROIODOMETHANE
Chemical Name Translation	氯碘甲烷
Reaxys-RN	1730802
InChIKey	PJGJQVRXEUVAFT-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00182807
InChI	InChI=1S/CH2ClI/c2-1-3/h1H2
Canonical SMILES	ICCl

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产品应用

氯碘甲烷一般用于simmons－smith 环丙化反应，但也应用于其他方面，比如曼尼西反应、氨甲基化、环氧化、开环和末端烯烃加成。同时，氯碘甲烷也是二碘甲烷特别有用的替代选择，用以提高反应选择性和产率。

安全信息

GHS Symbol

WGK Germany3

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激

Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P302+P350
P302+P352
P302+P352+P332+P313+P362+P364
P304+P340
P305+P351+P338
P305+P351+P338+P337+P313
P308+P313
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P332+P313
P337+P313
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P403+P233
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Warning

Packing GroupIII

UN Number UN2810

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36 Wear suitable protective clothing 穿戴适当的防护服；
S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；

Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light Light Sensitive {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect fro

Hazard Codes Xi

Warnings IRRITANT

Hazard Class6.1

Restrict -

其他信息

方法一:将二氯甲烷与碘化钠混合，在室温下搅拌，滴加二甲基甲酰胺。加毕，升温至反应物缓缓回流（约71℃）10h。静置过夜后进行水蒸气蒸馏，从馏出液中分出有机层，用水洗涤，有机层干燥后分馏得到氯碘甲烷。
MSDS 信息:Chloroiodomethane(593-71-5).msds
Sigma Aldrich:593-71-5(sigmaaldrich)
Acros Organics:氯碘甲烷 Chloroiodomethane, stabilized, 98%(593-71-5)
F:8
用途一:氯碘甲烷一般用于simmons－smith 环丙化反应，但也应用于其他方面，比如曼尼西反应、氨甲基化、环氧化、开环和末端烯烃加成。同时，氯碘甲烷也是二碘甲烷特别有用的替代选择，用以提高反应选择性和产率。
氯碘甲烷价格(试剂级):更新日期产品编号产品名称包装价格 2011/04/16 C1179 氯碘甲烷(含稳定剂铜屑) Chloroiodomethane (stabilized with Copper chip) 25G 1080元 2011/04/16 C1179 氯碘甲烷(含稳定剂铜屑) Chloroiodomethane (stabilized with Copper chip) 100G 3450元 2010/06/21 222150250 氯碘甲烷 Chloroiodomethane 98%, stabilized 25 ML 2263元
Alfa Aesar:氯碘甲烷,铜作稳定剂,98%, Chloroiodomethane, 98%, stab. with copper(593-71-5)
MOL 文件:593-71-5.mol
图谱信息:氯碘甲烷(593-71-5)核磁图( 1 HNMR) 氯碘甲烷(593-71-5)质谱(MS) 氯碘甲烷(593-71-5)红外图谱(IR1) 氯碘甲烷(593-71-5)核磁图( 13 CNMR)
氯碘甲烷价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 C1179 氯碘甲烷(含稳定剂铜屑) Chloroiodomethane (stabilized with Copper chip) 25G 774元 2014/06/02 C1179 氯碘甲烷(含稳定剂铜屑) Chloroiodomethane (stabilized with Copper chip) 100G 2460元 2010/06/21 222150250 氯碘甲烷 Chloroiodomethane 98%, stabilized 25 ML 2263元
TCI Shanghai:氯碘甲烷(含稳定剂铜屑) Chloroiodomethane (stabilized with Copper chip),>;97.0%(GC)(593-71-5)
海关编码:29034980
敏感性:Light Sensitive