2-Chlorobenzyl chloride 邻氯氯苄
CAS 611-19-8 MFCD00000893
信息真实价格透明
资金保障
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信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
一流品牌服务
分类
- {SNA} Aryl, Building Blocks, C7, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
- {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
- {Chemicalbook} 农药中间体: 除草剂中间体: 其他类除草剂
产品应用
- 2-Chlorobenzyl chloride was used as a sensory irritant to evaluate the characteristic modifications of the normal breathing pattern of exposed mice
相关文献及参考
- Short: III/20b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20b Year: 1988 Keyword: NQR ISBN: 3-540-18483-X ISBN: 978-3-540-18483-6 Internet Resource: DOI:10.1007/b86664 RefComment: IX,717 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
- Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
- Short: IV/1a Title: Densities of Liquid Systems: Nonaqueous Systems and Ternary Aqueous Systems Author: Lacmann, R.; Synowietz, C. Editor: Schäfer, Kl. Source: Landolt-Börnstein, New Series Volume: IV/1a Year: 1974 ISBN: 3-540-06269-6 ISBN: 978-3-540-06269-1 Internet Resource: DOI:10.1007/b20003 RefComment: X, 716 pages. Hardcover Abstract: Volume IV/1 contains information on the densities of liquid systems. It may b
安全信息
GHS Symbol
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H330 Fatal if inhaled 吸入致命
- H317 May cause an allergic skin reaction 可能导致皮肤过敏
- H302+H312+H332
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P332+P313
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
- P301+P312+P330
- P302+P350
- P337+P313
- P403+P233
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P302+P352+P312+P362+P364
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
- R34 Causes burns 会导致灼伤
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
- R50/53
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S29 Do not empty into drains 不要排入下水道;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Unreported SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 430 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : EPASR* United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW, Washington, DC 20460) History unknown. Volume(issue)/page/year: 8EHQ-0990-1020
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : >1140 mg/m3/1H TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : EPASR* United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW, Washington, DC 20460) History unknown. Volume(issue)/page/year: 8EHQ-0990-1020
其他信息
- 可燃性危险特性:热分解排出有毒氯化物烟雾
- 毒性分级:中毒
- 储运特性:库房低温通风干燥
- 方法二:以邻甲苯胺为原料,经重氮化置换,氯化而得。将邻甲苯胺,盐酸,水混合,冷至0-5℃,将亚硝酸钠滴入,进行重氮化反应。在迅速搅拌下,于0℃倒入氯化亚铜,自然升温至20-25℃,最后升至60-65℃,保温20min后冷却,静置、分层、洗涤、蒸馏,得到邻氯甲苯。邻氯甲苯与三氯化磷混合,于130-140℃通氯,得邻氯氯苄。
- 图谱信息:邻氯氯苄(611-19-8)质谱(MS) 邻氯氯苄(611-19-8)红外图谱(IR2) 邻氯氯苄(611-19-8)核磁图( 13 CNMR) 邻氯氯苄(611-19-8)Raman光谱 邻氯氯苄(611-19-8)红外图谱(IR1)
- 下游产品:邻氯苯甲醛 --> 异恶草酮 --> 益康唑 --> 氯辛硫磷 --> 邻氯苯乙酸 --> 2-(2-氯苯基)-2-溴乙酸甲酯 --> (2-氯苯基)甲基磺酰氯 --> 2-氯苯乙酸甲酯 --> 1-(2-氯苄基)哌嗪
- 方法一:其制备方法是将邻氯甲苯与三氯化磷在反应器内混合,于130~140℃通入氯气至反应液的相对密度达1.20~1.22为止,然后分馏得产品。 也可以用偶氮二异丁腈为催化剂,以邻氯甲苯在溶剂中通氯气氯化而制得产品。
- Sigma Aldrich:611-19-8(sigmaaldrich)
- MSDS 信息:1-Chloro-2-(chloromethyl)-benzene(611-19-8).msds
- 海关编码:29036990
- Acros Organics:2-氯苄氯 2-Chlorobenzyl chloride, 98+%(611-19-8)
- Alfa Aesar:2-氯苯甲基氯,98+% 2-Chlorobenzyl chloride, 98+%(611-19-8)
- 类别:有毒物质
- MOL 文件:611-19-8.mol
- 用途一:用于生产邻氯氰苄、邻氯苯甲醇以及合成染料、制药等
- 邻氯氯苄价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0420 2-氯苄氯 2-Chlorobenzyl Chloride 500G 432元 2014/06/02 D0420 2-氯苄氯 2-Chlorobenzyl Chloride 25G 142元 2010/06/21 186530010 邻氯氯苄 2-Chlorobenzyl chloride 98+% 1 LT 905元
- 用途二:邻氯氯苄是除草剂异恶草松的中间体,也是医药酶抑宁的中间体。
- 蒸气压:3 mm Hg ( 84 °C)
- 用途三:有机合成原料,医药工业用于制兴奋药酶抑宁等。
- 蒸气密度:5.5 (vs air)
- 急性毒性:吸入-大鼠 LC50: >; 1140 毫克/立方米/1小时; 未报-大鼠 LD50: 430 毫克/公斤
- 上游原料:三氯化磷 --> 邻甲基苯胺 --> 偶氮二异丁腈 --> 2-氯甲苯
- F:19-21
- 灭火剂:二氧化碳, 泡沫, 干粉
- TCI Shanghai:2-氯苄氯 2-Chlorobenzyl Chloride,>;98.0%(GC)(611-19-8)