Benzylchloromethyl ether 苄基氯甲基醚

CAS 3587-60-8 MFCD00000886

化学结构图

3587-60-8
SMILES: ClCOCc1ccccc1

化学属性

Mol. FormulaC8H9ClO
Mol. Weight156.61
Density1.126
Boiling Point207.1°C at 760 mmHg
Refractive index1.5230 to 1.5280
Flash Point91°C(lit.)
TSCANo
Appearance 无色液体。沸点103℃（1.73kPa），53-56℃（0.2kPa），相对密度1.1350，折光率1.5192。
pH:A

别名和识别编码

Chemical NameBenzylchloromethyl ether
Synonym Benzyl chloromethyl ether {LY} Benzyl chloromethyl ether {} {LY} Benzyl chloromethyl ether {} {} {LY} Benzyl chloromethyl ether {} {} {} {LY} Benzyl chloromethyl ether {} {} {} {} {LY} Benzyl chloromethyl ether {} {} {} {} {} {LY} Benzyl chloromethyl ether {} {} {} {} {} {} {LY} Benzyl chloromethyl ether {} {} {} {} {} {} {} {LY} Benzyl chloromethyl ether {} {} {} {} {} {} {} {} {LY} Benzyl chloromethyl ether {} {} {} {} {} {} {} {} {} {LY} Benzyl chloromethyl ether {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzyl chloromethyl ether {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzyl chloromethyl ether {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzyl chloromethyl ether {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzyl chloromethyl ether {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzyl chloromethyl ether {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzyl chloromet
CAS Number3587-60-8
EC Number250-023-7
Beilstein Registry Number1364034
MDL NumberMFCD00000886
PubChem Substance ID137983
Reaxys-RN1364034
Chemical Name Translation苄基氯甲基醚
InChIKeyLADPCMZCENPFGV-UHFFFAOYSA-N
LabNetwork Molecule IDLN00111204
InChIInChI=1S/C8H9ClO/c9-7-10-6-8-4-2-1-3-5-8/h1-5H,6-7H2
Canonical SMILESClCOCC1=CC=CC=C1
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分类

  • {SNA} Building Blocks, C8, Chemical Synthesis, Ethers, Organic Building Blocks, Oxygen Compounds
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

产品应用

  • 酸保护基团; 导入苯甲酰氧基和羟甲基基团。

相关文献及参考

  • Beilstein:6(2)414
  • Short: III/38B

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R22 Harmful if swallowed 吞咽有害
  • R23 Toxic by inhalation 吸入有毒
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R45 May cause cancer 可能致癌
  • R48/22
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P285 In case of inadequate ventilation wear respiratory protection. 在通风不足的情况下，戴呼吸防护。
  • P301+P312
  • P301+P312+P330
  • P302+P350
  • P302+P352+P312+P362+P364
  • P304+P340+P311
  • P304+P341
  • P305+P351+P338
  • P305+P351+P338+P310
  • P308+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P342+P311
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H302 Harmful if swallowed 吞食有害
  • H302+H332
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H318 Causes serious eye damage 严重伤害眼睛
  • H331 Toxic if inhaled 吸入中毒
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H350 May cause cancer 可能致癌
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 6.1 T T,N
UN Number 2810 UN2810
Packing GroupIII
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Class6.1

其他信息

  • 苄基氯甲基醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1207 苄基氯甲基醚 Benzyl Chloromethyl Ether 25G 581元 2014/06/02 B1207 苄基氯甲基醚 Benzyl Chloromethyl Ether 500G 3610元 2010/06/21 376950100 苄基氯甲基醚 Benzyl chloromethyl ether 75% 10 GR 296元
  • 上游原料:甲醛
  • Sigma Aldrich:3587-60-8(sigmaaldrich)
  • MSDS 信息:Benzylchloromethyl ether(3587-60-8).msds
  • MOL 文件:3587-60-8.mol
  • 用途一:有机合成中间体。
  • TCI Shanghai:苄基氯甲基醚 Benzyl Chloromethyl Ether,>;90.0%(GC)(3587-60-8)
  • 图谱信息:苄基氯甲基醚(3587-60-8)红外图谱(IR1)
  • F:19-21
  • Acros Organics:苄基氯甲醚 Benzyl chloromethyl ether, 75%(3587-60-8)
  • 方法一:由苄醇、甲醛、氯化氢一起反应而得。先将苄醇和甲醛溶液混合，冷却到5℃，通入氯化氢，使反应液达到饱和，再于10℃继续通入氯化氢。反应物分层，上层溶液加无水氯化钙干燥，减压下抽除其中的氯化氢。然后减压蒸馏，收集96-99℃（1.47kPa）馏分，得产品。
  • 检测方法:GC,NMR
  • 用途二:酸保护基团; 导入苯甲酰氧基和羟甲基基团。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  6. C9 - Ethers
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Epoxides

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