CAS 79-00-5 MFCD00000852-1,1,2-Trichloroethane 1,1,2-三氯乙烷 TAO{mole}

1,1,2-Trichloroethane 1,1,2-三氯乙烷

CAS 79-00-5 MFCD00000852

化学结构图

SMILES: ClCC(Cl)Cl

化学属性

Mol. Formula	C2H3Cl3
Mol. Weight	133.40
Boiling Point	114°C
Refractive index	1.4700 to 1.4720
Density	1.435
Stability	对光敏感
Melting Point	-37°C
Flash Point	11°C
Solubility	4 g/L (20 °C)

别名和识别编码

Chemical Name	1,1,2-Trichloroethane
Synonym	1,1,2-Trichloroethane {LY} 1,1,2-Trichloroethane 1,1,2-tce 1,1,2-trichloro-ethan 1,1,2-三氯乙烷 1,1,2-三氯乙烷;三氯化乙烷;β-三氯乙烷 1,2,2-Trichloroethane 1，1，2-三氯乙烷 1，1，2-三氯乙酸酯 2-三氯乙烷 CHCl2CH2Cl Ethane trichloride Ethane,1,1,2-trichloro- NCI-C04579 R-140 RCRA waste number U227 RCRA waste number U359 Trichloroethane Trichloroethane, 1,1,2-Vinyl trichloride Trichloräthan Trojchloroetan(1,1,2) VINYL TRICHLORIDE Vinyl trichloride Vinyl trichloride,β-Trichloroethan b beta-T {} {LY} 1,1,2-Trichloroethane {} {} {LY} 1,1,2-Trichloroethane {} {} {} {LY} 1,1,2-Trichloroethane {} {} {} {} {LY} 1,1,2-Trichloroethane {} {} {} {} {} {LY} 1,1,2-Trichloroethane
MDL Number	MFCD00000852
CAS Number	79-00-5
PubChem Substance ID	87576342
Beilstein Registry Number	1,85
EC Number	201-166-9
Chemical Name Translation	1,1,2-三氯乙烷
Reaxys-RN	1731726
Merck Number	9637
Wiswesser Line Notation	GYG1G
LabNetwork Molecule ID	LN00194303
Canonical SMILES	ClC(Cl)CCl

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分类

{SNA} Additional Standards, Alpha Sort, Analytical Standards, Chemical Class, Chloro,
{SA} Alkyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
{uni_hamburg} no charge; 2fragments
{SNA} Alpha Sort, Alphabetical Index of Analytical Standards, Analytical Standards, Chemical Class, Chloro, Chromatography, Environmental Standards, Halogenated, Standards for Personal Care and Cosmetic Products, T, T-Z, TP - TZ, Volatiles/ Semivolatiles, neats, prohibited substances (EU-REGULATION No 1223/2009), 分析/色谱

产品应用

脂肪、油脂、树脂、生物碱等溶剂，有机合成。

安全信息

Precautionary statements

P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P332+P313
P501 Dispose of contents/container to..… 处理内容物/容器.....
P301+P312+P330
P302+P350
P337+P313
P302+P352+P332+P313+P362+P364
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P303+P361+P353
P403+P233
P201 Obtain special instructions before use. 使用前获取专门指示。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P273 Avoid release to the environment. 避免释放到环境中。
P305+P351+P338+P337+P313
P308+P311
P405 Store locked up. 上锁保管。
P304+P340+P311
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。

WGK Germany3

Signal word Danger

Hazard statements

H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
H332 Harmful if inhaled 吸入有害
H351 Suspected of causing cancer 怀疑致癌
H302 Harmful if swallowed 吞食有害
H312 Harmful in contact with skin 皮肤接触有害
H302+H312
H331 Toxic if inhaled 吸入中毒
H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。

GHS Symbol

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSKJ3150000

Safety Statements

S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
S46 If swallowed, seek medical advice immediately and show this container or label 食入时，立即求医并出示容器/标签；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；

Hazard Codes T Xn

Risk Statements

R11 Highly flammable 非常易燃
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂

UN Number 2810

Packing GroupIII

Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

Hazard Class6.1

Warnings 危化品目录(2015) 危险化学品

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 76 gm/kg/78W-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
   Endocrine - adrenal cortex tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/page/year: NCI-TR-74,1978

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 152 gm/kg/78W-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
   Endocrine - adrenal cortex tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/page/year: NCI-TR-74,1978

{h

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Behavioral - sleep
   Liver - hepatitis (hepatocellular necrosis), zonal
REFERENCE :
   AJHYA2 American Journal of Hygiene.  (Baltimore, MD)  V.1-80, 1921-64.  For
   publisher information, see AJEPAS.  Volume(issue)/page/year: 16,325,1932

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 836 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TSCAT* Office of Toxic Substances Report.  (U.S. Environmental Protection
   Agency, Office of Toxic Substances, 401 M St., SW, Washington, DC 20460)
   Volume(issue)/page/year: OTS051

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 3730 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 970 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AOHYA3 Annals of Occupational Hygiene.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford,

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 135 mmol/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11

TYPE OF TEST            : Micronucleus test
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 100 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(iss

TYPE OF TEST            : Sex chromosome loss and nondisjunction
TEST SYSTEM             : Mold - Aspergillus nidulans
DOSE/DURATION           : 750 ppm
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 201,401,1988

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Rodent - mouse Embryo
DOSE/DURATION           : 25 mg/L
REFERENCE :
   CALEDQ Cancer Letters (Shannon, Ireland).  (Elsevier Scientific Pub. Ireland
   Ltd., POB 85, Limerick, Ireland)  V.1-    1975- Volume(issue)/page/year:
   28,85,1985

TYPE OF TEST            : DNA adduct
TEST SYSTEM             : Mammal - species unspecified Lymphocyte
DOSE/DURATION           : 1 mmol/L
REFERENCE :
   TOLED5 Toxicology Letters.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1977-  Volume(issue)/page/year: 11,243,1982

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Administration onto the skin
TEST SYSTEM             : Rodent - guinea pig
DOSE/DURATION           : 2880 ug/kg
REFERENCE :
   APTOA6 Acta Pharmacologica et Toxicologica.  (Copenhagen, Denmark)  V.1-59,
   1945-86.  For publisher information, see PHTOEH  Volume(issue)/page/year:
   41,298,1977

TYPE OF TEST            : Mut

其他信息

下游产品:二氯乙烯 --> 1，1-二氯乙烯
可燃性危险特性:不易燃; 燃烧产生有毒
储运特性:库房通风低温干燥; 与食品添加剂分开存放
{A
图谱信息:1,1,2-三氯乙烷(79-00-5)Raman光谱 1,1,2-三氯乙烷(79-00-5)核磁图( 1 HNMR) 1,1,2-三氯乙烷(79-00-5)红外图谱(IR1) 1,1,2
方法一:1.氯乙烯氯化法预先往反应釜内投入三氯乙烷，然后于20-25℃下通入氯乙烯和氯气（摩尔比1：1.2）进行氯化合成。生成物经水洗、分离而得。2.1,2-二氯乙烷氯化法在三氯化铝或其他金属氯化物存在下，于60℃氯化即得。
Hazard Note:Irritant
用途一:主要用作脂肪、树脂、蜡、生物碱的溶剂，橡胶和树脂的中间体，农药杀虫剂，制备1,1-二氯乙烯等化学品
用途四:脂肪、油脂、树脂、生物碱等溶剂，有机合成。
{Chemi
有愉快的气味。不燃烧。溶于乙醇、乙醚和
刺激数据:皮肤-兔子 810 毫克/24小时重度；眼睛-兔子500 毫克/24小时轻度
用途二:用于有机合成，也用作醋酸纤维和橡胶的溶剂
急性毒性:腹腔-大鼠 LD50： 265 毫克/公斤；口服-小鼠 LD50： 378 毫克/公斤
挥发性有机化合物(VOCs)单组分标准液
用途五:脂肪、油脂、树脂、生物碱等溶剂，有机合成。校准仪器和装置；评价方法；工作标准；质量保证/质量控制；其他。
用途三:用作脂肪、油、蜡和树脂的溶剂，染料、香料的萃取剂，树脂和橡胶等的中间体，农业上的杀虫剂、熏蒸剂以及合成1,1-二氯乙烯的原料。用于生产偏二氯乙烯。
防护措施:高毒。对眼、鼻粘膜有刺激作用。小鼠吸入4小时，其LD50为0.002。吸入3小时，其LD50为0.018。经口LD50为0.1～0.2g/kg。空气中最高容许浓度10ppm。
类别:农药
图谱信息:1,1,2-三氯乙烷(79-00-5)Raman光谱 1,1,2-三氯乙烷(79-00-5)核磁图( 1 HNMR) 1
1,1,2-三氯乙烷价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 80133328 1.1.2-三氯乙烷 500ml 28.4元 2011/04/16 T0381 1,1,2-三氯乙烷 1,1,2-Trichloroethane 25G 146元 2011/04/16 S0640 1,1,2-三氯乙烷(1mg/ml的甲醇溶液)[用于水分析] 1,1,2-Trichloroethane (1mg/ml in Methanol) [for Water Analysis] 1ML 198元
TCI Shanghai:1,1,2-三氯乙烷(1mg/ml的甲醇溶液)[用于水分析] 1,1,2-Trichloroethane (1mg/ml in Methanol) [for Water Analysis](79-00-5)
Acros Organics:1,1,2-三氯乙烷 1,1,2-Trichloroethane, 98%(
Sigma Aldrich:79-00-5(sigmaaldrich)
上游原料:1,2-二氯乙烷 --> 三氯乙烷
常规方法:用耐酸铁桶包装。
毒性分级:高毒
职业标准:TWA 45 毫克/立方米； STEL 110 毫克/立方米
MOL 文件:79-00-5.mol
MSDS 信息:1,1,2-三氯乙烷(79-00-5).msds
外观性质:无色液体，有芳香气味。
Acros Organics:1,1,2-三氯乙烷 1,1,2-Trichloroethane, 98%(79-00-5)