Pentachloroethane 五氯乙烷

CAS 76-01-7 MFCD00000846

化学结构图

76-01-7
SMILES: ClC(Cl)C(Cl)(Cl)Cl

化学属性

Mol. FormulaC2HCl5
Mol. Weight202.28
Refractive index1.5020 to 1.5080
Boiling Point162°C
Density1.68 g/mL at 25 °C(lit.)
Flash PointNone
TSCAYes
Melting Point-29°
Solubility不溶于水。

别名和识别编码

Chemical NamePentachloroethane
CAS Number76-01-7
PubChem Substance ID6419
EC Number200-925-1
Beilstein Registry Number1(3)165
MDL NumberMFCD00000846
Reaxys-RN1736845
Merck Number7108
Synonym pentachloro-ethan {uni_hamburg} NCI-C53894 Pentachloräthan CHCl2CCl3 Pentachlorethan epapesticidechemicalcode598300 Pentachlorethane Pentachloorethaan Ethane pentachloride Ethane,pentachloro- 五氧化乙烷 R-120 Pentachloraethan freon120 1,1,1,2,2-Pentachloroethane pentachloroethane 五氯乙烷 freon 120 Pentaline C2HCl5 (pentachloro-ethane) 1,1,1,2,2-pentachloro-ethane 38. Pentachlorethan PENTALIN Pentacloroetano pentachlorethane(french) RCRA waste number U184 五氯乙烷, 96% Pentalin ethane, pentachloro- PENTACHLOROETHANE ethanepentachloride
Chemical Name Translation五氯乙烷
Wiswesser Line NotationGYGXGGG
LabNetwork Molecule IDLN01743588
InChIInChI=1S/C2HCl5/c3-1(4)2(5,6)7/h1H
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分类

  • {SNA} Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards, N-P, Others, Pesticides, Bactericides, Fungicides and Disinfectants, Standards for Personal Care and Cosmetic Products, neats, prohibited substances (EU-REGULATION No 1223/2009), 农残和代谢标准品, 农残标准品, 按照字母排序
  • {SA} Alkyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • Alphabetic, Analytical Standards, Analytical/Chromatography, P, PA - PEN
  • {SNA} Alkyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons,
  • {SNA} Analytical Standards,

相关文献及参考

  • Merck 14 ,7108
  • Short: II/27B Title: Diamagnetic Susceptibility of Organic Compounds, Oils, Paraffins and Polyethylenes Author: Kumar, M.; Gupta, R. Editor: Gupta, Radha Raman Source: Landolt-Börnstein, New Series Volume: II/27B Year: 2008 Keyword: diamagnetic susceptibility; organic compounds ISBN: 978-3-540-44359-9 (print) ISBN: 978-3-540-45860-9 (online) Internet Resource: doi:10.1007/978-3-540-45860-9 RefComment: VIII, 503 p. With CD-ROM., Hardcover RefComment: Written for: Scientists and researchers in the fields of physics, chemistry, materials science RefComment: Supplement and Revised Editon to II/16 Abstract: The volume II/27 has been divided into three subvolumes according to the classes of compounds: Subvolume A: Diamagnetic susceptibility and magnetic anisotropy of inorganic and organometallic compounds; Subvolume B: Diamagnetic susceptibility of organic compounds, oils, paraffins and polyethylenes; Subvolume C: Diamagnetic susceptibility and magnetic anisotropy of organic compounds. The data presented in this volume are based on the literature survey of the chemical abstracts up to 2005. The calculated values of diamagnetic susceptibility of organic compounds in the present subvolume II/27B are presented along with their experimental values. They have been calculated with the use of structural parameters in structural formula by using different theoretical methods available in the literature.
  • Short: II/5 Title: Molecular Acoustics Author: Schaaffs, W. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/5 Year: 1967 ISBN: 3-540-03897-3 ISBN: 978-3-540-03897-9 Internet Resource: DOI:10.1007/b19950 RefComment: 321 figs., XII, 286 pages, Hardcover
  • Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H351 Suspected of causing cancer 怀疑致癌
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
  • H302 Harmful if swallowed 吞食有害
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes T,N
RTECSKI6300000
Precautionary statements
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P332+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P301+P312+P330
  • P302+P350
  • P337+P313
  • P308+P313
  • P403+P233
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P332+P313+P362+P364
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P304+P340+P311
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P305+P351+P338+P337+P313
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P305+P351+P338
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P405 Store locked up. 上锁保管。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
Signal word Danger {} {} {} {} {TCI}
UN Number 1669 UN1669 UN 1669 6.1/PG 2
Risk Statements
  • R51/53
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R48/23
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性:吸入,皮肤接触和吞食都会产生十分严重的不可逆危险
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
  • R11 Highly flammable 非常易燃
  • R48/20
Safety Statements
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Packing GroupII
Hazard Class6.1
Storage condition 2-8°C
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 920 mg/kg
TOXIC EFFECTS :
   Behavioral - altered sleep time (including change in righting reflex)
   Behavioral - ataxia
   Liver - other changes
REFERENCE :
   SRTCAC Science Reports of the Research Institutes, Tohoku University, Series
   C: Medicine. (Tohoku University, Research Institute for Tuberculosis and
   Cancer, 4-1 Seiryo-machi, Sendai, Japan)  V.1-   1949-
   Volume(issue)/page/year: 36(1-4),10,1989

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 35 gm/m3/2H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AEPPAE Naunyn-Schmiedeberg's Archiv fuer Experimentelle Pathologie und
   Pharmakologie.  (Berlin, Ger.) V.110-253, 1925-66.  For publisher
   information, see NSAPCC.  Volume(issue)/page/year: 141,19,1929

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 700 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   QJPPAL Quarterly Journal of Pharmacy & Pharmacology.  (London, UK)  V.2-21,
   1929-48.  For publisher information, see JPPMAB.  Volume(issue)/page/year:
   7,205,1934

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 4238 ppm/2H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicen

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 80 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 369,243,1996

TYPE OF TEST            : Mutation test systems - not otherwise specified
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 500 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 343,157,1995

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 100 mg/L
REFERENCE :
   SCIEAS Science.  (American Assoc. for the Advancement of Science, 1333 H
   St., NW, Washington, DC 20005)  V.1-    1895-  Volume(issue)/page/year:
   236,933,1987

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 70 mg/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 25814 umol/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   19,98,1992

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 2500 umol/L
REFERENCE :
   TCMUD8 Teratogenesis, Carcinogenesis, and Mutagenesis.  (Alan R. Liss, Inc.,
   41 E. 11th St., New York, NY 10003)  V.1-    1980- Volume(issue)/page/year:
   9,349,1989

Warnings 危险化学品

其他信息

  • 五氯乙烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0031 五氯乙烷 Pentachloroethane 500G 3030元 2014/06/02 P0031 五氯乙烷 Pentachloroethane 25G 293元 2010/05/25 44475 五氯乙烷, 96% Pentachloroethane, 96% 250g 2142元
  • 可燃性危险特性:高热、明火可燃;高热分解有毒氯化物烟雾
  • TCI Shanghai:五氯乙烷 Pentachloroethane,>;96.0%(GC)(76-01-7)
  • 毒性分级:中毒
  • 职业标准:TWA 40 毫克/立方米
  • 方法一:由三氯乙烯通氯加成而得。将三氯乙烯加入氯化锅内,在日光灯照射下,缓缓通氯反应,温度为30-40℃,通氯至相对密度达1.680-1.684(20℃)为止。用碳酸钠尿素水溶液除去过剩的氯气,即得五氯乙烷。收率为94%。另外由四氯乙烷于紫外光照射下氯化也可得到该品。
  • 下游产品:三氯乙烯 --> 四氯乙烯 --> 六氯乙烷
  • 灭火剂:雾状水、泡沫、二氧化碳、砂土。
  • 图谱信息:五氯乙烷(76-01-7)质谱(MS)
  • 储运特性:库房通风低温干燥; 与食品添加剂分开存放
  • 用途二:五氯乙烷是良好的极性溶剂、清洁剂、矿石浮选剂、木材干燥剂,还用于制造四氯乙烯(驱肠虫药)、六氯乙烷(兽用驱虫药)等。
  • Alfa Aesar:五氯乙烷,96% Pentachloroethane, 96%(76-01-7)
  • 外观性质:无色重质液体,有氯仿气味。
  • MOL 文件:76-01-7.mol
  • 上游原料:三氯乙烯 --> 1,1,2,2-四氯乙烷
  • 用途一:用作溶剂,也用于有机合成
  • Sigma Aldrich:76-01-7(sigmaaldrich)
  • 急性毒性:口服-大鼠 LD50: 920 毫克/公斤; 吸入-小鼠 LCL0: 35000 毫克/立方米/2 小时
  • MSDS 信息:五氯乙烷(76-01-7).msds
  • 类别:有毒物品

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